• 제목/요약/키워드: Hydrogen exchange

검색결과 408건 처리시간 0.028초

인체에서 분리된 Lactobacillus acidophilus가 생산하는 박테리오신의 선별과 정제 (Screening and Partial Purification of Bacteriocins by Strains of Lactobacillus acidophilus Isolated from Human Origin)

  • 김세헌;김영교
    • Journal of Dairy Science and Biotechnology
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    • 제15권1호
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    • pp.21-26
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    • 1997
  • Lactobacillus acidophilus 223, 606, and NCFM-F among 21 isolated from fecal contents of humans demonstrated inhibitory activity attributed to bacteriocin(s). The bacteriocin(s) were heat stable and nondialyzable proteinous compounds and exhibited narrow inhibitory spectra of activity. Neither hydrogen peroxide nor pH were responsible for inhibitory action. All of the producer strains were resistant to their own bacteriocin(s). The bacteriocin(s) were purified by ammonium sulfate precipitation, gel chromatography and ion exchange chromatography for further characterization. The bacteriocin(s) of human origin exhibited similar characteristics.

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Characterization of Enhanced CO Oxidation Activity by Alumina Supported Platinum Catalyst

  • Jo, Myung-Chan
    • 한국환경과학회지
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    • 제18권10호
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    • pp.1071-1077
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    • 2009
  • A novel pretreatment technique was applied to the conventional Pt/alumina catalyst to prepare for the highly efficient catalyst for the preferential oxidation of carbon monoxide in hydrogen-rich condition. Their performance was investigated by selective CO oxidation reaction. CO conversion with the oxygen-treated Pt/Alumina catalyst increased remarkably especially at the low temperature below $100^{\circ}C$. This result is promising for the normal operation of the proton exchange membrane fuel cell (PEMFC) without CO poisoning of the anode catalyst. XRD analysis results showed that metallic Pt peaks were not observed for the oxygen-treated catalyst. This implies that well dispersed small Pt particles exist on the catalyst. This result was continued by high resolution transmission electron microscopy (HRTEM) analysis. Consequently, it can be concluded that highly dispersed Pt nanoparticles could be prepared by the novel pretreatment technique and thus, CO conversion could be increased considerably especially at the low temperatures below $100^{\circ}C$.

Platinum nanocomposites and its applications: A review

  • Sharon, Madhuri;Nandgavkar, Isaac;Sharon, Maheshwar
    • Advances in materials Research
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    • 제6권2호
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    • pp.129-153
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    • 2017
  • Platinum is a transition metal that is very resistant to corrosion. It is used as catalyst for converting methyl alcohol to formaldehyde, as catalytic converter in cars, for hydrocracking of heavy oils, in Fuel Cell devices etc. Moreover, Platinum compounds are important ingredient for cancer chemotherapy drugs. The nano forms of Platinum due to its unique physico-chemical properties that are not found in its bulk counterpart, has been found to be of great importance in electronics, optoelectronics, enzyme immobilization etc. The stability of Platinum nanoparticles has supported its use for the development of efficient and durable proton exchange membrane Fuel Cells. The present review concentrates on the use of Platinum conjugated with various metal or compounds, to fabricate nanocomposites, to enhance the efficiency of Platinum nanoparticles. The recent advances in the synthesis methods of different Platinum-based nanocomposites and their applications in Fuel Cell, sensors, bioimaging, light emitting diode, dye sensitized solar cell, hydrogen generation and in biosystems has also been discussed.

작동조건을 고려한 자동차용 PEM 연료전지 시스템 성능 시뮬레이션 (1) (The Simulation of PEMFC System Performance for Automotive Application (1))

  • 방정환;김한상;이동훈;민경덕;김민수;조영만
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.460-465
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    • 2003
  • The modeling of PEM (Proton Exchange Membrane) fuel cell system consisting of fuel cell stack and BOP (Balance of Plant) is presented in this paper. The effects of temperature, pressure (air, hydrogen), and humidity on the fuel cell system performance were mainly investigated using thermo-dynamical and electro-chemical equations. To understand the power distribution characteristics of fuel cell system, the effects of operating temperature and air pressure on maximum power and system power were also demonstrated. Through this study, we can get the basic insight into the fuel cell stack and BOP component sizing and it can be used effectively for the optimization of the practical fuel cell systems in purpose.

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모바일용 연료전지 개발 (The development of mobile fuel cell)

  • 이강인;박민수;조용훈;조윤환;성영은;주종남
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.549-550
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    • 2006
  • Mobile fuel cell is highlighted in these days because mobile fuel cell can contain more energy than existing batteries. Nowadays mobile devices like cellular phone, PMP(portable multi-media player), notebook, and etc. need more energy, But existing batteries like Li-ion or Ni-MH batteries are not going to satisfy such demands. In this paper, mobile fuel cell is developed. Its size is 50*70*8mm and it is made of aluminium plates. The fuel cell type is PEM and the fuel is pure hydrogen and oxygen.

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고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화 (Performance change according to the catalyst intrusion rate in the MEA for the PEM water electrolysis)

  • 김홍열
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.254-256
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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고체산화물연료전지의 시뮬레이션을 위한 전기화학모델 (Electrochemical model for the simulation of solid oxide fuel cells)

  • 박준근;이신구;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.63-66
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    • 2008
  • This study presents 0-dimensional model for solid oxide fuel cells(SOFCs). The physics of the cell and the simplifying assumptions are presented, and only hydrogen participates in the electrochemical reaction. The electrical potential is predicted using this model. The Butler-Volmer equation is used to describe the activation polarization and the exchange current density is changed according to the partial pressure of reactants and the temperature. The electrical conductivities of electrodes and an electrolyte are calculated for the ohmic polarization. Material characteristics and temperature affect those factors. Analysis of concentration polarization based on transport of gaseous species through porous electrodes is incorporated in this model. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results and numerical results by other researchers.

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Electrochemical Investigation of Animal Tissue Embedded Biosensor Bound with Ethylene-Propylene Rubber

  • Yoon, Kil-Joong
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2913-2917
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    • 2010
  • When rubber dissolved in toluene was used as a binding material of graphite powder, the mechanical robustness of the carbon paste was guaranteed by the fast volatility of the solvent immediately after electrode construction. This characteristic of the rubber solution met qualifications for practical use of carbon paste electrodes and enabled the design of a new enzyme electrode bound with EPDM. In order to confirm whether the electrode shows quantitative electrochemical behaviors or not, its kinetic parameters, e. g. the symmetry factor (0.2), the exchange current density ($3.66\;{\mu}A/cm^2$), the capacity of the double layer ($2.0{\times}10^{-5}\;F$), the Michaelis constant ($4.39{\times}10^{-3}\;M$), the diffusion coefficient of substrate ($2.58{\times}10^{-12}\;cm^2/sec$), the time constant (0.018 sec) and other factors were investigated.

고분자전해질 수전해용 MEA의 촉매침투도에 따른 성능변화 (Performance Change according to the Catalyst Intrusion Rate in the MEA for the PEM Water Electrolysis)

  • 김홍열;이지정;이재영;이홍기
    • 신재생에너지
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    • 제5권4호
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    • pp.75-78
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    • 2009
  • The performances of proton exchange membrane (PEM) water electrolysis depend on many factors such as materials, geometries, fabrication methods, operating conditions, and so forth. The fabrication method is concerned, membrane electrode assemblies (MEA) are a most important part to show different performances by different fabrication methods. The performance change of PEM water electrolysis was experimentally measured according to the fabrication differences of the anode electrodes. One point of view is the catalyst intrusion rate to the anode gas diffusion layer (GDL), and the other point of view is the catalyst loading distribution in depth of the anode GDL. Results show that the performances of MEA with deep intrusion of the catalysts are better in the range of low current densities but worse at higher current densities. The catalyst loading distribution does not affect significantly to the performance of PEM water electrolyser.

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