• Title/Summary/Keyword: Hydrogen safety

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Theoretical Study on the Behavior of Momentum-controlled Buoyant Jet and Flame of Hydrogen (운동량에 의해 제어되는 수소 부양 제트 및 화염의 거동에 관한 이론적 해석)

  • Yang, Won;Won, Sang-Hee;Kim, Min-Kook;Chung, Suk-Ho;Kim, Jong-Soo
    • Journal of the Korean Society of Combustion
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    • v.10 no.3
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    • pp.34-41
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    • 2005
  • Hydrogen safety is one of the key technical issue with growing attention on utilization of hydrogen energy. This study is aimed to predict behavior of momentum-controlling buoyant jet and flame caused by hydrogen leakage from a high pressured tank. Approximate solutions were derived for the case of turbulent buoyant jet and diffusion flame in still air. In case of hydrogen jet with low Froude number (100-4000), computed jet trajectories were compared with experimental data and showed good agreement with them. Jet and flame trajectories and flame length of hydrogen are predicted and compared with the buoyant flame of propane. The results well show that buoyancy is dominant in the range of low Froude number, while initial momentum is dominant in the range of high Froude number. That effect is more distinct for hydrogen flame than the case of propane.

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Theoretical Study on the Behavior of Momentum-controlled Buoyant Jet and Flame of Hydrogen (운동량에 의해 제어되는 수소 부양 제트 및 화염의 거동에 관한 이론적 해석)

  • Yang, Won;Kim, Jong-Soo;Won, Sang-Hee;Kim, Min-Kook;Chung, Suk-Ho
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.207-214
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    • 2005
  • Hydrogen safety is one of the key technical issue with growing attention on utilization of hydrogen energy. This study is aimed to predict behavior of momentum-controlling buoyant jet and flame caused by hydrogen leakage from a high pressured tank. Approximate solutions were derived for the case of turbulent buoyant jet and diffusion flame in still air. In case of hydrogen jet with low Froude number (100-4000), computed jet trajectories were compared with experimental data and showed good agreement with them. Jet and flame trajectories and flame length of hydrogen are predicted and compared with the buoyant flame of propane. The results well show that buoyancy is dominant in the range of low Froude number, while initial momentum is dominant in the range of high Froude number. That effect is more distinct for hydrogen flame than the case of propane.

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Review and new trends of hydrogen gas sensor technologies (수소센서 기술의 고찰과 최근동향)

  • Han, Sang-Do
    • Journal of Sensor Science and Technology
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    • v.19 no.2
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    • pp.67-86
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    • 2010
  • Hydrogen is emerging as clean fuel and important industrial raw materials. The hydrogen gas is not sensed by the human olfactory system, But the combustion characteristics of hydrogen is that the ignition is very easy, the propagation speed of the flame is very fast and explosion limits is a wide range of 4 %~75 %. Therefore it is extremely in danger, and the need for its leakage detection technologies is especially important in places such as a production, transportation, storage and usage. The hydrogen sensors are classified with ceramic type, semiconductor type, optical type, electrochemical type and so on. Hydrogen sensors and their technologies are reviewed in detail for materials, fabrication process, sensing characteristics, good point and faults, and production and utilization of sensors be discussed.

CFD analysis of the effect of different PAR locations against hydrogen recombination rate

  • Lee, Khor Chong;Ryu, Myungrok;Park, Kweonha
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.2
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    • pp.112-119
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    • 2016
  • Many studies have been conducted on the performance of a passive autocatalytic recombiner (PAR), but not many have focused on the locations where the PAR is installed. During a severe accident in a nuclear reactor containment, a large amount of hydrogen gas can be produced and released into the containment, leading to hydrogen deflagration or a detonation. A PAR is a hydrogen mitigation method that is widely implemented in current and advanced light water reactors. Therefore, for this study, a PAR was installed at different locations in order to investigate the difference in hydrogen reduction rate. The results indicate that the hydrogen reduction rate of a PAR is proportional to the distance between the hydrogen induction location and the bottom wall.

Large Eddy Simulation for the Prediction of Unsteady Dispersion Behavior of Hydrogen Fluoride (불산의 비정상 확산거동 예측을 위한 대와동모사)

  • Ko, M.W.;Oh, Chang Bo;Han, Y.S.;Choi, B.I.;Do, K.H.;Kim, M.B.;Kim, T.H.
    • Journal of the Korean Society of Safety
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    • v.30 no.1
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    • pp.14-20
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    • 2015
  • A Large Eddy Simulation(LES) was performed for the prediction of unsteady dispersion behavior of hydrogen fluoride (HF). The HF leakage accident occurred at the Gumi fourth industrial complex was numerically investigated using the Fire Dynamics Simulator (FDS) based on the LES. The accident area was modeled three-dimensionally and time-varying boundary conditions for wind were adopted in the simulation for considering the realistic accident conditions. The Message Passing Interface (MPI) parallel computation technique was used to reduce the computational time. As a result, it was found that the present LES simulation could predict the unsteady dispersion features of HF near the accident area effectively. The dispersion behaviors of the leaked HF was much affected by the unsteady wind direction. The LES could predict the time variation of the HF concentration reasonably and give an useful information for the risk analysis while the prediction with the time-averaging concept of HF concentration had a limitation for the amount of HF concentration at specific location point. It was identified that the LES is very useful to predict the dispersion characteristics of hazardous chemicals.

An Empirical Evaluation of Safety of the Common Vent Structure for Stationary Fuel Cell Systems (건물용 연료전지 복합배기구조 안전 실증평가)

  • LEE, EUN-KYUNG;LEE, JUNG-WOON;MOON, JONG-SAM;LEE, SEONG-HEE;SHIN, DONG-HUN
    • Journal of Hydrogen and New Energy
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    • v.29 no.6
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    • pp.596-605
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    • 2018
  • Interest in hydrogen, as an energy carrier, has been growing to solve the problems on shortage of fossile fuels and greenhouse gas. According to the standard KGS FU 551 for stationary fuel cell installation, the fuel cell system could be connected up to two common exhausts to one floor. depending on the required power for building or the installation environment in buildings, multiple fuel cell systems could be installed. Afterwards the number of perforations and flues could be decided. Hence, economic efficiency in significantly determined with respect to installation area and the number of fuel cell systems. In addition, the complexity of common vent structure for stationary fuel cell systems could be changed. In this paper, Verification experiments were conducted by connecting the common exhaust system to the fuel cell simulation system and the actual fuel cell system. Humidity and temperature were changed at ON/OFF, but no factors were found to affect performance or system malfunction. Exhaust emissions were also measured to obtain optimized values. We intend to expand the diffusion of stationary fuel cells by verifying safety of common exhaust structure.

A Case Study on the Risk Analysis for the Installation of Measurement Error Verification Facility in Hydrogen Refueling Station (수소 충전소 계량오차 검증 설비 설치를 위한 위험성 분석 사례 연구)

  • Hwayoung, Lee;Hyeonwoo, Jang;Minkyung, Lee;Jeonghwan, Kim;Jaehun, Lee
    • Journal of the Korean Institute of Gas
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    • v.26 no.6
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    • pp.30-36
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    • 2022
  • In commercial transactions of energy sources using hydrogen charging stations, high-accuracy flow meters are needed to prevent accidents such as overcharging due to inaccurate measurements and to ensure transparency in hydrogen commercial transactions through accurate measurements. This research developed a Corioli-type flowmeter prototype and conducted a risk assessment to prevent accidents during a process change comparison experiment for existing charging stations to verify the measurement performance. A process change section was defined for the installation of measurement facilities for empirical experiments and HAZOP was conducted. In addition, JSA was also conducted to secure the safety of experimenters, such as preventing valve mis-opening during empirical experiments. Measures were established to improve the risk factors derived through HAZOP, and work procedures were established to minimize human errors and ensure the safety of workers through JSA. The design change and system manufacturing for the installation of the metering system were completed by reflecting the risk assessment results, and safety could be confirmed through the performance comparison test of the developed meter prototype. The developed prototype flow meter showed a total of 30 flow measurements under the operating conditions of 70 MPa, and the average error was -1.58% to 3.96%. Such a metering error was analyzed to have the same performance as a flow meter installed and operated for commercial use.

A Study on the Risk Assessment for Strengthening Management Safety of Hydrogen Fueling Station (수소충전소의 경영안전성 강화를 위한 위험성평가 추가 항목 연구)

  • Lee, Jang Won;Kim, Chang Soo
    • Journal of the Society of Disaster Information
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    • v.18 no.3
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    • pp.520-531
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    • 2022
  • Purpose: Based on the risk evaluation of hydrogen fueling stations, this study aims to find a plan to strengthen management safety by examining profitability and management risk, which are major concerns of employers. Method: The risk evaluation was divided into 'acceptable risk' and 'allowable risk' over time from the stage of installation of hydrogen fueling stations, and compared and analyzed with the results of existing studies. Result: Existing studies have been appropriately applied to the risk assessment performed at the stage of installing hydrogen fueling stations. However, possible risks could be found at the operational stage. In other words, it was derived that an evaluation of management risk was also necessary. And through this, it was confirmed that the safety of hydrogen fueling stations was strengthened. Conclusion: The risk assessment that precedes the stage of installing hydrogen fueling stations is appropriate because significant results have been derived from the 'acceptable risk' assessment. However, the operator needs to evaluate the risks that may occur at the operating stage, that is, the 'allowable risks' and prepare countermeasures. Therefore, it is proposed to add management risk assessment items to build and operate safer hydrogen fueling stations.

A Study on the Selection of Hydrogen Refueling Station Locations within Military Bases Considering Minimum Safe Distances between Adjacent Buildings (인접 건물 간 최소 안전거리를 고려한 군부대 내 수소충전소 위치선정 연구)

  • Dong-Yeon Kim;Hyuk-Jin Kwon
    • Journal of Internet Computing and Services
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    • v.24 no.6
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    • pp.171-180
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    • 2023
  • Hydrogen energy technology is gaining importance in the era of the Fourth Industrial Revolution, offering military advantages when applied to military vehicles due to its characteristics such as reduced greenhouse gas emissions, noise, and low vibration. Korea's military has initiated the Army Tiger 4.0 plan, focusing on hydrogen application, downsizing, and AI-based smart features. The Ministry of National Defense plans to collaborate with the Ministry of Environment to expand hydrogen charging stations nationwide, anticipating increased deployment of military hydrogen vehicles. However, considering the Jet Fire and VCE(Vapor Cloud Explosion) nature of hydrogen, ensuring safety during installation is crucial. Current military guidelines specify a minimum safety distance of 2m from adjacent buildings for charging stations. Scientific methods have been employed to quantitatively assess the accident damage range of hydrogen, proposing a minimum safety distance beyond the affected area.

Characteristics of Chemical Reaction and Ignition Delay of $H_2$/Air/HFP Mixtures (수소/공기/HFP 혼합기의 화학반응 및 점화지연 특성)

  • Lee, Eui-Ju;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.25 no.1
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    • pp.17-21
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    • 2010
  • The chemistry and ignition delay of hydrogen/air/HFP premixed mixtures was investigated numerically with unsteady perfectly stirred reactor(PSR). The detailed chemistry of 93 species and 817 reaction mechanism was introduced for hydrogen/air/HFP mixtures. The results shows the temporal concentration variations of major or reactants such as hydrogen and oxygen during autoignition were similar to the spatial distribution of premixed flame while water vapor produced at the ignition temperature was decomposed later, which can be clarified with the relate species production rates that the the re-growth (or shoulder) of OH concentration is a result of F radicals attacking $H_20$ forming OH and HF. For the stoichiometric $H_2$/air mixture inhibited by 20% HFP, HFP thermal decomposition reaction prevails over the radical attack such as H at initial stage. Even though relatively large HFP addition contributes to delay the ignition, chemical effect on the ignition delay is not effective because of late thermal decomposition of HFP. The most small ignition delay was observed at a slightly fuel lean condition ($\phi$ = 0.9), and temperature dependency of ignition delay was clearly shown near 900 K.