• Journal of Hydrogen and New Energy
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• v.33 no.6
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• pp.692-698
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• 2022

With the expansion of domestic hydrogen fuelling station infrastructure, it is necessary to secure reliability among hydrogen traders, and for this, technology to accurately measure hydrogen is important. In this study, 4 types of hydrogen trading volume calculation models (model 1-4) were presented to improve the accuracy of the hydrogen trading volume. In order to obtain the reference value of model 4, and experiment was conducted using a flow rate measurement equipment, and the error rate of the calculated value for each model was compared and analyzed. As a result, model 1 had the lowest metering accuracy, model 2 had the second highest metering accuracy and model 3 had the highest metering accuracy until a certain point. But after the point, model 2 had the highest metering accuracy and model 3 had the second metering accuracy.

• Journal of Hydrogen and New Energy
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• v.34 no.2
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• pp.162-168
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• 2023

The fast refueling process of compressed hydrogen has an important impact on the filling efficiency and safety. With the development and use of hydrogen energy, the demand for precision measurement of filling hydrogen thermodynamic parameters is also increasing. In this paper, the compressibility factor calculation model of high-pressure hydrogen gas was studied, and the basic equation of state and thermo-physical parameters were calculated. The hydrogen density data provided by the National Institute of Standards and Technology was compared with the calculation results of each model. Results show that at a pressure of 0.1-100 MPa and a temperature of 233-363 K, the calculation accuracy of the Zheng-Li equation of state was less than 0.5%. In the range of 0.1-70 MPa, the accuracy of Redich-Kwong equation is less than 3%. The hydrogen pressure more influences on the compressibility factor than the hydrogen temperature does. Using the Zheng-Li equation of state to calculate the compressibility factor of on-board high pressure hydrogen can obtain high accuracy.

• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.507-511
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• 2019

Hydrogen permeability is widely used to evaluate the polymer membrane durability of polymer electrolyte fuel cells (PEMFC). Linear sweep voltammetry (LSV) is mainly used to measure hydrogen permeability easily. There are many differences in LSV measurement method among researchers, and it is often difficult to compare the results. Therefore, in this study, we tried to confirm the accuracy by comparing the hydrogen permeability of LSV method and gas chromatograph which is difficult to measure but accurate value. The LSV method used the DOE and NEDO methods. When the hydrogen permeability was measured by varying the temperature and the relative humidity, the DOE LSV method showed an accuracy of less than 5% in the error range compared with the GC method. In the NEDO LSV method, the error was reduced when the hydrogen permeation current density was determined at the current value of 0.3 V as the DOE method.

• 연구논문집
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• s.31
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• pp.149-156
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• 2001

Hydrogen damage affects carbon steel tubes in many fossil-fuel-fired boilers, often causing large tube ruptures that necessitate an immediate shutdown. Therefore, equipment handling high-temperature, high-pressure hydrogen must undergo careful periodic inspection because of its susceptibility to hydrogen attack. This paper describes the application of an ultrasonic technique for detecting the presence of hydrogen damage in utility boiler tubes. The accuracy of the technique has been shown in laboratory tests. However, it is difficult to evaluate hydrogen attack quantitatively by this technique, because ultrasonic wave is influenced by the test conditions and the material itself.

• Journal of Hydrogen and New Energy
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• v.33 no.6
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• pp.684-691
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• 2022

Hydrogen fuel cell electric vehicles are typically refueled at a wide range of temperatures (-40℃ to 85℃) in the hydrogen refueling station in accordance with the worldwide accepted standard. Currently, there is no traceable method by which to verify and calibrate the hydrogen flowmeters to be used at hydrogen refueling stations except for a water calibration process as a conventional method. KRISS hydrogen field test standard based on the gravimetric principle was developed to verify the measurement accuracy of the mass flowmeter to be used at hydrogen refueling stations for the first time in Korea.

• Korean Journal of Materials Research
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• v.27 no.3
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• pp.127-131
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• 2017

Isosteric heat of hydrogen adsorption is one of the most important parameters required to describe solid-state hydrogen storage systems. Typically, it is calculated from adsorption isotherms measured at 77K (liquid N2) and 87K (liquid Ar). This simple calculation, however, results in a high degree of uncertainty due to the small temperature range. Therefore, the original Sievert type setup is upgraded using a heating and cooling device to regulate the wide sample temperature. This upgraded setup allows a wide temperature range for isotherms (77K ~ 117K) providing a minimized uncertainty (error) of measurement for adsorption enthalpy calculation and yielding reliable results. To this end, we measure the isosteric heats of hydrogen adsorption of two prototypical samples: activated carbon and metal-organic frameworks (e.g. MIL-53), and compared the small temperature range (77~87K) to the wide one (77K ~ 117K).

• Journal of Hydrogen and New Energy
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• v.28 no.6
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• pp.729-737
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• 2017

The measurement accuracy of Tunable Diode Laser Absorption Spectroscopy based Tomography (TDLAST) for the temperature and concentration fields are dependant upon the arrangement method of the used laser beams. This paper reports on the optimization of laser beam arrangements using phantom data. It has been verified that the measurement error of the TDLAST decreased with increase of laser beam numbers. Further, it has been confirmed that perpendicular arrangements between the horizontal and the vertical laser beams without additional diagonal laser beams shows the minimum measurement errors.

• Korean Journal of Materials Research
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• v.29 no.5
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• pp.336-341
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• 2019

The gas adsorption isotherm requires accurate measurement for the analysis of porous materials and is used as an index of surface area, pore distribution, and adsorption amount of gas. Basically, adsorption isotherms of porous materials are measured conventionally at 77K and 87K using liquid nitrogen and liquid argon. The cold volume calibration in this conventional method is done simply by splitting a sample cell into two zones (cold and warm volumes) by controlling the level sensor in a Dewar filled with liquid nitrogen or argon. As a result, BET measurement for textural properties is mainly limited to liquefied gases (i.e. $N_2$ or Ar) at atmospheric pressure. In order to independently investigate other gases (e.g. hydrogen isotopes) at cryogenic temperature, a novel temperature control system in the sample cell is required, and consequently cold volume calibration at various temperatures becomes more important. In this study, a cryocooler system is installed in a commercially available BET device to control the sample cell temperature, and the automated cold volume calibration method of temperature variation is introduced. This developed calibration method presents a reliable and reproducible method of cryogenic measurement for hydrogen isotope separation in porous materials, and also provides large flexibility for evaluating various other gases at various temperature.

• Journal of Hydrogen and New Energy
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• v.27 no.2
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• pp.236-243
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• 2016

This paper presents a simple thermo-physical model of reciprocating compressors for household refrigerator-freezers. The compressor model has been developed based on thermodynamic principles and large data sets from the compressor calorimeter tests. The input data are compressor geometry (displacement and clearance volume), compressor speed, suction pressure and temperature, discharge pressure, and ambient temperature. The model can estimate mass flow rate and compressor power consumption within 3.0% accuracy, which is not much larger than measurement errors associated with calorimeter testing under ideal conditions.

• Journal of the Korean Institute of Gas
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• v.26 no.6
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• pp.30-36
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• 2022

In commercial transactions of energy sources using hydrogen charging stations, high-accuracy flow meters are needed to prevent accidents such as overcharging due to inaccurate measurements and to ensure transparency in hydrogen commercial transactions through accurate measurements. This research developed a Corioli-type flowmeter prototype and conducted a risk assessment to prevent accidents during a process change comparison experiment for existing charging stations to verify the measurement performance. A process change section was defined for the installation of measurement facilities for empirical experiments and HAZOP was conducted. In addition, JSA was also conducted to secure the safety of experimenters, such as preventing valve mis-opening during empirical experiments. Measures were established to improve the risk factors derived through HAZOP, and work procedures were established to minimize human errors and ensure the safety of workers through JSA. The design change and system manufacturing for the installation of the metering system were completed by reflecting the risk assessment results, and safety could be confirmed through the performance comparison test of the developed meter prototype. The developed prototype flow meter showed a total of 30 flow measurements under the operating conditions of 70 MPa, and the average error was -1.58% to 3.96%. Such a metering error was analyzed to have the same performance as a flow meter installed and operated for commercial use.