• 한국분말재료학회지
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• 제8권3호
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• pp.151-156
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• 2001

MgO based nanocomposite powder including ferromagnetic iron particle dispersions, which can be available for the magnetic and catalytic applications, was fabricated by the spray pyrolysis process using ultra-sonic atomizer and reduction processes. Liquid source was prepared from iron (Fe)-nitrate, as a source of Fe nano-dispersion, and magnesium (Mg)-nitrate, as a source of MgO materials, with pure water solvent. After the chamber were heated to given temperatures (500~$^800{\circ}C$), the mist of liquid droplets generated by ultrasonic atomizer carried into the chamber by a carrier gas of air, and the ist was decomposed into Fe-oxide and MgO nano-powder. The obtained powders were reduced by hydrogen atmosphere at 600~$^800{\circ}C$. The reduction behavior was investigated by thermal gravity and hygrometry. After reduction, the aggregated sub-micron Fe/MgO powders were obtained, and each aggregated powder composed of nano-sized Fe/MgO materials. By the difference of the chamber temperature, the particle size of Fe and MgO was changed in a few 10 nm levels. Also, the nano-porous Fe-MgO sub-micron powders were obtained. Through this preparation process and the evaluation of phase and microstructure, it was concluded that the Fe/MgO nanocomposite powders with high surface area and the higher coercive force were successfully fabricated.

• 한국분말재료학회지
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• 제25권2호
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• pp.120-125
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• 2018

Boron nitride nanotubes (BNNTs) are receiving great attention because of their unusual material properties, such as high thermal conductivity, mechanical strength, and electrical resistance. However, high-throughput and high-efficiency synthesis of BNNTs has been hindered due to the high boiling point of boron (${\sim}4000^{\circ}C$) and weak interaction between boron and nitrogen. Although, hydrogen-catalyzed plasma synthesis has shown potential for scalable synthesis of BNNTs, the direct use of $H_2$ gas as a precursor material is not strongly recommended, as it is extremely flammable. In the present study, BNNTs have been synthesized using radio-frequency inductively coupled thermal plasma (RF-ITP) catalyzed by solid-state ammonium chloride ($NH_4Cl$), a safe catalyst materials for BNNT synthesis. Similar to BNNTs synthesized from h-BN (hexagonal boron nitride) + $H_2$, successful fabrication of BNNTs synthesized from $h-BN+NH_4Cl$ is confirmed by their sheet-like properties, FE-SEM images, and XRD analysis. In addition, improved dispersion properties in aqueous solution are found in BNNTs synthesized from $h-BN+NH_4Cl$.

• Elastomers and Composites
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• 제50권2호
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• pp.110-118
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• 2015

In this study, diethylaminoethyl methacrylate-styrene-butadiene terpolymer (DEAEMA-SBR), in which diethylaminoethyl methacrylate (DEAEMA) was introduced to the SBR molecule as a third monomer, was synthesized by cold emulsion polymerization. It is expected that amine group introduced to a rubber molecule would improve dispersion of silica by the formation of hydrogen bond (or ionic coupling) between the amine group and silanol groups of silica surface. The chemical structure of DEAEMA-SBR was analyzed using proton nuclear magnetic resonance spectroscopy (H-NMR), Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC) and differential scanning calorimetry (DSC). Then, various properties of DEAEMA-SBR/silica composite such as crosslink density, bound rubber content, abrasion resistance, and mechanical properties were evaluated. As a result, bound rubber content and crosslink density of DEAEMA-SBR/silica compound were higher than those of the SBR 1721 composite. Abrasion resistance and moduli at 300% elongation of the DEAEMA-SBR/silica composite were better than those of SBR 1721 composite due to the high bound rubber content and crosslink density. These results are attributed to high affinity between DEAEMA-SBR and silica. The proposed study suggests that DEAEMA-SBR can help to improve mechanical properties and abrasion resistance of the tire tread part.

• 폴리머
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• 제37권4호
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• pp.507-512
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• 2013

수분산 폴리우레탄(waterborne polyurethane; WPU)의 물리화학적/전기적 특성을 개선하기 위하여 그래핀에 이소시아네이트기를 도입하고 in-situ 방법으로 폴리우레탄을 중합하여 그래핀/WPU 나노 복합체를 제조하였다. 본 연구의 접근 방법으로 그래핀을 2 wt%까지 그래핀/WPU 나노 복합체에 도입하면 기존 WPU에 비해 인장강도가 57%, 전기전도도는 약 $10^2$배 정도 향상되는 결과를 얻었다. 또한 단순 블렌드 방법으로 만든 그래핀/WPU 복합체와 비교하였을 때, in-situ 중합 방법으로 제조된 복합체가 상대적으로 우수한 기계적 물성과 전기 전도도를 가졌다. 이것은 전자현미경을 이용한 복합체 단면의 형태학적 분석으로부터 이소시아네이트기가 개질된 그래핀(iGO)이 in-situ 중합 방법에 기인한 WPU 매트릭스와의 공유결합과 수소결합을 통하여 균일하게 분산되었기 때문이다.

• 한국재료학회지
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• 제25권1호
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• pp.27-31
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• 2015

This paper proposes a novel way of fabricating aligned porous Sn by freeze-drying of camphene slurry with stannic oxide ($SnO_2$) coated Sn powders. The $SnO_2$ coated Sn powders were prepared by surface oxidation of the initial and ball-milled Sn powders, as well as heat treatment of tin chloride coated Cu powders. Camphene slurries with 10 vol% solid powders were prepared by mixing at $50^{\circ}C$ with a small amount of oligomeric polyester dispersant. Freezing the slurry was done in a Teflon cylinder attached to a copper bottom plate cooled at $-25^{\circ}C$. Improved dispersion stability of camphene slurry and the homogeneous frozen body was achieved using the oxidized Sn powder at $670^{\circ}C$ in air after ball milling. The porous Sn specimen, prepared by freeze-drying of the camphene slurry with oxidized Sn powder from the heat-treated Sn/tin chloride mixture and sintering at $1100^{\circ}C$ for 1 h in a hydrogen atmosphere, showed large pores of about $200{\mu}m$, which were aligned parallel to the camphene growth direction, and small pores in their internal walls. However, $100{\mu}m$ spherical particles were observed in the bottom part of the specimen due to the melting of the Sn powder during sintering of the green compact.

• 한국가스학회지
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• 제17권5호
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• pp.22-27
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• 2013

수소와 CNG를 혼합한 HCNG는 CNG에 비해 연소효율이 높고 보다 친환경적인 연료로 CNG 엔진의 다음 단계의 엔진으로 각광받고 있으며, 수소시대로의 가교역할을 할 것이라 전망된다. 2014년 EURO-6의 도입으로 CNG 및 HCNG 차량에서 발생되는 메탄가스에 대해서도 규제가 이루어질 전망이다. 본 연구에서는 HCNG 엔진의 배기가스 중 메탄가스를 저감하기 위한 메탄산화촉매를 다루었다. 메탄산화촉매의 장시간 운전에 따른 내구성 및 메탄산화 양상 등에 대해 연구했으며, 이 때 촉매의 화학적인 현상을 분석하기 위해 촉매의 중요한 인자인 귀금속 분산도, 비표면적 변화 등을 촉매 활성과 연계하여 연구하였다.

• 멤브레인
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• 제29권1호
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• pp.30-36
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• 2019

본 연구에서는 titanium nitride (TiN) 나노 섬유와 poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) 전도성 고분자로 이루어진 전극과 poly(vinyl alcohol) (PVA) 기반 고분자 전해질 분리막을 이용하여 슈퍼 캐퍼시터를 제조하였다. TiN 나노 섬유의 경우 높은 전기 전도도와 이차원적 구조로 인한 스케폴드 효과를 기대할 수 있다는 점에서 전극 물질로 사용되었다. PEDOT-PSS 전도성 고분자는 수소 이온과 산화-환원 반응을 통해 보다 높은 정전용량을 나타낼 수 있으며 용액상에 분산이 용이해 유무기 복합제를 형성하기에 적합하였다. PVA 기반의 고분자 전해질 분리막은 기존의 액상의 전해질의 문제인 외부 충격에 대한 안정성을 확보할 수 있으며 염으로 사용된 $H_3PO_4$의 경우 수소 이온은 빠른 확산으로 인해 캐퍼시터의 충방전 효율에 이점이 있다. 본 연구에서 보고된 PEDOT-PSS/TiN 슈퍼캐퍼시터의 정전용량은 약 75 F/g으로 기존의 탄소기반 캐퍼시터에 비해 큰 폭으로 증가한 값이다.

• 천문학회보
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• 제45권1호
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• pp.61.4-62
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• 2020

We present H I gas kinematics and star formation activities of NGC 6822, a dwarf galaxy located in the Local Volume at a distance of ~490 kpc. We perform profile decomposition of the line-of-sight velocity profiles of the high-resolution (~42.4" × 12") spatial; ~1.6 km/s spectral) H I data cube taken with the Australia Telescope Compact Array (ATCA). For this, we use a new tool, the so-called BAYGAUD (BAYesian GAUssian Decompositor) which is based on Bayesian Markov Chain Monte Carlo (MCMC) techniques, allowing us to decompose a line-of-sight velocity profile into an optimal number of Gaussian components in a quantitative manner. We classify the decomposed H I gas components of NGC 6822 into kinematically cold, warm or hot ones with respect to their velocity dispersion: 1) cold: < 4 km/s, 2) warm: 4 ~ 8 km/s, 3) hot: > 8 km/s. We then derive the Toomre-Q parameters of NGC 6822 using the kinematically decomposed H I gas maps. We also correlate their gas surface densities with the surface star formation rates derived using both GALEX far-ultraviolet and WISE 22 micron data to examine the impact of gas turbulence caused by stellar feedback on the Kennicutt-Schmidt (K-S) law. The kinematically cold component is likely to better follow the linear extension of the Kennicutt-Schmidt (K-S) law for molecular hydrogen (H2) at the low gas surface density regime where H I is not saturated.

• 비파괴검사학회지
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• 제35권1호
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• pp.46-51
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• 2015

스테인레스강은 고온, 고압에서 부식에 효과적인 재료로써 액화수소, 가스 등을 저장하는 저장용기 및 고온의 유체들을 이송하는 배관재료로 널리 사용되고 있다. 일반적으로 스테인레스강의 용접은 TIG용접이 이용되어지고 있으며 용접후 용접부위에 발생하는 초기 용접결함 및 사용중 발생하는 열적 피로균열 등이 재료의 신뢰성을 저하하는 요인들로 지적되고 있다. 본 논문에서는 레이저 유도초음파를 이용하여 초기 용접결함에 대한 초음파 특성 규명을 위하여 스테인레스강의 용접부에 인공균열의 크기를 5 mm, 10 mm, 20 mm 길이로 가공후 유도초음파의 결함 길이 변화에 따른 특성을 평가하였다. 배관의 두께 등을 고려하여 L(0,1)모드와 L(0,2)모드를 이용하였으며 각각의 모드가 결함의 길이 변화에 따라 변화를 보였지만 L(0,2)모드가 L(0,1)모드보다 결함 길이에 더욱 민감하게 반응하였다. 본 연구에서는 L(0,1)모드와 L(0,2)모드의 진폭비를 구하여 결함과의 연관성을 평가한 결과 결함 길이와 선형적인 관계를 나타냄으로써 각 모드를 단독적으로 평가하는 것보다는 두 모드의 진폭비를 이용하여 결함을 평가하는 것이 더욱 효과적임을 알 수 있었다.

• 한국염색가공학회지
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• 제1권1호
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• pp.19-25
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• 1989

In past, dye diffusion and dyeing rate in fibers have been emphasized in dyeing phenomena. However, in the light of the properties of colloids in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Electrostatic bonding, hydrogen bonding and Van der Waals adsorption are common in dyeing as well as covalent bonding. Particularly, electrostatic bonding is premised on the existance of ionic radicals in fibers. The present study was aimed to clarify the electrokinetic phenomena of dyeing through the role of electric double layer by ion in amphoteric fibers with different ionic effects under different pH. Spectrophotometric analysis method was used to compare dyeing condition of surface, which can be detected by electrokinetic phenomena and the inner of fibers after deceleration of dyed fibers. Nylon and wool, the typical amphoteric fibers were dyed with monoazo acid dyes such as C.I. Acid Orange 20, and C.I. Acid Orange 10. Various combinations were prepared by combining pH, temperature and dye concentration, in order to generate streaming electric potential which were measured by microvolt meter and specific conductivity meter. The results were transformed to zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers. The amount of dyes of inner fibers were also measured by the Lambert-Beer’s law. The main results obtained are as follows. 1. By measuring zeta pontential, it was possible to detect the dyeing mechanism, surface charge density, surface dye amount and effective surface area concerning dye adsorption of the amphoteric fibers. 2. Zeta pontential increases in negative at low pH and high dye concentration in the process of dyeing. This implied that there existed ionic bond formation in the dyeing mechanism between acid dyes and amphoteric fibers. 3. Dibasic acid dye had little changing rate in zeta potential due to the difference in solubility of dye and in number of dissociated ions per dye molecule to bond with amino radicals of amphoteric fibers. The dye adsorption of mono basic acid dye was higher than that of dibasic acid dye. 4. The effective surface areas concerning dyeing were $6.3E+05\;cm^2/g$ in nylon, $1.6E+07\;cm^2/g$ in wool fiber being higher order of wool then nylon.