• Title/Summary/Keyword: Hydrogen-tightness

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A Study on Air-tightness of High Pressure Liquid Hydrogen Pumping System at the Low Temperature (액체수소용 초저온 고압 피스톤 펌프의 기밀성 향상에 관한 기초연구)

  • Lee, Jonggoo;Lee, Jongmin;Lee, Jongtai
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.4
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    • pp.302-310
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    • 2013
  • As an initial step to develop a liquid hydrogen pump of piston type operated under cryogenic and high pressure, leakage and piston head shape for the piston pump were discussed with temperature and pressure. As the results, the leakage depended on correlation among density, viscosity, clearance area by the low temperature. In order to reduce the leakage, it was found that the air-tightness can be improved by minimizing contact surface between piston and cylinder, and also increasing pressure in-cylinder can reduce piston clearance. Among the proposed piston shapes, D type piston shape had the most air-tightness. D type piston had smaller contact surface than other piston shape and easier expansion of cup shape by pressure. The leakage of D type piston shape was found about 7%, compared with A type piston shape. But it was required that analyze about vapor lock by friction and wear resistance.

Analysis of Hydrogen-tightness on the Metal Sealing of a Fuel Pipe for FCEV according to Material Change of the Fitting Body (체결부 재료에 따른 FCEV 연료파이프 메탈 씰링부의 기밀성 분석)

  • Lee, J.M.;Han, E.S.;Chon, M.S.;Lee, H.W.
    • Transactions of Materials Processing
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    • v.28 no.5
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    • pp.266-274
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    • 2019
  • Metal sealing is used to connecting the parts between valves and fuel pipes for a FCEV which utilizes hydrogen gas of 700 bar. Instead of general carbon steel, stainless steel is the primary material used to manufacture fuel pipes due to hydrogen embrittlement. The shape of deformation between metals is an important factor on the air-tightness of the metal to metal contact. Since the stainless steel pipe is hardened using the plastic forming during the tip shaping stage, this work hardening could have an effect on the deformed shape and characteristics of contact surfaces in fastening of pipes. In this paper, the deformation history of the pipe model was considered in order to analyze the hydrogen-tightness on the metal sealing part. The contact distance and the forward displacement for fastening were compared using experimental results and the simulation results. The simulation of the effect of material change on the fitting body demonstrated that the hardness or the strength of the formed tip of the pipe was designed to a proper valued level since the characteristics of the contact surface was exhibited better when the strength of the pipe was lower than that of the fitting body.

A Study on Development of High Pressure Hydrogen Injection Valve (직접분사식 고압 수소분사밸브의 개발에 관한 연구)

  • Kim, Yun-Young;Ahn, Jong-Yun;Lee, Jong-Tai
    • Transactions of the Korean hydrogen and new energy society
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    • v.11 no.3
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    • pp.107-117
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    • 2000
  • Ball poppet valve type high pressure hydrogen injection valve actuated by solenoid has been developed for the feasibility of practical use of hydrogen fueled engine with direct injection and the precise control of fuel injection ratio in hydrogen fueled engine with dual injection. The gas-tightness of ball poppet injection valve is improved by the introduction of ball-shaped valve face, valve end typed spherical pair, and valve stem with rotating blade. Ball poppet valve is mainly closed by differential pressure due to the area difference between valve fillet and pressure piston. So, it can be operated by solenoid actuator with small driving force. From the evaluation of ball poppet injection valve, it was found that the gastightness and controlment of this injection valve are better than those of injection valve had been developed before.

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Evaluation of Micro-defects and Air Tightness of Al Die-casting by Impregnation of Organic Solvent (유기용제 함침법을 통한 알루미늄 다이캐스팅의 미세결함 및 기밀성 평가)

  • Lee, Jin-Wook;Cho, Chang-hyun;Kim, Sung-Gye;Ko, Young-Gun;Kim, Dong-Ju
    • Journal of Korea Foundry Society
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    • v.42 no.4
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    • pp.218-225
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    • 2022
  • For hydrogen-vehicle applications (air pressure control valve housing, APCVH), an investigation was conducted to determine how micro-defects in a high- pressure die-casted Al alloy (industrial code: ALDC12) could be controlled by means of a post-treatment using an organic-based impregnation solution in order to improve the air- tightness of the die-casted Al sample. Two different impregnation solutions were proposed and its test results were compared to a imported product from Japan with respect to the processing variables used. A structural investigation of the components under study was conducted by means of computer tomography and 3D X-ray micro-CT. These observations revealed that the use of the impregnation treatment to seal micro-defects led to highly significant and beneficial changes which were attributed mainly to interconnections among inherent micro-pores. A leak test after impregnation revealed that the performance improvement rate of the die-casted Al sample was ~70% for INNO-01. Therefore, the developed impregnation solutions offer an effective strategy to control the micro-defects found in various vehicle parts via die-casting.

FEA(Finite Element Analysis) Study for Electronic Hydrogen Regulator of Confidentiality Improvement (전자식 수소레귤레이터 기밀성 향상을 위한 FEA 연구)

  • Son, Won-Sik;Song, Jae-Wook;Jeon, Wan-Jae;Kim, Seung-Mo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.9
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    • pp.175-181
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    • 2019
  • In the case of a conventional single stage decompression regulator used for large depressurization in the hydrogen fuel cell system of a fuel cell electric vehicle (FCEV), problems can arise, such as pulsation, slow response, hydrogen brittleness, leakage, high weight, and high cost due to high decompression. Most of these problems can be overcome easily using two decompression mechanisms (two-stage structures). In addition, a wide outlet-pressure control range can be secured if an electronic solenoid is applied to the second decompression. Accordingly, it is necessary to improve the precision of the outlet pressure of a two-stage pressure-reducing regulator and develop techniques, such as leakage prevention, durability, light weight, and price reduction. Therefore, to improve the outlet pressure accuracy and prevent leakage, the structural part before and after decompression to improve the air tightness were divided and the analysis was carried out assuming that the valve part was closed (open ratio: 0%) after each initial internal pressure application.

Theoretical Studies on the Hydrogen Atom Transfer Reaction (Ⅱ)$^*$

  • Lee, Ik-Choon;Song, Chang-Hyun;Lee, Byung-Choon
    • Bulletin of the Korean Chemical Society
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    • v.6 no.6
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    • pp.362-366
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    • 1985
  • The hydrogen atom transfer reaction between substituted methane, $CH_3X,$ and its radical, $CH_2X(X=H,F,CH_3,CN,OH\;and\;NH_2$ was studied by MINDO/3 method. The transition state(TS) structure and energy barriers were determined and variation of the transition state and of the reactivity due to the change of X were analyzed based on the potential energy surface characteristics. It was found that the greater the radical stabilization energy. the looser the TS becomes; the TS occurs at about 15% stretch of the C-H bond, which becomes longer as the radical stabilization energy of $CH_2X$ increasers. The intrinsic barrier, ${\Delta}E*_{x.x},$ of the reaction with X was found to increase in the order $H The degree of bond stretch of the C-H bond stretch of the C-H bond at the TS also had the same order indicating that the homolytic bond cleavage of the C-H bond is rate-determining. Orbital interactions at the TS between LUMO of the fragment $C{\ldots}H{\ldots}C$ and the symmetry adapted pair of nonbonding, $n{\pm}(=n_1{\pm}n_2),$ or pi orbitals of the two X atoms were shown to be the dominant contribution in determining tightness or looseness of the TS. The Marcus equation was shown to apply to the MINDO/3 barriers and energy changes of the reaction.

A Study on Safety Performance Evaluation of NG Blower for 5 kW Class Stationary Fuel Cell Systems (5 kW급 건물용 연료전지 시스템 연료승압 블로워 안전 성능 평가에 관한 연구)

  • BAEK, JAE-HOON;LEE, EUN-KYUNG;LEE, JUNG-WOON;LEE, SEUNG-KUK;MOON, JONG-SAM;KIM, KYU-HYUNG;PARK, HAN-WOO;KIM, DONG-CHEOL;LEE, JIN-HEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.675-682
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    • 2017
  • New government, the market for stationary fuel cell systems in domestic is expected to expand in line with the policy for expanding new and renewable energy. In order to promote and expand the domestic market for stationary fuel cell systems, it is required to do research and develop for cost reduction and efficiency improvement technologies through the localization of BOP. In this study, the safety performance including the power consumption, flow rate, noise and air-tightness of the domestic fuel booster blower and the foreign fuel booster blower was evaluated and the performance improvement of the domestic blower was confirmed. As a result of the power consumption measurement and the flow rate according to the back pressure of the A company 2nd prototype and B company, the values were 73 W, 27 LPM, and 55 W, 25 LPM. These results are attributed to the improvement of performance through design changes such as CAM angle and diaphragm material.

A Evaluation on the Effect of Vibration for the Application of PEMFC Stack to Unmanned Aircraft (고분자 전해질 연료전지 스택의 무인기 적용을 위한 진동 영향 평가)

  • KANG, JUN-YOUNG;OH, GUN-WOO;KIM, MIN-WOO;LEE, JUNG-WOON;LEE, SEUNG-KUK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.587-595
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    • 2018
  • Recently, research is being conducted to use a fuel cell as a power source of unmanned aircraft. However, safety standards about applying fuel cells to unmanned aircraft are insufficient. In this paper, to improve the safety of the fuel cells for unmanned aircraft is experimentally studied. For this reason, standards for safety of fuel cells were analyzed. And influence of vibration among the evaluation items related to the safety of the fuel cell for unmanned aircraft was discussed. In order to, at constant intervals, vibration was applied to the fuel cell, then the performance was measured, the measurement items were gas tightness, polarization curve, frequency response analysis (FRA). A total of 220 hours was experimented at 20 hour intervals. the result of vibration test, gas leakage rate was a maximum of -0.04826 kPa/min and Polarization curve reached a maximum of 1.0103 times of the initial value, the charge transfer resistance reached a maximum of 1.0104 times of the initial value. This research indicate that performance of fuel cell is affected by vibration and this study is expected to contribute to the safety of fuel cell for unmanned aircraft.

Analysis of the Edge Sealing Strength for Vacuum Glass Panel Using Design of Experiment (실험계획법을 이용한 진공유리 패널 모서리 용융 접합 강도실험 분석)

  • Kim, Seung-Jong;Jeon, Euy-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.4
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    • pp.1819-1824
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    • 2014
  • The vacuum-glazing panel is a panel that keeps two glasses completely sealed in a vacuum condition. It is the high function insulation material of having the wall level minimizing the heat loss by the conduction and convection heat transmission coefficient. The edge sealing is a very important process of vacuum glass on the strength, thickness and air tightness. In this study, by using the hydrogen mixture gas torch, two sheets of glass was sealing in the furnace. The thickness and strength of the glass according to the process parameters is measurement and analysis, and predicting the edge sealing strength of glass by using taguchi method of experiment. We verified the validity of the experiment by checking the error rate through additional experiment.