• Title/Summary/Keyword: Hydrogen Transfer

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STaRS Gen 2: Sejong Radiative Transfer through Raman and Rayleigh Scattering in Dusty Medium

  • Chang, Seok-Jun;Lee, Hee-Won;Seon, Kwang-Il
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.81.2-81.2
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    • 2021
  • Emission features formed through Raman scattering with atomic hydrogen provide unique and crucial information to probe the distribution and kinematics of a thick neutral region illuminated by a strong far-ultraviolet radiation source. We introduce a new 3-dimensional Monte-Carlo code to describe the radiative transfer of line photons subject to Raman and Rayleigh scattering with atomic hydrogen. In our Sejong Radiative Transfer through Raman and Rayleigh Scattering (STaRS) code, the position, direction, wavelength, and polarization of each photon is traced until escape. The thick neutral scattering region is divided into multiple cells. Each cell is characterized by its velocity and density, which ensures flexibility of the code in analyzing Raman-scattered features formed in a neutral region with complicated kinematics and density distribution. We are continuously developing STaRS to adopt the absorption and scattering effect by dust. This presentation introduces STaRS and its current state and study.

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Effects of Plate Pitch and Chevron Angle in a Plate Heat Exchanger on Thermal Energy Performance (판형 열교환기의 피치 및 세브론각이 열에너지 성능에 미치는 영향)

  • Kang, Byung Ha;Han, Sang Kyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.3
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    • pp.194-200
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    • 2004
  • Thermal energy performance of a brazed plate heat exchanger has been evaluated experimentally. The effects of plate pitch as well as chevron angle of a plate heat exchanger on the heat transfer rate and pressure drop have been investigated in the wide range as mass flow rates in detail. This problem is of particular interest in the design of a plate heat exchanger. The results obtained indicate that both heat transfer rate and pressure drop are increased as mass flow rate is increased, as expected. It is also found that the heat transfer rate is increased with a decrease in the plate pitch while the heat transfer is decreased with a decrease in the chevron angle. Friction factor correlations are suggested based on the measured pressure drop and effectiveness of plate heat exchangers are also compared.

Selection of Oxygen Carrier Candidates for Chemical Looping Combustion by Measurement of Oxygen Transfer Capacity and Attrition Loss (산소전달량 및 마모손실 측정에 의한 매체순환연소용 산소전달입자 후보 선정)

  • KIM, HANA;PARK, JAEHYEON;BAEK, JEOM-IN;RYU, HO-JUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.4
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    • pp.404-411
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    • 2016
  • To select appropriate oxygen carrier candidates for chemical looping combustion, reduction characteristics of seven oxygen carriers were measured and discussed using three different reduction gases, such as $H_2$, CO, and $CH_4$. Moreover, attrition losses of those oxygen carriers also measured and compared. Among seven oxygen carrier particles, OCN703-1100 and NiO/bentonite particles showed higher oxygen transfer capacity than other particles, but these particles showed more attrition loss than other particles. C14 and C28 particles which used as cheap oxygen carriers in European country showed lower oxygen transfer capacity and less attrition loss. Based on the experimental results, we could select OCN717-R1SU, NC001, and N002 particles as candidates for future works because these oxygen carriers showed enough oxygen transfer capacity and good attrition resistance.

Evaporation Heat Transfer and Pressure Drop of Carbon Dioxide In a Horizontal Tube (수평관내 이산화탄소의 증발 열전달과 압력강하)

  • Son, Chang-Hyo
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.2
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    • pp.189-196
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    • 2007
  • The evaporation heat transfer coefficient and pressure drop of $CO_2$(R-744) in a horizontal tube was investigated experimentally. The main components of the experimental apparatus are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and an evaporator(test section). The test section consists of a horizontal stainless steel tube of 4.57 mm inner diameter. The experiments were conducted at mass flux of $200{\sim}1000\;kg/m^2s$ saturation temperature of $0{\sim}20^{\circ}C$, and heat flux of $10{\sim}40\;kW/m^2$. The test results showed that the heat transfer coefficient of $CO_2$ has a greater effect on nucleate boiling more than convective boiling. Mass flux of $CO_2$ does not affect nucleate boiling too much. In comparison with test data and existing correlations, All of the existing correlations for the heat transfer coefficient underestimated the experimental data. However lung et al.'s correlation showed a good agreement with the experimental data. The evaporation pressure drop of $CO_2$ increases with increasing mass flux and decreasing saturation temperature. When comparison between the experimental pressure drop and existing correlations. Existing correlations failed to predict the evaporation pressure drop of $CO_2$.

The Study of Heat Transfer on a Isothermal Circular Surface by an Impinging, Circular Water Jets with the Low Velocity Against the Direction of Gravity (중력방향과 대향류인 저속 원형노즐제트 충돌에 의한 일정 두께 하향 등온원형평판에서의 열전달 현상)

  • Eom, Yongkyoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.449-458
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    • 2014
  • The heat transfer phenomenon was investigated in this study when a single round water jet with the low velocity and against the direction of gravity flows to the downward facing Isothermal of definite thickness circular plate. Experimental investigation is performed for a single round jet diameter 4mm, 6mm, and 8mm with the jet velocity 2.4m/s and jet fluid temperature of $24^{\circ}C$, varied the ratio of nozzle clearance/nozzle diameter (H/D)1, 2, 3, 6, and 8, on circular plate isothermal condition with $85^{\circ}C$. The local convection heat transfer coefficient distributions are analyzed based on the visualization of jet flow field. The effects of the diameter of Nozzle, the ratio of H/D and the ratio of nozzle diameter/circular plate diameter on heat transfer phenomenon are investigated. As a results of experiment is obtained correlation equation, $Nu_r=3.18Re_r^{0.55}Pr_r^{0.4}$.

Platinum Decoration of a 3D Oxidized Graphitic Carbon Nitride/Graphene Aerogel for Enhanced Visible-Light Photocatalytic Hydrogen Evolution

  • Thi Kieu Oanh Nguyen;Thanh Truong Dang;Tahereh Mahvelati-Shamsabadi;Jin Suk Chung
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.627-634
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    • 2023
  • Graphitic carbon nitride (g-C3N4) has attracted considerable attention since its discovery for its catalysis of water splitting to hydrogen and oxygen under visible light irradiation. However, pristine g-C3N4 confers only low photocatalytic efficiency and requires surface cocatalysts to reach moderate activity due to a lack of accessible surface active sites. Inspired by the high specific surface area and superior electron transfer of graphene, we developed a strongly coupled binary structure of graphene and g-C3N4 aerogel with 3D porous skeleton. The as-prepared 3D structure photocatalysts achieve a high surface area that favors efficient photogenerated charge separation and transfer, enhances the light-harvesting efficiency, and significantly improves the photocatalytic hydrogen evolution rate as well. The photocatalyst performance is observed to be optimized at the ratio 3:7 (g-C3N4:GO), leading to photocatalytic H2 evolution of 16125.1 mmol. g-1. h-1 under visible light irradiation, more than 161 times higher than the rate achieved by bulk g-C3N4.

Coupled Analysis of Hydrogen Transport Within ABAQUS (ABAQUS 를 이용한 수소확산 해석)

  • Oh, Chang-Sik;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.6
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    • pp.600-606
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    • 2009
  • In this paper, the coupled model with hydrogen transport and elasto-plasticity behavior is introduced. This model is implemented to the general-purpose FE code, ABAQUS, via the user-defined subroutine UMAT and UMATHT. In UMAT, the spatial gradients of hydrostatic stress and hydrogen induced deformation are calculated, and then are passed into UMATHT. Heat transfer equation within UMATHT is substituted by hydrogen transport equation including the effects of stress states and strain hardening. To validate this model, the finite element analyses coupled with hydrogen transport and mechanical loading are performed for the boundary layer specimens with low and high strength steel properties. The FE results are compared with the previous studies by Taha and Sofronis (2001).

A Development of a Transient Hydrogen Generation Model for Metal-Water Interactions

  • Lee, Jin-Yong;Park, Goon-Cherl;Lee, Byung-Chul
    • Nuclear Engineering and Technology
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    • v.32 no.6
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    • pp.549-558
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    • 2000
  • A transient model for hydrogen generation in molten metal-water interactions was developed with separate models for two stages of coarse mixing and stratification. The model selves the mechanistic equations (heat and mass transfer correlation, heat conduction equation and the concentration diffusion equation) of each stage with non-zero boundary conditions. Using this model, numerical simulations were performed for single droplet experiments in the Argonne National Laboratory tests and for FITS tests that simulated dynamic fragmentation and stratification. The calculation results of hydrogen generation showed better agreement to the experiment data than those of previous works. It was found from the analyses that the steam concentration to be reached at the reaction front might be the main constraint to the extent of the metal droplet oxidized. Also, the hydrogen generation rate in the coarse mixing stage was the higher than that in the stratification stage. The particle size was the most important factor in the coarse mixing stage to predict the amount of hydrogen generation.

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Hydrogen Transport through Palladium Foil Placed in Nafion Electrolyte of H2/O2 Fuel Cellsorption

  • Song, Seong-Min;Koo, Il-Gyo;Lee, Woong-Moo
    • Transactions of the Korean hydrogen and new energy society
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    • v.12 no.4
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    • pp.257-265
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    • 2001
  • Placing a hydrogen conducting, methanol impermeable metallic barrier like palladium (Pd) is a well-known method for preventing methanol crossover through solid polymer electrolyte for direct methanol fuel cells (DMFC). Applying a bias potential between the anode and the barrier can further develop this concept so that the hydrogen transfer rate is enhanced. Since hydrogen diffuses in Pd as atomic form while it moves through nafion electrolyte as ion, it has to be reduced or oxidized whenever it passes the interface formed by Pd and the electrolyte. We performed experiments to measure the hydrogen transport through the Pd membrane placed in Nafion electrolyte of hydrogen/oxygen fuel cell (PEMFC). Applying a bias potential between the hydrogen electrode of the cell and the Pd membrane facilitated the hydrogen passage through the Pd membrane. The results show that the cell current measured with the Pd membrane placed reached almost 40 % the value measured with the cell without Pd membrane. It was found that the current flown through the bias path is only a few percent of the cell current.

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A Study on Ammonia Reforming Catalyst and Reactor Design for 10 kW Class Ammonia-Hydrogen Dual-Fuel Engine (10 kW 급 암모니아-수소 혼소엔진을 위한 암모니아 개질 촉매 및 반응기 설계에 관한 연구)

  • LEE, SANGHO;CHOI, YOUNG;PARK, CHEOLWOONG;KIM, HONGSUK;LEE, YOUNG DUK;KIM, YOUNG SANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.4
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    • pp.372-379
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    • 2020
  • Ammonia-hydrogen dual-fuel engine is a way to reduce greenhouse gas emission because ammonia and hydrogen are carbon-free fuels. In ammonia-hydrogen dual-fuel engine, hydrogen is supplied to improve the combustion characteristic of ammonia. In this study, an ammonia reformer was developed to supply hydrogen for 10 kW class ammonia-hydrogen dual-fuel engine. Thermodynamic characteristic and catalyst were investigated for ammonia reforming. Heat transfer was important for high ammonia conversion of ammonia reformer. 99% of ammonia conversion was obtained when 10 LPM of ammonia and 610℃ of hot gas were supplied to the ammonia reformer.