• Title/Summary/Keyword: Hydrogen flux density

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A MONTE CARLO STUDY OF FLUX RATIOS OF RAMAN SCATTERED O VI FEATURES AT 6825 Å AND 7082 Å IN SYMBIOTIC STARS

  • Lee, Young-Min;Chang, Seok-Jun;Heo, Jeong-Eun;Hong, Chae-Lin;Lee, Hee-won
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.57.3-58
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    • 2016
  • A symbiotic star is a wide binary system consisting of a hot white dwarf and a mass losing giant, where the giant loses its material in the form of a slow stellar wind resulting in accretion onto the white dwarf through gravitational capture. Symbiotic stars are known to exhibit unique spectral features at 6825 and 7082, which are formed from O VI 1032 and 1038 through Raman scattering with atomic hydrogen. In this Monte Carlo study we investigate the flux ratio of 6825 and 7082 in a neutral region with a geometric shape of a slab, cylinder and sphere. By varying the amount of neutral hydrogen parametrized by the column density along a specified direction, we compute and compare the flux ratio of Raman scattered O VI 6825 and 7082. In the column density around 1020 cm-2, flux ratio changes in a complicated way, rapidly decreasing from the optically thin limit to unity the optically thick limit as the column density increases. It is also notable that when the neutral region is of a slab shape with the O VI source outside the slab, the optically thick limit is less than unity, implying a significant fraction of O VI photons escape through Rayleigh scattering near the boundary. We compare our high resolution CFHT data of HM Sge and AG Dra with the data simulated with finite cylinder models confirming that 'S' type symbiotic tend to be characterized by thicker HI region that 'D' type counterparts. It is expected that this study will be useful in interpretation of the clear disparity of Raman O VI 6825 and 7082 profiles, which will shed much light on the kinematics and the asymmetric distribution of O VI material around the hot white dwarf.

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Comparison of Pervaporation and Vapor Permeation Separation Processes for MTBE-methanol System

  • Kim, Youn-Kook;Lee, Keun-Bok;Rhim, Ji-Won
    • Korean Membrane Journal
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    • v.2 no.1
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    • pp.36-47
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    • 2000
  • This paper deals with the separation of MTBE-methanol mixtures using crosslinked Poly(vinyl alcohol)(PVA) membranes with sulfur-succinic acid(SSA) as a crosslinking agent by pervaporation and vapor permeation technique. The operating temperatures, methanol concentration in feed mixtures, and SSA concentrations in PVA membranes were varied to investigate the separation performance of PVA/SSA membranes and the optimum separation characteristics by pervaporation and vapor permeation. And also, for PVA/SSA membranes, the swelling measurements were carried out to study the transport phenomena. The swelling measurements were carried out for pure MTBE and methanol, and MTBE/methanol=90/10, 80/20 mixtures using PVA/SSA membranes with varying SSA compositions. There are two factors of the membrane network and the hydrogen bonding. In pervaporation separation was also carried out for MTBE/methanol=90/10, 80/20 mixtures at various temperatures. The sulfuric acid group in SSA took an important role in the membrane performance. The crosslinking effect might be over the hydrogen bonding effect due to the sulfuric acid group at 3 and 5% SSA membranes, and this two factors act vice versa on 7% SSA membrane. In this case, the 5% SSA membrane shows the highest separation factor of 2,095 with the flux of 12.79g/㎡$.$hr for MTBE/methanol=80/20 mixtures at 30$^{\circ}C$ which this mixtures show near the azeotopic composition. Compared to pervaporation, vapor permeation showed less flux and similar separation factor. In this case, the flux decreased significantly because of compact structure and the effect of hydrogen bonding. In vapor permeation, density or concentration of methanol in vaporous feed is lower than that of methanol in liquid feed, as a result, the hydrogen bonding portion between the solvent and the hydroxyl group in PVA is reduced in vapor permeation. In this case, the 7% SSA membranes shows the highest separation factor of 2,187 with the flux of 4.84g/㎡$.$hr for MTBE/methanol=80/20 mixtures at 30$^{\circ}C$.

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Comparison of Pervaporation and Vapor Permeation Separation Processes for MTBE-methanol System

  • 김연국;이근복;임지원
    • Membrane Journal
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    • v.2 no.1
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    • pp.36-36
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    • 1992
  • This paper deals with the separation of MTBE-methanol mixtures using crosslinked Poly(vinyl alcohol)(PVA) membranes with sulfur-succinic acid(SSA) as a crosslinking agent by pervaporation and vapor permeation technique. The operating temperatures, methanol concentration in feed mixtures, and SSA concentrations in PVA membranes were varied to investigate the separation performance of PVA/SSA membranes and the optimum separation characteristics by pervaporation and vapor permeation. And also, for PVA/SSA membranes, the swelling measurements were carried out to study the transport phenomena. The swelling measurements were carried out for pure MTBE and methanol, and MTBE/methanol=90/10, 80/20 mixtures using PVA/SSA membranes with varying SSA compositions. There are two factors of the membrane network and the hydrogen bonding. In pervaporation separation was also carried out for MTBE/methanol=90/10, 80/20 mixtures at various temperatures. The sulfuric acid group in SSA took an important role in the membrane performance. The crosslinking effect might be over the hydrogen bonding effect due to the sulfuric acid group at 3 and 5% SSA membranes, and this two factors act vice versa on 7% SSA membrane. In this case, the 5% SSA membrane shows the highest separation factor of 2,095 with the flux of 12.79g/㎡·hr for MTBE/methanol=80/20 mixtures at 30℃ which this mixtures show near the azeotopic composition. Compared to pervaporation, vapor permeation showed less flux and similar separation factor. In this case, the flux decreased significantly because of compact structure and the effect of hydrogen bonding. In vapor permeation, density or concentration of methanol in vaporous feed is lower than that of methanol in liquid feed, as a result, the hydrogen bonding portion between the solvent and the hydroxyl group in PVA is reduced in vapor permeation. In this case, the 7% SSA membranes shows the highest separation factor of 2,187 with the flux of 4.84g/㎡·hr for MTBE/methanol=80/20 mixtures at 30℃.

A Study on the Effect of Evaporation of Liquid Hydrogen Tank Related to Horizontal Sinewave (액화수소 저장탱크의 수평요동이 증발 특성에 미치는 영향에 대한 연구)

  • SEUNG JUN OH;JUN YEONG KWON;JEONG HWAN YOON
    • Journal of Hydrogen and New Energy
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    • v.34 no.2
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    • pp.155-161
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    • 2023
  • Recently, a study on alternative and renewable energy is being conducted due to energy depletion and environmental problems. In particular, a hydrogen has the advantage of converting and storing the remaining energy into water-electrolyzed hydrogen through renewable energy generation. In general, due to reasons such as insulation problems, a study on high-pressure hydrogen storage tanks and related parts has recently been conducted. However, in the case of liquid hydrogen, the volume can be reduced by about 800 times or more compared to high-pressure hydrogen gas, so the study on this is needed as a technology that can increase energy density. In this study, the evaporation characteristics were analyzed under fixed heat flux conditions for liquid hydrogen storage tanks and the change in thermal stratification according to sloshing was analyzed. The heat flux condition was fixed at 250 W/m2 and the horizontal resonance frequency of the primary mode was applied to the storage tank. As a result, it was confirmed that the thermal stratification phenomenon decreased compared to the case where the slashing was not present due to forced convection when the slashing was present.

Characteristic analysis of The Catalyst Layer and Gas Diffusion Layer Model for FEMFC optimal design (FEMFC 최적설계를 위한 촉매층모델과 기체확산층 특성해석)

  • Kwon, Kee-Hong
    • Journal of IKEEE
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    • v.21 no.2
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    • pp.123-129
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    • 2017
  • Proton Exchange Membrane Fuel Cell (FEMFC) is a strong candidate for future automobile and power generation because of its high power density, low emission and low operation temperature. The major concerns of the gas diffusion layer (GDL) inside a FEMFC is water management. The GDL is typically comprised of carbon for electrical conductivity and PTFE for Hydrophobicity. In this simulation, GDL flooding was investigated using a simplified approach method of an established equation models(Fick' Law, Darcy, Law, Stefan-Maxwell diffusion). The performance of GDL was shown using result of the inner heat, water density and oxygen density of the cell using model equations. The catalyst layer mode in FEMFC showed results of effectiveness factor, Butler-volmer and hydrogen flux density. These results are interesting because the influence of several factors has been shown and the information will be helpful for fuel cell design.

Simulation Study of Optimizing Multicusp Magnetic Line Configurations for a Negative Hydrogen Ion Source

  • Kim, Jae-Hong;Hong, Seong-Gwang;Kim, Jong-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.250.1-250.1
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    • 2014
  • A multicusp ion source has been used widely in negative hydrogen cyclotrons mainly for radioisotope productions. The ion source is designed to have cusp geometries of magnetic field inside plasma chamber, where ions are confining and their mean lifetimes increase. The magnetic confinement produced a number of permanent magnetic poles helps to increase beam currents and reduce the emittance. Therefore optimizing the number of magnets confining more ions and increasing their mean lifetime in plasma has to be investigated in order to improve the performance of the ion source. In this work a numerical simulation of the magnetic flux density from a number of permanent magnets is carried to optimize the cusp geometries producing the highest plasma density, which is clearly indicated along the full-line cusp geometry. The effect of magnetic fields and a number of poles on the plasma structure are investigated by a computing tool. The electron confinement effect becomes stronger and the density increases with increasing the number of poles. On the contrary, the escape of electrons from the loss cone becomes more frequent as the pole number increases [1]. To understand above observation the electron and ion's trajectories along with different cusp geometries are simulated. The simulation has been shown that the optimized numbers of magnets can improve the ion density and uniformity.

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$Ba[Ce_{0.9}Y_{0.1}]O_{3-\delta}$ - Ni Composite Membrane for Hydrogen Separation by Aerosol Deposition Method (에어로졸 증착법[aerosol depostion method]에 의한 $Ba[Ce_{0.9}Y_{0.1}]O_{3-\delta}$ - Ni 수소분리막 제조)

  • Park, Young-Soo;Byeon, Myeong-Seob;Choi, Jin-Sub;Kim, Jin-Ho;Hwang, Kwang-Taek
    • Journal of Hydrogen and New Energy
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    • v.21 no.2
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    • pp.117-122
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    • 2010
  • BCY($Ba(Ce_{0.9}Y_{0.1})O_{3-\delta}$) oxide, shows high protonic conductivity at high temperatures, and are referred to as hydrogen separation membrane. For high efficiency of hydrogen separation ($H_2$ flux and selectivity) and low fabrication cost, ultimate thin and dense BCY-Ni layer have to be coated on a porous substrate such as $ZrO_2$. Aerosol depostion (AD) process is a novel technique to grow ceramic film with high density and nano-crystal structure at room-temperature, and would be applied to the fabrication process of AD integration ceramic layer effectively. XRD and SEM measurements were conducted in order to analyze the characteristics of BCY-Ni membrane fabricated by AD process.

Analysis of Slag Behavior near the Slag Tap in an Entrained Flow Coal Gasifier (분류층 석탄가스화기 하부 슬래그 탭 부근의 슬래그 거동 해석)

  • Chung, Jae-Hwa;Chi, Jun-Hwa;Lee, Joong-Won;Seo, Seok-Bin;Kim, Ki-Tae;Park, Ho-Young
    • Journal of Hydrogen and New Energy
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    • v.22 no.6
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    • pp.913-924
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    • 2011
  • A steady-state analysis has been conducted to predict the behavior of the slag layer in the entrained-flow slagging coal gasifier. The analysis takes into consideration the composition dependent slag properties such as density, viscosity, heat capacity, thermal conductivity, and temperature of critical viscosity. The amount of added flux to the design coal and the variation of syngas temperature inside the gasifier have been adopted as calculation parameters. The predicted results are the local thickness of the molten and the solid slag layers, and the slag viscosity and the velocity distribution across the molten slag layer along the gasifier wall near the slag tap.

Collective effect of hydrogen in argon and Mg as ambiance for the heat treatment on MgB2

  • Sinha, B.B.;Jang, S.H.;Chung, K.C.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.2
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    • pp.24-28
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    • 2014
  • Magnesium diboride superconductor is still of considerable interest because of its appealing characteristics towards application mainly at around 20 K. Unlike Nb-based superconductors, $MgB_2$ can be operated by cryogen-free cooler which provides a cost effective alternative at low field of around 2-5 T. To explore this operating field region considerable efforts are necessary to marginally improve the superconducting properties of $MgB_2$. Under this situation, even the heat treatment environment during the synthesis is considered as an important factor. The addition of $H_2$ gas in small amount with Ar as a mixed gas during annealing has an adverse effect on the superconducting properties of $MgB_2$. It is although interesting to find that the presence of Mg vapor along with hydrogen during heat treatment results in the appreciable improvement in the flux pinning and the overall response of the critical current density for the ex-situ $MgB_2$ samples.

Flow Boiling Heat Transfer Characteristics on Sintered Microporous Surfaces in a Mini-channel (마이크로 소결 구조 채널에서의 흐름 비등 열전달 특성 연구)

  • KIM, YEONGHWAN;SHIN, DONG HWAN;KIM, JIN SUB;MOON, YOOYONG;HEO, JAEHUN;LEE, JUNGHO
    • Journal of Hydrogen and New Energy
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    • v.29 no.1
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    • pp.105-110
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    • 2018
  • The flow boiling heat transfer of water was experimentally investigated on plain and sintered microporous surfaces in a mini-channel. The effects of microporous coating on flow boiling heat transfer of subcooled water were investigated in a 300 mm long mini-channel with a cross section of $20{\times}10mm^2$. The test section has sufficiently long entrance length of 300 mm which provides a fully-developed flow before the channel inlet. The bottom side of the channel was heated by a copper block assembled with a high-density cartridge heater and other sides of the channel were insulated. The microporous surface was fabricated by sintering copper particles with the average particle size of $50{\mu}m$ on the top side of the copper block. Heat transfer measurement was conducted at the mass flux of $208kg/m^2s$ and the heat flux up to $500kW/m^2$. Microporous coated surface showed an earlier boiling incipience compared with plain surface regardless of the mass flux. Microporous coating were significantly attributed to local wall temperature and local heat transfer coefficient for flow boiling.