• 공업화학
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• 제19권1호
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• pp.66-72
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• 2008

탄소강 재질은 부식에 취약하여 용도에 따라 화성피막화 공정으로 처리하여 내부식성을 부여한다. 제이인산망간염 수화물, $MnHPO_4{\cdot}2.25H_2O$는 인산망간피막을 입히기 위한 전처리 공정용 혼합물 제품의 주성분으로 사용된다. 이 망간 함유 물질은 수용액 중에서 합성되어 여과와 건조, 그리고 일련의 건식 분쇄와 분급 과정을 통하여 생산된다. 이러한 공정은 명백히 환경친화적이지 못할 뿐만 아니라 비용 효율적이지 못하다. 본 연구에서는 더블제트 침전 기술에 기반을 두고 수용액 중에서 해당 망간 화합물을 입자 크기가 비교적 균일하게 합성하기 위한 새로운 공정기술 원리를 실험적으로 검토하였다. 안정화 첨가제의 효과들이 주사전자현미경 사진을 통하여, 생성된 결정성 침전 입자의 크기의 균일성 측면에서, 비교 검토되었다. 폴리비닐 피롤리돈과 아라비아 검이 더블제트 침전 공정에서 결정의 성장 단계를 제어하여 비교적 균일한 입자를 합성하는 안정제로서 훌륭한 효과를 발휘하는 것으로 밝혀졌다.

• 대한기계학회논문집B
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• 제34권3호
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• pp.275-282
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• 2010

동축공기 수소 난류 확산화염에서 선회류가 NOx에 미치는 영향을 연구하였다. 공기와의 혼합을 증가시키기 위해 동축공기관에 스월러의 각도를 30, 45, 60, $90^{\circ}$로 바꾸어가며 화염길이와 질소산화물 배출수준을 측정하였다. 연료 속도를 85.7~160.2 m/s, 동축공기 속도는 7.4~14.4 m/s로 조절하였다. 실험을 통해 동축 공기 속도 증가에 따라 화염길이와 질소산화물 배출수준은 증가하였고, 회전류 증가에 따라 감소함을 관찰하였다. EINOx에 미치는 동축공기와 회전류 영향을 상사하기 위하여 far-field 개념의 유효직경($d_{F,eff}$)을 도입하여 동축공기와 선회류에 의한 혼합효과를 표현하였다. 질소산화물 배기배출지표는 화염체류시간(${\sim}{\tau_R}^{1/2.8}$)과 전체 신장률(${\sim}{S_G}^{1/2.8}$)에 영향을 받았다.

• 자동차안전학회지
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• 제15권1호
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• pp.27-34
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• 2023

The registration rate of eco-friendly vehicles, such as hydrogen vehicles, is increasing rapidly, however, few first responders have experienced related accidents. Accident scenarios at hydrogen refueling stations and hydrogen vehicles on a road were investigated, and the relative importance of each scenario was analyzed using AHP analysis. Leakage, jet flame, and explosion that occurred inside and outside the hydrogen refueling station were reviewed, and the hydrogen gas explosion in the compartment showed the highest importance value. In case of the hydrogen vehicle, traffic accident statistics and actual accidents were used. It was analyzed that the hydrogen vessel explosion on the road due to the failure of TPRD and the leakage in the underground parking area were difficult to respond. The developed accident scenarios are expected to be used for first responder training.

• 한국연소학회지
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• 제5권2호
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• pp.51-62
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• 2000

The relationship among the flame radiation, NOx emissions, residence time, and global strain rate are examined for turbulent non-premixed jet flames with wide variations in coaxial air conditions. Measurements of NOx emission, flame geometry and flame radiation were made to explain the NOx emission scaling based on global parameters such as flame residence time, global strain rate, and radiant fraction. The overall 1/2-power scaling is observed in coaxial air flames, irrespective of coaxial air conditions, but the degree of deviation from the 1/2-slope curve in each case differs from one another. From the comparison between the results of pure hydrogen flames and those of helium diluted hydrogen flames, it is observed that flame radiation plays a significant role in pure hydrogen flames with coaxial air and the deviation from 1/2-power scaling may be explained in two reasons: the difference in the flame radiation and the difference in jet similarity in coaxial air flames. From the radiation measurements, more detailed explanations on these deviations were suggested.

• 한국수소및신에너지학회논문집
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• 제20권6호
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• pp.505-511
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• 2009

The hydriding and electrochemical characteristics of Zr-based $AB_2$ alloy produced by gas atomization have been extensively examined. For the particle morphology of the as-cast and gas-atomized powders, it can be seen that the mechanically crushed powders are irregular, while the atomized powder particles are spherical. The increase of jet pressure of gas atomization process results in the decrease of hydrogen storage capacity and the slope of plateau pressure significantly increases. TEM and EDS studies showed the increase of jet pressure in the atomization process accelerated the phase separation within grain of the gas-atomized alloy, which brought about a poor hydrogenation property. However, the gas-atomized $AB_2$ alloy powders produced by jet pressure of 50 bar kept up the reversible $H_2$ storage capacity and discharge capacity similar to the mechanically crushed particles. In addition, the electrode of gas-atomized Zr-based $AB_2$ alloy of 50 bar showed improved cyclic stability over that of the cast and crushed particulate, which is attributed to the restriction of crack propagation by grain boundary and dislocation with ch/discharging cycling.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년도 제31회 추계학술대회논문집
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• pp.393-396
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• 2008

질소 희석 가스가 수소화염의 화염안정성에 미치는 영향을 실험적으로 연구하였다. 연료는 수소이며 수소화염을 부상시키기 위하여 동축공기를 사용하였다. 이때 수소의 속도는 200 m/s이고 동축공기의 속도는 16 m/s로 고정하였다. 질소 희석 가스는 연료 공급라인에 주입되었으며 전체 연료 부피의 0$\sim$20%까지 주입하였다. 화염구조분석을 위하여 PIV/OH PLIF 동시측정 기법을 사용하였다. 수소 난류 확산화염 화염안정성 실험을 통하여 질소 가스 주입에 따라 부상화염 높이는 증가하였으며, 난류 화염 전파속도는 감소하였다. 그리고 난류 화염전파속도는 난류강도의 함수로 표현될 수 있었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.266-271
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• 2006

Characteristic of partial oxidation of methane using arc-jet plasma by AC power is investigated. Arc-jet reactor used in this work is slightly modified from typical arc jet reactor so that it can make and sustain stable state of plasma. Methane conversion, selectivity of chemicals such as hydrogen and hydrocarbon materials in the product are analyzed. Parametric approach on the performance of the reactor or detail on the partial oxidation process is carried with $O_2/C$ ratio as parameter. In addition to the results, SED and arc length is changed to understand the effect of current-voltage correlation on the reforming performance and relative role of thermal process.

• 전기의세계
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• 제21권4호
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• pp.27-38
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• 1972

This paper discusses the characteristics about the ignition of D.C. main discharge is a plasma jet generator, manufactured for trial as non-transferred type, when the electrical energy appropriate to the ignition is supplied to the gap between the electrodes by using advance discharge of attenuating high frequency voltage generated by a high frequency oscillator with mercury spark gap. These characteristics are under the influences of (a) the length of mercury gap in high frequency oscillator and the quantity of hydrogen flow supplied to it, (b) the condenser capacity of the high frequency oscillator circuit, (c) the length of plasma jet torch in D.C. main discharge circuit and the quantity of argon flow supplied to it, (d) the circuit constants of D.C. main discharge circuit. The results for these characteristics, obtained by this research, are considered to be helpful to the designs for the ignition of a plasma jet as well as the welding arc stabilizer by high frequency discharge and the high frequency arc welder.

• 펄프종이기술
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• 제46권2호
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• pp.46-56
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• 2014

The aim of this reviews is to introduce the information concerning design of the UV-curable jet ink composition in order to provide a good adhesive property on non-porous surface. In order to clarify the viscosity dependence of flying speed for the UV curable jet ink, rheological analysis and observation of the flying state of the ink were carried out. The relationship between ink formulas and adhesive property on non-porous surface was investigated. It was examined the adhesive property of radical polymerization type UV curable jet ink included hydrogen abstraction type photo-initiator, it was expected that the strong adhesive strength can be obtained between the ink and non-porous surface in this study. UV curable jet ink with a slight amount of water was prepared. Optimum ratio of the cationic polymerization type UV curable jet ink shows an adequate adhesive strength towards two kinds of non-porous surface such as glass, poly(vinyl chloride) when tests were conducted on the ink jet-printing test machine.

• 한국연소학회지
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• 제17권1호
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• pp.22-29
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• 2012

The detachment stability characteristics of syngas $H_2$/CO jet attached flames were studied. The flame stability was observed while varying the syngas fuel composition, coaxial nozzle diameter and fuel nozzle rim thickness. The detachment stability limit of the syngas single jet flame was found to decrease with increasing mole fraction of carbon monoxide in the fuel. In hydrogen jet flames with coaxial air, the flame detachment stability was found to be independent of the coaxial nozzle diameter. However, velocities of appearance of liftoff and blowout velocities of lifted flames have dependence. At lower fuel velocity range, the critical coaxial air velocity leading to flame detachment increases with increasing fuel jet velocity, whereas at higher fuel velocity range, it decreases. This increasing-decreasing non-monotonic trend appears for all $H_2$/CO syngas compositions (50/50~100/0% $H_2$/CO). To qualitatively understand the flame behavior near the nozzle rim, $OH^*$ chemiluminescence imaging was performed near the detachment limit conditions. For all fuel compositions, local extinction on the rim is observed at lower fuel velocities(increasing stability region), while local flame extinction downstream of the rim is observed at higher fuel velocities(decreasing stability region). Maximum values of the non-monotonic trends appear to be identical when the fuel jet velocity is normalized by the critical fuel velocity obtained in the single jet cases.