• Title/Summary/Keyword: Hydrogen exchange

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Co(Ⅲ) Complexes of Glycine Methyl Ester (Ⅰ). Preparation and Characterization (Co(Ⅲ) Glycine Methyl Ester 착물에 관한 연구 (제1보). 착물의 합성과 구조규명)

  • Ja Hong Kim;Sang Chul Shim
    • Journal of the Korean Chemical Society
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    • v.24 no.5
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    • pp.356-360
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    • 1980
  • Octahedral Co(Ⅲ) complexes of the glycine methyl ester have been prepared and characterized by elemental analysis, infrared, and NMR spectrum. Co(Ⅲ) glycine methyl ester complex has been isolated from the reaction of glycine and glycine methyl ester in aqueous solution by cation exchange resin, Dowex 50W-X8 (hydrogen form). It has been observed that the complexes have $C_1-cis(0-0), C_2-cis(0-0), trans(0-0)$ geometry.

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FUEL CELL ELECTRIC VEHICLES: RECENT ADVANCES AND CHALLENGES - REVIEW

  • Yang, W.C.
    • International Journal of Automotive Technology
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    • v.1 no.1
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    • pp.9-16
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    • 2000
  • The growing concerns on environmental protection have been constantly demanding cleaner and more energy efficient vehicles without compromising any conveniences provided by the conventional vehicles. The recent significant advances in proton-exchange-membrane (PEM) fuel cell technology have shown the possibility of developing such vehicles powered by fuel cells. Several prototype fuel cell electric vehicles (FCEV) have been already developed by several major automotive manufactures, and all of the favorable features have been demonstrated in the public roads. FCEV is essentially a zero emission vehicle and allows to overcome the range limitation of the current battery electric vehicles. Being motivated by the laboratory and field demonstrations of the fuel cell technologies, variety of fuel cell alliances between fuel cell developers, automotive manufactures, petroleum companies and government agencies have been formed to expedite the realization of commercially viable FCEV. However, there still remain major issues that need to be overcome before it can be fully accepted by consumers. This paper describes the current fuel cell vehicle development status and the staggering challenges for the successful introduction of consumer acceptable FCEVS.

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DEVELOPMENT OF FUEL CELL HYBRID ELECTRIC VEHICLE PERFORMANCE SIMULATOR

  • Park, C.;Oh, K.;Kim, D.;Kim, H.
    • International Journal of Automotive Technology
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    • v.5 no.4
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    • pp.287-295
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    • 2004
  • A performance simulator for the fuel cell hybrid electric vehicle (FCHEV) is developed to evaluate the potentials of hybridization for fuel cell electric vehicle. Dynamic models of FCHEV's electric powertrain components such as fuel cell stack, battery, traction motor, DC/DC converter, etc. are obtained by modular approach using MATLAB SIMULINK. In addition, a thermodynamic model of the fuel cell is introduced using bondgraph to investigate the temperature effect on the vehicle performance. It is found from the simulation results that the hybridization of fuel cell electric vehicle (FCEV) provides better hydrogen fuel economy especially in the city driving owing to the braking energy recuperation and relatively high efficiency operation of the fuel cell. It is also found from the thermodynamic simulation of the FCEV that the fuel economy and acceleration performance are affected by the temperature due to the relatively low efficiency and reduced output power of the fuel cell stack at low temperature.

Study of performance of a stack in the presence of CO and air (연료전지의 CO 피독 및 회복에 관한 연구)

  • Kim, Hee-Su;Kim, Dong-Chan;Han, Ji-Hee;Lee, Ho-Jun
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.180-183
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    • 2007
  • CO in the reformed gas for proton exchange membrane fuel cell(PEMFC) has a strong tendency to adsorb on the surface of the catalyst and thus to block the sites that hydrogen needs for reactions. Even part per million levels of CO can cause serious poisoning. This CO poisoning can overcome to bleed trace amounts of air into the anode. In this study, we indicated the alteration of stack performance in various CO concentration and then bled a small amount of air. The performance of stack was reduced by increasing CO amount, and recovered by air bleeding. But the air-bleeding have an impact on performance of anode should be further explored.

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Operating Characteristics on Coupling of Fuel-Cell System with Natural Gas Reformer (휴대전원용 직접알코올 연료전지의 OCV특성 연구)

  • Park, Se-Joon;Choi, Yong-Sung;Lee, Kyung-Sup
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.4
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    • pp.592-596
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    • 2009
  • DAFC(direct alcohol fuel cell) takes the same structure and operational principle with PEMFC(Proton exchange membrane fuel cell). However, DAFC, which uses liquid alcohol instead of hydrogen as fuel, is able to be used as a portable power for small-scaled electronic devices such as MP3, PMP, and mobile phone because alcohol is quite convenient steady-state compound to carry and store it. This paper presents the OCV(open circuit voltage) characteristics of the cases which are alcohol species and different weight rate of ethanol, respectively. The OCV of methanol fuel cell is slightly higher 0.2V than ethanol one, and 8% wt. rate ethanol is rated as the most appropriate fuel for DAFC.

The Effect of Operating Conditions on the Heat-flow Characteristics and Reforming Efficiency of Steam Reformer with Combustor (연소기가 장착된 수증기 개질기에서 운전조건이 열유동 특성 및 개질효율에 미치는 영향)

  • Kim, Ji-Seok;Lee, Jae-Seong;Kim, Ho-Young
    • Journal of the Korean Society of Combustion
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    • v.16 no.1
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    • pp.36-45
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    • 2011
  • The heat-flow characteristics and reforming efficiency of steam reformer with combustor are numerically investigated at various operating conditions. SCR(Steam to Carbon Ratio) and GHSV(Gas Hourly Space Velocity) are adopted as important operating conditions. User-Defined-Function(UDF) was used to simultaneously calculate reforming and combustion reaction. Numerical results show that hot burned gas rise by a buoyant force and heat exchange between reforming reactors and cocurrent flow occurs in the combustion region. The results also indicate that an increase of SCR leads to decrease the mole fraction of hydrogen at the reactor outlet. As GHSV increases, conversion rate decreases.

Backbone NMR Assignments of WW2 domain from human AIP4

  • Seo, Min-Duk
    • Journal of the Korean Magnetic Resonance Society
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    • v.24 no.2
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    • pp.38-42
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    • 2020
  • WW domains are small protein modules consisting of three-stranded antiparallel β-sheet, and involved in the protein-protein interaction for various biological systems. We overexpressed and purified WW2 domain from human AIP4/Itch (a member of Nedd4 family) using a pH/temperature dependent cleavage system. The backbone assignments of WW2 domain were completed, and secondary structure was predicted. Furthermore, backbone flexibility of WW2 domain was determined by 1H-15N heteronuclear NOE and amide hydrogen exchange experiments. The structural information would contribute to the structural determination of WW2 domain as well as the interaction study of WW2 domain with various binding partners.

Cryogenic Distillation Apparatus for Hydrogen Isotopes Separation (수소동위원소 분리를 위한 초저온증류장치)

  • 송규민;손순환;김광신;김위수
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.163-166
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    • 2001
  • KEPCO has a plan to construct TRF (tritium removal facility) in wolsong nuclear power plant site by 2005. In advance of WTRF construction, the pilot plant was installed at KEPRI in order to show process reliability of WTRF. The main processes of this pilot plant are LPCE(liquid phase catalytic exchange) and CD (cryogenic distillation). Deuterium is separated from heavy water in LPCE process and concentrated in CD process. CD process consists of cold box, where are a distillation column and heat exchangers, vacuum system, cryogenic refrigerant supply system and instrument & control system. The experience of the pilot plant will be used in WTRF design review, operating procedure revision and fundamental education for the operators.

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SPECTRAL DIAGNOSTICS OF THE ENERGETIC PARTICLES IN SOLAR FLARES

  • FANG C.;DING M. D.;HENOUX J. C.;GAN W. Q.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.295-298
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    • 1996
  • Non-LTE calculations, with the non-thermal ionization effects included, indicated that for electron bombardment, the H$\alpha$ line is widely broadened and shows a strong central reversal. Significant enhancements at the line wings of Ly$\alpha$ and Ly$\beta$ are also predicted at the beginning of the impulsive phase of flares. For the proton bombardment, no strong broadening and no large central reversal are expected. However, due to proton-hydrogen charge exchange, the enhancements at the red wings of Ly$\alpha$ and Ly$\beta$ lines at the early impulsive phase of flares are significant. Our results show that the electron beam can also in some cases generate visible and UV continuum emission in white-light flares. However, at the onset phase, a negative flare may appear within several seconds, due to the increase of the H- opacity. Another spectroscopic signature of energetic particles, i.e. the impact polarization of atomic lines, is also mentioned.

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Electric Voltage and Current Characteristics of Fuel Cell for Machine Tool Power Supply (공작기계 동력용 연료전지의 전압과 전류특성에 관한 연구)

  • Kim H. G.;Kim Y. S.;KIm H. Y.
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.1
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    • pp.1-7
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    • 2005
  • PEMFC (Proton Exchange Membrane Fuel Cell) is considered as an attractive option to produce electric power in manyapplications. A fundamental step of theoretical fuel cell open circuit potential is examined and compared with the measured data from 1.2KW PEMFC module. The hydrogen pressure and stack temperature are also measured during the operation of PEMFC module. It is found that the stack voltage and current data agree in general with the results calculated by chemical potential approach though they still have a discrepancy. It is analysed that the discrepancy is due to activation polarization, concentration overvoltage and ohmic overvoltage.