• Title/Summary/Keyword: Hydrogen safety

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The Strategy Plans for Practical use of Hydrogen Fueled Vehicles in Domestic (국내의 수소 자동차 실용화를 위한 전략 방안)

  • Lee, Kwang-Ju;Lee, Jong-Tae;Yong, Gee-Joong
    • Journal of Hydrogen and New Energy
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    • v.21 no.4
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    • pp.346-353
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    • 2010
  • Hydrogen fueled vehicle was evaluated as one of the next-generation technology that will be able to solve the global warming, depletion of fossil fuel and etc. The practical use of hydrogen fueled vehicle, nevertheless, is being delayed more than expected schedule due to various causes. In order to promote the dissemination of hydrogen fueled vehicle, development status and obstacle factors of practical use for hydrogen fueled vehicles were reviewed and the strategy plans for dissemination promotion were proposed. Hydrogen fueled vehicles are included the hydrogen fuel cell, neat and enriched hydrogen fueled engines. The technicalness, economy, safety, cognizance, system, support and etc were considered in the strategy plans.

A optimization study on the preparation and coating conditions on honeycomb type of Pd/TiO2 catalysts to secure hydrogen utilization process safety (수소 활용공정 안전성 확보를 위한 Pd/TiO2 수소 상온산화 촉매의 제조 및 허니컴 구조의 코팅 조건 최적화 연구)

  • Jang, Young hee;Lee, Sang Moon;Kim, Sung Su
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.47-54
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    • 2021
  • In this study, the performance of a honeycomb-type hydrogen oxidation catalyst to remove hydrogen in a hydrogen economy society to secure leaking hydrogen. The Pd/TiO2 catalyst was prepared based on a liquid phase reduction method that is not exposed to a heat source, and it was showed through H2-chemisorption analysis that it existed as very small active particles of 2~4 nm. In addition, it was found that the metal dispersion decreased and the active particle size increased as the reduction reaction temperature increased. It was meant that the active metal particle size and the hydrogen oxidation performance were in a proportional correlation, so that it was consistent with the hydrogen oxidation performance reduction result. The prepared catalyst was coated on a support in the form of a honeycomb so that it could be applied to the hydrogen industrial process. When 20 wt% or more of the AS-40 binder was coated, oxidation performance of 90% or more was observed under low-concentration hydrogen conditions. It was showed through SEM analysis that long-term catalytic activity can be expected by enhancing the adhesion strength of the catalyst and preventing catalyst desorption. It is a basic research that can secure safety in a hydrogen society such as gasification, organic resource, and it can be utilized as a system that can respond to unexpected safety accidents in the future.

Assessment of Thermal Protection Performance of Firefighting Garments for Hydrogen Jet Fire (수소제트화재에 대한 특수 방화복의 열 방호 성능시험 평가)

  • UNGGI YOON;BYOUNGJIK PARK;YANGKYUN KIM;SUNGWOOK KANG;OHKKUN LIM
    • Journal of Hydrogen and New Energy
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    • v.35 no.3
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    • pp.310-317
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    • 2024
  • In this study, Aimed to develop technology to ensure the safety of firefighters responding to hydrogen incidents and to review the performance of protective super absorbent polymer (SAP) that could help maintain the thermal protection performance of equipment with protective properties. Tests were conducted, including bench-scale and full-scale thermal exposure tests, to review the protective performance of SAP using firefighting garments commonly used by firefighters. The results showed that without SAP application, 2nd degree burn areas were measured at 9.4%, and 3rd degree burn areas at 7.7%. In contrast, when SAP was applied, the percentage of 2nd degree burn areas decreased to 7% on the lower body, and there was no temperature rise causing 3rd degree burns. Therefore, it is expected that by applying SAP to the outer surface of firefighter garments, even under temporarily high temperature conditions such as hydrogen jet flames, thermal damage to firefighters could be protected for a certain period.

A Study on Influence of Fuel Cell Performance by Hydrogen Odorant (수소가스 부취제가 연료전지의 성능에 미치는 영향 연구)

  • Han, Sang-Won;Oh, Seok-Hwan;Kim, Young-Gyu;Lee, Sung-Hun;Chae, Jae-Ou
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.491-494
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    • 2008
  • The hydrogen fuel and fuel cell which have high energy efficiency and low pollutant emission are getting interest as an alternative energies due to the fossil fuel exhaust, green house effect and atmospheric pollutant problems. The hydrogen gas is very effective as an alternative energy. But, if it is leaked into the air it forms the mixed gas with the air then the danger of the explosion is risen up. So, the secure the safety is mostly important. In this research, to detect the leakage of the hydrogen rapidly, added the odorant materials which don't include the sulfur component into the hydrogen gas and researched on the effect of each odorant on the performance of the fuel cell. As the results, setting the cumulation electric power on the basis and comparing the pure hydrogen, 2,3-Butanedione 5ppm mixed gas 86.1%, 5-Ethylidene-2-Norbornene 17ppm mixed gas 88.2%, Isovaleraldehyde 10ppm mixed gas 74.8%, Ethyl Isobutyrate 2.2ppm mixed gas 93.5% of performance was shown.

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Investigation of a Hydrogen Mitigation System During Large Break Loss-Of-Coolant Accident for a Two-Loop Pressurized Water Reactor

  • Dehjourian, Mehdi;Sayareh, Reza;Rahgoshay, Mohammad;Jahanfarnia, Gholamreza;Shirani, Amir Saied
    • Nuclear Engineering and Technology
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    • v.48 no.5
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    • pp.1174-1183
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    • 2016
  • Hydrogen release during severe accidents poses a serious threat to containment integrity. Mitigating procedures are necessary to prevent global or local explosions, especially in large steel shell containments. The management of hydrogen safety and prevention of over-pressurization could be implemented through a hydrogen reduction system and spray system. During the course of the hypothetical large break loss-of-coolant accident in a nuclear power plant, hydrogen is generated by a reaction between steam and the fuel-cladding inside the reactor pressure vessel and also core concrete interaction after ejection of melt into the cavity. The MELCOR 1.8.6 was used to assess core degradation and containment behavior during the large break loss-of-coolant accident without the actuation of the safety injection system except for accumulators in Beznau nuclear power plant. Also, hydrogen distribution in containment and performance of hydrogen reduction system were investigated.

Analysis of Characteristics of Spent Fuels on Long-Term Dry Storage Condition

  • Yoon, Suji;Park, Kwangheon;Yun, Hyungju
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.205-214
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    • 2021
  • Currently, the interim storage pools of spent fuels in South Korea are expected to become saturated from 2024. It is required to prepare an operation plan of a domestic dry storage facility during a long-term period, with the researches on safety evaluation methods. This study modified the FRAPCON code to predict the spent fuel integrity evaluation such as the axial cladding temperature, the hoop stress and hydrogen distribution in dry storage. The cladding temperature in dry storage was calculated using the COBRA-SFS code with the burnup information which was calculated using the FRAPCON code. The hoop stress was calculated using the ideal gas equation with spent fuel information such as rod internal pressure. Numerical analysis method was used to calculate the degree of hydrogen diffusion according to the hydrogen concentration and temperature distribution during a dry storage period. Before 50 years of dry storage, the cladding temperature and hoop stress decreased rapidly. However, after 50 years, they decreased gradually and the cladding temperature was below 400 K. The initial temperature distribution and hydrogen concentration showed a parabolic line, but hydrogen was transferred by the hydrogen concentration and temperature gradient over time.

Optimization of Designing Barrier to Mitigate Hazardous Area in Hydrogen Refueling Stations (수소충전소 폭발위험장소 완화를 위한 확산차단벽 최적화 설계)

  • SEUNGHYO AN;SEHYEON OH;EUNHEE KIM;JUNSEO LEE;BYUNGCHOL MA
    • Journal of Hydrogen and New Energy
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    • v.34 no.6
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    • pp.734-740
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    • 2023
  • Hydrogen emphasis on safety management due to its high potential for accidents from wide explosive limits and low ignition energy. To prevent accidents, appropriate explosion-proof electrical equipment with installed to safe management of ignition sources. However, designing all facilities with explosion-proof structures can significantly increase costs and impose limitations. In this study, we optimize the barrier to effectively control the initial momentum in case of hydrogen release and form the control room as a non-hazardous area. We employed response surface method (RSM), the barrier distance, width and height of the barrier were set as variables. The Box-Behnken design method the selection of 15 cases, and FLACS assessed the presence of hazardous area. Analysis of variance (ANOVA) analysis resulting in an optimized barrier area. Through this methodology, the workplace can optimize the barrier according to the actual workplace conditions and classify reasonable hazardous area, which is believed to secure safety in hydrogen facilities and minimize economic burden.

Analyzing Effective Factors on Hydrogen Release Based on Response Surface Method and Analysis of Variance (반응표면법과 ANOVA 기반의 수소 누출에 대한 유효인자 분석)

  • JUNSEO LEE;SEHYEON OH;SEUNGHYO AN;EUNHEE KIM;BYUNGCHOL MA
    • Journal of Hydrogen and New Energy
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    • v.34 no.6
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    • pp.712-721
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    • 2023
  • While hydrogen is widely used, it has a low minimum ignition energy, raising safety concerns when using it. This research studied which parameters are the key variables in the hydrogen release and diffusion. These parameters were divided into six process variables in the initial release and two environmental variables in the dispersion. One hundred and twenty cases were selected through design of experiment, and the end-point in each case were analyzed using PHAST. Afterwards, an end-point prediction model was developed using RSM and ANOVA, and the impact of each variable on the endpoint was analyzed. As a result, the influence of eight variables was graded. The nozzle diameter had the greatest influence on the end-point, while the pipe roughness coefficient had no effect on the end-point. It is expected that these results will be used as basic data to improve safety across all fields of hydrogen handling facilities.

A Study on Implementation Plan of Clean Hydrogen Certification System (청정수소 인증제 시행방안 연구)

  • RHEE, HAN WOO;KIM, JIN HO
    • Journal of Hydrogen and New Energy
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    • v.33 no.4
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    • pp.301-308
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    • 2022
  • The Hydrogen Economy Promotion and Hydrogen Safety Management Act (hereinafter referred to as the "Hydrogen Economy Act") stipulates matters related to certification and cancellation of clean hydrogen by grade, and requires those who produce, import, or sell clean hydrogen to report to the Minister of Trade, Industry and Energy. In order for this system to operate smoothly, the clean hydrogen Certification system must be designed to meet international standards, and the institution operating the System must have appropriate capabilities and foundations. The clean hydrogen certification system should serve as an opportunity for Korea's domestic energy industry to take a leap forward.

Strength Safety Evaluation of Composite Pressure Container for Hydrogen Fuel Tanks (수소연료탱크용 복합소재 압력용기에 관한 강도안전성 평가연구)

  • Kim, Chung-Kyun;Kim, Do-Hyun
    • Journal of the Korean Institute of Gas
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    • v.15 no.1
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    • pp.30-34
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    • 2011
  • This paper presents a strength safety evaluation of composite pressure container for hydrogen fuel tanks with a storage capacity of 104 liter and 70MPa pressure. The carbon fiber composite container is manufactured by an aluminum liner of Al6061-T6 and composite multi-layers of hoop winding layer in circumferential direction, $12^{\circ}C$ inclined winding layer and $70^{\circ}C$winding layer in helical direction respectively. The FEM results on the strength safety of composite fuel tanks were evaluated with a criterion of design safety of US DOT-CFFC and KS B ISO 11119-2 codes. The FEM computed results indicate that the proposed design model of 104 liter composite container is safe based on two strength safety codes. But, the computed results of carbon fiber fuel tanks based on US DOT-CFFC code is safer compared with that of KS B ISO 11119-2. Thus the hydrogen gas pressure container of 70MPa may be evaluated and designed by US DOT-CFFC code for more strength safety.