• Title/Summary/Keyword: Hydrogen safety

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Effect of gas composition on dispersion characteristics of blowout gas on offshore platform

  • Yang, Dongdong;Chen, Guoming;Shi, Jihao;Li, Xinhong
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.11 no.2
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    • pp.914-922
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    • 2019
  • Gas composition has a significant impact on the dispersion behavior and accumulation characteristics of blowout gas. However, few public studies has investigated the corresponding effect of gas composition. Therefore, this study firstly builds the FLACS-based numerical model about an offshore drilling platform. Then several scenarios by varying the composition of blowout gas are simulated while the scenario with the composition of "Deepwater Horizon" accident is regarded as the benchmark. Furthermore, the effects of the gas composition on the flammable cloud volume, the influenced area of flammable cloud, the influenced area of hydrogen sulfide and the critical time of the hydrogen sulfide spreading to the living area are analyzed. The results demonstrate that gas composition is a driving factor for dispersion characteristics of blowout gas. All the results can give support to reduce the risk of the similar accidents incurred by real blowouts.

The Basic Study on the Leak Test Method of the Hydrogen Exhaust Pipe for a Fuel Cell Vehicle (연료전지차용 수소배출 배관 및 배관이음매 안전성 평가를 위한 기초 연구)

  • Suh, Ho-Cheol;Park, Kyoung-Suk;Seo, Kyung-Doo;Yong, Gee-Joong
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.2
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    • pp.185-192
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    • 2011
  • This study deals with a basic proposal to prove the safety for the exhausted fittings of the hydrogen fuel cell vehicle. First, this study was approached to numerical analysis solving to close the exact boundary condition (Axial, Bending, Lateral) and the second, this study produced the Lateral movement equipment for the vibration. For the numerical analysis, This study was considered with the exact solution of Lateral movement and the resonance effect for durability sample according to fitting positions. The second, This study was made for special equipment for displacement/gas leak and the frequency because the domestic samples were comparing with foreign fitting and foreign fitting for the hydrogen fuel cell vehicle. The result of this study was satisfied with domestic fittings for the basic reference but it need more test because of other situation for hydrogen fuel cell vehicle.

Clinical effect of 3.0% Hydrogen peroxide bleaching patch with primer (프라이머를 이용한 3.0% 과산화수소 미백 패치의 임상효과)

  • Jin-Kyoung Kim
    • Journal of Korean Clinical Health Science
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    • v.11 no.1
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    • pp.1625-1631
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    • 2023
  • Purpose The The purpose of this study was to clinically evaluate the efficacy and safety of a self-whitening patch containing a primer containing taurine and 3.0% hydrogen peroxide. Methods A double-blind randomized clinical trial was conducted on 55 subjects. The whitening patches containing 3.0% hydrogen peroxide were applied to the labial surfaces of maxillary six anterior teeth once daily for 30 minutes using a primer, and whitening efficacy was measured by △E* values before application and at 3, 5, 7, and 10 days after application. Stability was determined using the Gingival index (GI) and visual analogue scale (VAS). Results Changes in △E* values were clinically recognizable as early as day 5 after patch application, and whitening effects were visible by day 7. There was no statistically significant difference in gingival index (p=0.069). Conclusions Self-whitening patches using primer and 3.0% hydrogen peroxide applied once daily for 30 minutes showed effective whitening effect from the 5th day after application and could be used safely without significant side effects.

Sensitivity Analysis Study of Geotechnical Factors for Gas Explosion Vibration in Shallow-depth Underground Hydrogen Storage Facility (저심도 지하 수소저장소에서의 가스 폭발 진동에 대한 지반공학적 인자들의 민감도 분석 연구)

  • Go, Gyu-Hyun;Woo, Hyeon‑Jae;Cao, Van-Hoa;Kim, Hee-Won;Kim, YoungSeok;Choi, Hyun-Jun
    • Journal of the Korean Geotechnical Society
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    • v.40 no.4
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    • pp.169-178
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    • 2024
  • While stable mid- to large-scale underground hydrogen storage infrastructures are needed to meet the rapidly increasing demand for hydrogen energy, evaluating the safety of explosion vibrations in adjacent buildings is becoming important because of gas explosions in underground hydrogen storage facilities. In this study, a numerical analysis of vibration safety effects on nearby building structures was performed assuming a hydrogen gas explosion disaster scenario in a low-depth underground hydrogen storage facility. A parametric study using a meta-model was conducted to predict changes in ground dynamic behavior for each combination of ground properties and to analyze sensitivity to geotechnical influencing factors. Directly above the hydrogen storage facility, the unit weight of the ground had the greatest influence on the change in ground vibration due to the explosion, whereas, farther away from the facility, the sensitivity of dynamic properties was found to be high. In addition, in evaluating the vibration stability of ground building structures based on the predicted ground vibration data and blasting vibration tolerance criteria, in the case of large reinforced concrete building structures, the ground vibration safety was guaranteed with a separation distance of about 10-30 m.

Adverse Effects on Crops and Soils Following an Accidental Release of Hydrogen Fluoride and Hydrofluoric Acid

  • Kang, Dae-Won;Kim, Hyuck-Soo;Kunhikrishnan, Anitha;Kim, Da-In;Lee, Seul;Park, Sang-Won;Yoo, Ji-Hyock;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.651-654
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    • 2016
  • A number of accidents relating to highly toxic hydrogen fluoride (HF) or hydrofluoric acid (HA) release have occurred over fast few decades in Korea. Thus, this study was conducted to investigate the fluoride (F) concentrations in paddy soil and brown rice from 2 different areas where the soils were exposed to HF and HA. In the first case, the HF leakage accident that occurred in 2012 affected the surrounding soils and crops and consequently, crops (rice) affected by HF were unavailable for forage even though F did not accumulate in the soil. For example, at the time of accident, F concentrations in brown rice samples were $33.0-1,395mg\;kg^{-1}$, while F concentrations in soil samples were $155-295mg\;kg^{-1}$ which were less than the Korean standard guideline values of $400mg\;kg^{-1}$. However, after a year, F concentrations in brown rice were observed below the detection limit ($1mg\;kg^{-1}$), although F concentrations in soils were similar with those in 2012. Also, large amounts of wastewater discharges containing HA occurred in 2013 and some agricultural soils exceeded the Korean standard guideline values for F ($400mg\;kg^{-1}$), but soil-plant F transfer was not observed. In conclusion, it was observed that soil to plant transfer of F is unlikely although HF and HA as gas or liquid form can cause direct damage to plants.

A Study on the Safety Job Procedures for Alkaline Water Electrolysis Facilities Based on Renewable Energy (재생에너지 기반 알칼라인 수전해설비의 안전작업절차 방안 연구)

  • Doo-Hyoun Seo;Tae-Hun Kim;Kwang-Won Rhie;Seong-Chul Hong;Hyun-Gi Kim
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.27-34
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    • 2024
  • In accordance with the clean hydrogen-centered hydrogen industry development plan, technology development and demonstration operation of water electrolysis devices are being actively carried out. Risk assessments are performed on newly developed hydrogen-using facilities and supplies to identify potential hazard factors. However, in general, most industrial accidents are caused by operator's human error or incorrect work practices. Additionally, the possibility of accidents occurring during operation control, maintenance, and inspection increases. For this reason, for equipment developed for demonstration operation, the correct work methods for the main jobs of operator must be reviewed and work procedures must be prepared. Accordingly, in this study, we conducted a job safety analysis (JSA) on major jobs in the operation of water electrolysis facilities to study safe work methods and necessary measures.

The Trends of Hydrogen Energy Technology Development and Application to Ship (수소에너지 기술 개발 현황과 선박적용 동향)

  • Han, Won-Hui;Choi, Jung-Sik;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.16 no.3
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    • pp.313-320
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    • 2010
  • Hydrogen energy begins to grab the attention as a leading alternative to solve environmental pollution and energy issue. The preparation for the hydrogen energy age is at the primary stage. But it is expected that the utilization of hydrogen energy is a feasible objective through government policy and invigoration of studies in relevant fields of industry. The preparation and research are badly in need to equip a ship with hydrogen energy engine. Some researches on ship with fuel cell are in progress, however, considering a ship that has become larger and it is being operated in special circumstances, the researches on ship with hydrogen energy engine is keenly necessary. And more concerns and supports are required in this regard.

A Study on the Quantitative Risk Assessment of Hydrogen-LPG Combined Refueling Station (수소-LPG 복합충전소 정량적 위험성평가에 관한 연구)

  • Kang, Seung Kyu
    • Journal of Energy Engineering
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    • v.28 no.4
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    • pp.29-34
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    • 2019
  • In this study, a quantitative risk assessment was carried out for a hydrogen complex station. The complex fueling station to be evaluated was hydrogen-LPG, and the components of each station were analyzed and the risk was evaluated. The final risk is assessed by individual and societal risks, taking into account the impact of damage and the frequency of accidents. As a result of individual risk calculation for the hydrogen-LPG fueling station that is the subject of this study, the hydrogen-LPG type fueling station does not show the unacceptable hazardous area (> 1 × 10E-3) proposed by HSE. The level of individual risk for both the public and the worker is within acceptable limits. In societal risk assessment, the model to be interpreted shows the distribution of risks in an acceptable range(ALARP, As Low As Reasonably Practicable). To ensure improved safety, we recommend regular inspections and checks for high-risk hydrogen reservoirs, dispensers, tube trailer leaks, and LPG vapor recovery lines.

Analysis on the Legal Control Levels and GHS Classification Information Status for Strongly Acidic Hazardous Materials (강산성 유해화학물질의 법적관리 수준 및 GHS 분류정보 제공 실태분석 연구)

  • Lee, Kwon Seob;Jo, Ji Hoon;Park, Jin Woo;Song, Se Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.4
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    • pp.384-392
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    • 2013
  • Objective: This study inspected incident cases, legal control levels, and GHS(Globally Harmonized System of Classification and Labeling of Chemicals) classification results of strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid, which have been responsible for many recent chemical accidents. As a result, it is deemed necessary for legal control levels of these strong acids to be revised and GHS classification be managed nation-wide. Methods: This study inspected incident cases and legal control levels for strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid. The study analyzed and compared chemical information status and GHS classification results. Results: There were 76 domestic incidents involving strongly acidic hazardous materials over the five years between 2007 and 2011. They include 37 leakage incidents(46.7%) within a workplace, 30 leakage incidents(39.5%) during transportation, and nine leakage incidents(13.8%) following an explosion. The strongly acidic materials in question are defined and controlled as toxic chemicals according to the classes of Substances Requiring Preparation for Accidents, Managed Hazardous Substance, Hazardous Chemical(corrosive) as set forth under the Enforcement Decree of the Toxic Chemicals Control Act and Rules on Occupational Safety and Health Standards of Occupational Safety and Health Act. Among them, nitric acid is solely controlled as a class 6 hazardous material, oxidizing liquid, under the Hazardous Chemicals Control Act. The classification results of the EU ECHA(European Chemicals Agency) CLP(Commission Regulation(EC) No. 790/2009 of 10 August 2009, for the purposes of its adaptation to technical and scientific progress, Regulation(EC) No 1272/2008 of the European Parliament and of the Council on classification, labeling and packaging of substances and mixtures) and NIER (National Institute of Environmental Research) are almost identical for the three chemicals, with the exception of sulfuric acid. Much of the classification information of NITE (National Institute of Technology and Evaluation) and KOSHA(Korea Occupational Safety and Health Agency, KOSHA) is the same. NIER provides 12(41.4%) out of 29 classifications, as does KOSHA.