• Transactions of the Korean hydrogen and new energy society
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• v.34 no.4
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• pp.381-387
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• 2023

The risk assessment (safety assessment) must be performed to verify the risks during operation and installation of the hydrogen system and to ensure safe design and operation. Among them, hazard and operability study (HAZOP), a qualitative risk assessment, is most often used to discover risk factors and secure safety. However, in HAZOP performance, there is a difference in the level of evaluation results depending on the level and experience of the evaluator, and there is a high possibility that subjective results will be derived. This study aims to develop a risk factor library that can list and provide information on potential risk factors in order to solve these problems when performing HAZOP, reduce risk factors that are omitted or overlooked.

• Journal of the Korean Institute of Gas
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• v.25 no.6
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• pp.53-65
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• 2021

While the hydrogen refueling station is rapidly expanded and installed, the safety inspection of the hydrogen pressure vessel in the station should be very important. Of these, according to ASME, hydrogen embrittlement tests must be performed for hydrogen vessel that store hydrogen above a certain pressure. The main test method for hydrogen embrittlement inspection is to carry out fracture tests and fatigue fracture tests in a high pressure hydrogen atmosphere, which allows the durability limit of the pressure vessel to be measured and the endurable limit to be determined in the hydrogen atmosphere. In detail, the critical crack depth can be calculated by the stress intensity factor(K), and the service life can be determined by da/dN (fatigue growth rate). API579-1/ ASME FFS-1 part 9 exemplifies the calculation method according to the mode of crack-like flaws, but for various shapes such as plates and cylinders, there are about 55 modes according to the shape and location of the crack. Due to the fairly complex formula, it is not easily accessible. In this study, we will show you how to calculate fracture mechanics numerically via Excel and VBA. In addition, this was applied to analyze the effects of the thickness and inner diameter of the pressure vessel on the service life.

• International Journal of Safety
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• v.6 no.2
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• pp.1-7
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• 2007

In this study mechanical strength of A53B carbon steel was analyzed using several types of test specimens directly machined from oil recycling pipe experienced a failure due to hydrogen attack in chemical plants. High temperature hydrogen attack (HTHA) is the damage process of grain boundary facets due to a chemical reaction of carbides with hydrogen, thus forming cavities with high pressure methane gas. Driven by the methane gas pressure, the cavities grow on grain boundaries forming intergranular micro cracks. Microscopic optical examination, tensile test, Charpy impact test, hardness measurement, and small punch (SP) test were performed. Carbon content of the hydrogen attacked specimens was dramatically reduced compared with that of standard specification of A53B. Traces of decarburization and micro-cracks were observed by optical and scanning electron microscopy. Charpy impact energy in hydrogen attacked part of the pipe exhibited very low values due to the decarburization and micro fissure formation by HTHA, on the other hand, data tested from the sound part of the pipe showed high and scattered impact energy. Maximum reaction forces and ductility in SP test were decreased at hydrogen attacked part of the pipe compared with sound part of the pipe. Finite element analyses for SP test were performed to estimate tensile properties for untested part of the pipe in tensile test. And fracture toughness was calculated using an equivalent strain concept with SP test and finite element analysis results.

• Journal of computational fluids engineering
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• v.17 no.3
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• pp.75-86
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• 2012

We developed a preliminary CFD analysis methodology to predict a pressure build up due to hydrogen flame acceleration in the APR1400 IRWST on the basis of CFD analysis results for test data of hydrogen flame acceleration in a scaled-down test facility performed by Korea Atomic Energy Research Institute. We found out that ANSYS CFX-13 with a combustion model of the so-called turbulent flame closure and a model constant of A = 5.0, a grid model with a hexahedral cell length of 5.0 mm, and a time step size of $1.0{\times}10^{-5}$ s can be a useful tool to predict the pressure build up due to the hydrogen flame acceleration in the test results. Through the comparison of the simulated results with the test results, we found out that the proposed CFD analysis methodology enables us to predict the peak pressure within an error range of about ${\pm}29%$ for the hydrogen concentration of 19.5%. However, the error ranges of the peak pressure for the hydrogen concentration of 15.4% and 18.6% were about 66% and 51%, respectively. To reduce the error ranges in case of the hydrogen concentration of 15.4% and 18.6%, some uncertainties of the test conditions should be clarified. In addition, an investigation for a possibility of flame extinction in the test results should be performed.

• Journal of the Korean Institute of Gas
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• v.26 no.3
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• pp.38-44
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• 2022

As the supply of hydrogen charging stations for hydrogen supply accelerates due to the hydrogen economy revitalization policy, the risk of accidents is also increasing. Since most hydrogen explosion accidents lead to major accidents, it is very important to secure safety when using hydrogen energy. In order to utilize hydrogen energy, it is essential to secure the safety of hydrogen storage containers used for production, storage, and transportation of liquid hydrogen. In this paper, in order to evaluate the structural safety of a hydrogen-filled pressure vessel, the behavioral characteristics of gas pressure were analyzed by finite element analysis. SA-372 Grade J / Class 70 was used for the material of the pressure vessel, and a hexahedral mesh was applied in the analysis model considering only the 1/4 shape because the pressure vessel is axisymmetric. A finite element analysis was performed at the maximum pressure using a hydrogen gas pressure vessel, and the von Mises stress, deformation, and strain energy density of the vessel were observed.

• Journal of the Korean Society of Safety
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• v.25 no.2
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• pp.12-17
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• 2010

Numerical simulations were performed for the prediction of the flame structure during the interaction between hydrogen and hydrocarbon flames. A counterflow flow geometry was introduced to establish the interacting two flames. Methane was used as a representative hydrocarbon fuel in this study. A well-known numerical code for the counterflow flame, OPPDIF, was used for the simulations. The detailed chemistry was adopted to predict the flame structure reasonably. The interaction of two one-dimensional premixed flames established in counterflow burner was investigated with the global strain rate and velocity ratio. It was found that the maximum temperature located near the methane flame surface while the heat release rate of methane was lower than hydrogen flame. The flame thickness become narrow with increasing the velocity ratio while the global strain rate was fixed. The local strain rate and heat release rate at the methane flame surface were correlated with the global strain rate, while those at the hydrogen flame were not correlated with the global strain rate. However, the maximum temperature of the interacting flames was correlated with the global strain rate.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.57-62
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• 2021

In this study, risk assessment was conducted in case of leakage of storage facilities (tube trailer) using the HyKoRAM program developed through international joint research. The high-pressure gas facilities in the hydrogen filling station are divided into four main categories: storage facilities (tube trailers), processing facilities (compressors), compressed gas facilities, and filling facilities (dispensers). Among them, the design specifications of the tube trailer, which is a storage facility, and the surrounding environmental conditions were reflected to construct an accident scenario with previously occurring accidents and potential accidents. Through this, we identify the risks of storage facilities at hydrogen refueling stations and suggest measures to improve the safety of hydrogen charging stations.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.1
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• pp.73-81
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• 2020

For the fault tree analysis (FTA) analysis of the packaged hydrogen filling station, the composition of the charging station was analyzed and the fault tree (FT) diagram was prepared. FT diagrams were created by dividing the causes of events into external factors and internal factors with the hydrogen event as the top event. The external factors include the effects of major disasters caused by natural disasters and external factors as OR gates. Internal factors are divided into tube tailer, compressor & storage tank, and dispenser, which are composed of mistakes in operation process and causes of accidents caused by parts leakage. In this study, the purpose was to improve the hydrogen station. The subjects of this study were domestic packaged hydrogen stations and FTA study was conducted based on the previous studies, failure mode & effect analysis (FMEA) and hazard & operability study (HAZOP). Top event as a hydrogen leaking event and constructed the flow of events based on the previous study. Refer to "Off shore and onshore reliability data 6th edition", "European Industry Reliability Data Bank", technique for human error rate prediction (THERP) for reliability data. We hope that this study will help to improve the safety and activation of the hydrogen station.

• Journal of the Korean Society of Safety
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• v.34 no.5
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• pp.7-14
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• 2019

The type III vessel, which is used to store high-pressure hydrogen gas, is made by wrapping the vessel's liner with carbon fiber composite materials for strength performance and lightening. The liner seals the internal gas and the composite resists the internal pressure. The properties of the fiber composite material depends on the angle and thickness of the fiber. Thus, engineers should consider these various design variables. However, it significantly increases the design cost due to the trial and error under designing based on experience or experiments. And, for aluminum liners, fatigue loads due to using and charging could give a huge impact on the performance of the structure. However, fatigue failure does not necessarily occur in the position under the highest load in use. Therefore, for hydrogen storage vessel, fatigue evaluation according to design patterns is essential because stress distribution varies depend on composite layer patterns. This study performed an optimization analysis and evaluated a high-pressure hydrogen storage vessel to minimize these trial and error and improve the reliability of the structure, while simultaneously conducting fatigue assessment of all patterns derived from the optimization analysis process. The results of this study are thought to be useful in the strength improvement and life design of composite reinforced high-pressure storage vessels.

• Journal of the Korean Society of Marine Environment & Safety
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• v.29 no.1
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• pp.76-85
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• 2023

Demand for hydrogen as a renewable energy resource is increasing. However, unlike conventional fossil fuels, hydrogen requires a dedicated refueling station for fuel supply. A risk assessment of hydrogen refueling stations must be undertaken to secure the infrastructure. Therefore, in this study, a risk assessment for hydrogen refueling stations was conducted through both qualitative and quantitative risk assessments. For the qualitative evaluation, the hydrogen dispenser module was evaluated as two nodes using the hazard and operability (HAZOP) analysis. The risk due to filter clogging and high-pressure accidents was evaluated to be high according to the criticality estimation matrix. For the quantitative risk assessment, the Hydrogen Korea Risk Assessment Module (Hy-KoRAM) was used to indicate the shape of the fire and the range of damage impact, and to evaluate the individual and social risks. The individual risk level was determined of to be as low as reasonably practicable (ALARP). Additional safety measures proposed include placing the hydrogen refueling station about 100m away from public facilities. The social risk level was derived as 1E-04/year, with a frequency of approximately 10 deaths, falling within the ALARP range. As a result of the qualitative and quantitative risk assessments, additional safety measures for the process and a safety improvement plan are proposed through the establishment of a restricted area near the hydrogen refueling station.