• 대한원격탐사학회지
• /
• 제37권3호
• /
• pp.591-601
• /
• 2021

국내의 화학 산업이 지속적으로 발전이 이루어짐에 따라 화학물질의 취급량과 운송량은 매년 증가하고 있다. 우리나라 도로 화물운송은 90%이상을 차지하고 있으며, 화학물질 운송도 대부분 도로를 통해 이루어지고 있다. 이러한 화학물질 운송차량들은 사고가 발생하게 되면 대형사고로 이어질 수 있다. 운송차량은 1차 피해인 교통사고뿐만 아니라 2차 피해인 환경 피해 요인들인 수질오염, 토양오염 등을 발생시킬 가능성이 높다. 본 연구는 반포IC와 서초IC 구간을 연구지역으로 설정하여 염화수소 가스 누출에 대한 시나리오를 작성하여, ALOHA 프로그램을 사용하여 예측거리를 측정하고 거리에 따라 염화수소 가스가 도달한 시간을 분석하였다. 또한 GIS를 이용해 시간별로 발생한 피해 영역에 대해서 인구밀도를 이용한 리스크 평가를 수행하였다. 이를 통해 피해 영역에 대해서 예방·대응 방안의 필요성을 제시하였다.

• 한국위험물학회지
• /
• 제2권1호
• /
• pp.6-11
• /
• 2014

There have been frequent chemical leaks over the past 10 years. Particularly, inorganic acids like sulfuric acid, nitric acid, and hydrogen chloride take up 37 % of the total chemical accidents which took place for the past 10 years. When an acid chemical leak happens, fume is generated, diffusing into the air, which might cause serious damage to health of local residents and the environment. However, most of the acid-based chemicals, detecting and analysis methods have not been settled considering the frequency of accidents. In this study, we investigated detection and analysis methods to quickly analyze accident sites and evaluate the impacts on environments. Reviewing local and international test analysis methods of acids suggested that nitric acid, sulfuric acid, hydrogen chloride and hydrogen fluoride can be analyzed with IC. It was also found that UV is better for the analysis of hydrogen fluoride and GC/MS for acrylic acid. The analytical methods suggested in the official test methods basically have limitations of consuming much time at stages of preparation and analysis. Considering prompt responses to chemical accidents, further studies should be done to compare the applicability of rapid monitoring methods such as FT-IR, IMR-MS and SIFT-MS.

• 한국원자력학회:학술대회논문집
• /
• 한국원자력학회 1997년도 추계학술발표회논문집(1)
• /
• pp.495-500
• /
• 1997

For hydrogen management in severe accidents with degraded nuclear core of PWR's, several experiments have been performed in the SNU hydrogen mixing facility. The objectives are understanding the extent of hydrogen mixing and analyzing the effects of factors which dominate uniform or non-uniform mixing at compartments in the containment building. The facility represents on a 1/11th linearly scaled model of the YGN unit 3&4, hydrogen was simulated by helium. Because there are the gaps between safety injection tank and compartment layers in the containment, the test facility was constructed in three dimentinal mode for analyzing of mixture behavior through the gaps. From the experimental results we could conclude that overall hydrogen concentration distributed uniformly in the free volume of the test compartment, but fluctuated in the gaps. This paper is focused on experimental result from several experiment.

• 한국가스학회지
• /
• 제20권3호
• /
• pp.12-21
• /
• 2016

화석연료의 의존도를 줄이고자 대체에너지 연구가 활발하게 이루어지고 있는 현재, 산업에서 가장 많이 사용하고 있는 대체에너지 중 하나가 수소이다. 수소의 수요는 매년 꾸준히 증가하고 있으며, 수소의 생산 및 이송을 위한 설비도 늘어나고 있는 실정이다. 이에 따른 수소설비에서 중대사고가 발생할 확률 또한 증가할 것으로 예상된다. 또한 산업현장에서 가장 사고를 많이 초래하는 물질은 LPG 61%, 수소 12%, LNG 10%로 세 가지 가연성가스의 사고 빈도는 높은 축에 속한다. 따라서 산업용으로 많이 사용되며 사고다발성 가연성 가스인 수소, LNG, LPG가 제한된 공간에서 폭발했을 때의 폭발위험성에 대하여 CFD 시뮬레이션을 이용하여 계산을 하였고, 그 결과들을 기반으로 비교분석하여, 제한된 공간에서의 각 가스별 폭발에 대한 위험성을 검토하였다.

• 한국수소및신에너지학회논문집
• /
• 제34권3호
• /
• pp.297-306
• /
• 2023

The frequency of fatal accidents that can occur at hydrogen refueling station was compared with the risk criterion for the general public suggested by the health and safety executive. If hydrogen refueling station meets the accident prevention facility standards presented in KGS Code FP216/217, it was confirmed that the risk of hydrogen refueling station was not at an unacceptable (intolerable) risk level. However, the risk of hydrogen refueling station due to small leak was analyzed as low as reasonably practicable. Therefore, methods for improving the safety instrumented function of hydrogen refueling station were reviewed. It was confirmed that the risk of hydrogen refueling station can be affected by the number of installed safety instrumentation system components, redundant architecture, mission time, proof test interval, etc. And methods for maintaining the risk of hydrogen refueling station at an acceptable risk level have been proposed.

• 한국가스학회지
• /
• 제16권1호
• /
• pp.15-21
• /
• 2012

수소가스의 제트 누출에 의한 확산, 화재, 그리고 폭발에 의한 위험 범위를 분석하고, 안전거리 기준을 설정하기 위한 위험거리를 확산, 화재, 그리고 폭발에 대한 단순한 예측 식들을 제시하였다. 핀홀에 의한 누출과 같은 소량 수소가스 누출속도에 있어서 피해거리는 제트누출 확산에 의한 피해거리가 제트화재에 의한 피해거리보다 크며, 압력의 제곱근에 그리고 누출 홀의 직경에 비례하고 이는 수 십 미터에 이른다. 배관의 완전 파손 또는 저장 탱크의 큰 홀 발생과 같은 대량의 수소가스 누출속도에서는 제트화재의 피해거리가 개방공간의 가스운 폭발에 의한 피해거리보다 크며, 수 백 미터에 이른다. 수소충전소와 건물과의 최소이격거리 즉 안전거리 설정 기준을 대량 수소가스누출 사고시나리오를 기반으로 한다면, 도심지에 수소충전소는 안전거리 기준을 만족시키기 어려울 것이다. 따라서 대량의 수소가스 누출사고를 안전장치들을 통하여 예방하고, 안전거리 기준을 소량의 수소가스누출사고 기준으로 설정 할 수 있다. 그러나 대량누출 가능성이 있는 경우 학교와 병원 등 인구밀집 건물은 수 백 미터의 안전거리를 유지하여야 한다.

• 한국수소및신에너지학회논문집
• /
• 제31권1호
• /
• pp.73-81
• /
• 2020

For the fault tree analysis (FTA) analysis of the packaged hydrogen filling station, the composition of the charging station was analyzed and the fault tree (FT) diagram was prepared. FT diagrams were created by dividing the causes of events into external factors and internal factors with the hydrogen event as the top event. The external factors include the effects of major disasters caused by natural disasters and external factors as OR gates. Internal factors are divided into tube tailer, compressor & storage tank, and dispenser, which are composed of mistakes in operation process and causes of accidents caused by parts leakage. In this study, the purpose was to improve the hydrogen station. The subjects of this study were domestic packaged hydrogen stations and FTA study was conducted based on the previous studies, failure mode & effect analysis (FMEA) and hazard & operability study (HAZOP). Top event as a hydrogen leaking event and constructed the flow of events based on the previous study. Refer to "Off shore and onshore reliability data 6th edition", "European Industry Reliability Data Bank", technique for human error rate prediction (THERP) for reliability data. We hope that this study will help to improve the safety and activation of the hydrogen station.

• 대한안전경영과학회지
• /
• 제16권4호
• /
• pp.159-165
• /
• 2014

For the hydrogen economy system being tried starting with the 21st century, the fields that was not dealt with so far, such as the safety measure for large leakage accidents, the safety problem at infrastructures like a hydrogen station, the safety problem in terms of automobiles depending on introduction of hydrogen cars, the safety problem in a supply for homes like fuel cells, etc., are being deeply reviewed. In order to establish a safety control system, an essential prerequisite in using and commercializing hydrogen gas as an efficient energy source, it is necessary to conduct an analysis, such as analysis of hydrogen accident examples, clarification of physical mechanisms, qualitative and quantitative evaluation of safety, development of accident interception technologies, etc. This study prepared scenarios of hydrogen gas leakage that can happen at hydrogen stations, and predicted damage when hydrogen leaks by using PHAST for this.

• Nuclear Engineering and Technology
• /
• 제17권1호
• /
• pp.53-67
• /
• 1985

중대 노심사고는 아직 Design Basis Accident에 포함되지 않고 있으나, 극히 적은 사고 확률을 가지는 반면 사고 후 영향이 큼으로해서 원자력발전소의 전반적 위험 평가에 중요한 요인중의 하나가 되고 있다. 중대 노심사고시 격납용기 손상에 관련된 물리현상들은 Steam Explosion, Debris Bed Coolability, Hydrogen Burning, Steam Spike와 Core-Concrete Interaction 등이며, 각각의 현상에 대한 좀 더 나은 이해를 위해 현재 이루어지고 있는 연구들에 대한 개략적 설명을 시도 하였다.

• 한국수소및신에너지학회논문집
• /
• 제33권3호
• /
• pp.232-239
• /
• 2022

This study performed qualitative and quantitative risk assessment of equipment for evaluating the protocol of hydrogen refueling stations and suggested measures to improve safety. Hazard and operability study was performed for qualitative risk assessment, and Hy-KoRAM was used for quantitative risk assessment. Through a qualitative risk assessment, additional ventilation devices were installed, simultaneous venting of the storage container was prohibited, and the number of repeated refilling of the evaluation equipment was identified to manage the number of fillings of the container. Through quantitative risk assessment, the area around the device was set as a restricted area when evaluating the station, and measures were suggested to reduce the frequency of accidents.