• 천문학회보
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• 제35권2호
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• pp.43.1-43.1
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• 2010

A novel method to characterize the topology of the early-universe intergalactic medium during the epoch of cosmic reionization is presented. The 21-cm radiation background from high redshift is analyzed through calculation of the 2-dimensional (2D) genus. The radiative transfer of hydrogen-ionizing photons and ionization-rate equations are calculated in a suite of numerical simulations under various input parameters. The 2D genus is calculated from the mock 21-cm images of high-redshift universe. We construct the 2D genus curve by varying the threshold differential brightness temperature, and compare this to the 2D genus curve of the underlying density field. We find that (1) the 2D genus curve reflects the evolutionary track of cosmic reionization and (2) the 2D genus curve can discriminate between certain reionization scenarios and thus indirectly probe the properties of radiation-sources. Choosing the right beam shape of a radio antenna is found crucial for this analysis. Square Kilometer Array (SKA) is found to be a suitable apparatus for this analysis in terms of sensitivity, even though some deterioration of the data for this purpose is unavoidable under the planned size of the antenna core.

• 천문학회보
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• 제43권1호
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• pp.63.4-64
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• 2018

High resolution spectroscopy of the yellow symbiotic star AG Draconis is performed with the Canada-France-Hawaii Telescope to analyse the line profiles of Raman scattered O VI broad emission features at $6825{\AA}$ and $7082{\AA}$ with a view to investigating the wind accretion process from the mass losing giant to the white dwarf. These two spectral features are formed through inelastic scattering of O $VI{\lambda}{\lambda}32$ and 1038 with atomic hydrogen. We find that these features exhibit double-component profiles with red parts stronger than blue ones with the velocity separation of ~ 60 km s-1 in the O VI velocity space. Monte Carlo simulations for O VI line radiative transfer are performed by assuming that the O VI emission region constitutes a part of the accretion flow around the white dwarf and that Raman O VI features are formed in the neutral part of the slow stellar wind from the giant companion. The overall Raman O VI profiles are reasonably fit with an azimuthally asymmetric accretion flow and the mass loss rate ~ 4 ${\times}$ 10^{-7} M_sun yr^{-1}. We also find that additional bipolar neutral regions moving away with a speed ~ 70 km s^{-1} in the directions perpendicular to the orbital plane provide considerably improved fit to the red wing parts of Raman features.

• 한국해양공학회지
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• 제34권2호
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• pp.110-119
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• 2020

Explosions and fires on offshore drilling units and process plants, which cause loss of life and environmental damage, have been studied extensively. However, research on drilling units increased only after the 2010 Deepwater Horizon accident in the Gulf of Mexico. A major reason for explosions and fires on a drilling unit is blowout, which is caused by a failure to control the high temperatures and pressures upstream of the offshore underwater well. The area susceptible to explosion and fire due to blowout is the drill floor, which supports the main drilling system. Structural instability and collapse of the drill floor can threaten the structural integrity of the entire unit. This study simulates the behavior of fire subsequent to blowout and assesses the thermal load. A heat transfer structure analysis of the drill floor was carried out using the assessed thermal load, and the risk was noted. In order to maintain the structural integrity of the drill floor, passive fire protection of certain areas was recommended.

• Advances in nano research
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• 제2권2호
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• pp.77-88
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• 2014

Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

• 한국염색가공학회지
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• 제26권4호
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• pp.305-310
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• 2014

In this study, we presented a newly synthesized pyrene-naphthalene diimide(NDI)-pyrene triad. The optical and structural properties were examined using various characterization techniques. A donor-acceptor-donor triad molecule exhibited a strong charge transfer, though there existed neither intramolecular nor intermolecular hydrogen bonding sites, due to the formation of preferential complementary complex between pyrene and NDI. Powder XRD measurement revealed a sharp and distinctive X-ray patterns, indicating the presence of microcrystalline-like structure. POM images showed anisotropic fingerprint texture similar to that of cholesteric phase, and SEM images showed numerous columnar structures with length of 1 to $10{\mu}m$. Above observation clearly demonstrated that ${\pi}$-complementary NDI-pyrene interactions in the traid was strong enough to form columnar aggregates in the long range.

• 센서학회지
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• 제21권1호
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• pp.46-52
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• 2012

The rapid water pollution in stream, river, lake and sea in recent years raises an urgent need for continuous monitoring and policymaking to conserve the global clean environment. In particular, the increasing water pollution in coastal marine areas adds to the importance of the environmental monitoring systems. In this paper, the mobile server is designed to gathers information of the water quality at coastal areas. The obtained data by the server is transmitted from field servers to the base station via multi-hop communication in wireless sensor network. The information collected includes dissolved oxygen(DO), hydrogen ion exponent(pH), temperature, etc. By the information provided the real-time monitoring of water quality at the coastal marine area. In addition, wireless sensor network-based flooding routing protocol was designed and used to transfer the measured water quality information efficiently. Telosb sensor node is programmed using nesC language in TinyOS platform for small scale wireless sensor network monitoring from a remote server.

• 센서학회지
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• 제20권1호
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• pp.35-39
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• 2011

A disposable electrochemical immunosensor system has been developed for the detection of herbicide in aqueous samples. Disposable screen printed carbon electrodes(SPCE) were used as basic electrodes and an enzyme, horseradish peroxidase (HRP), and anti-herbicide antibodies was immobilised on to the working electrode of SPCE by using avidin-biotin coupling reactions. An herbicide-glucose oxidase conjugates have been used for the competitive immunoreaction with sample herbicides. The enzymatic reaction between the conjugated glucose oxidase and glucose added generates hydrogen peroxide, which was reduced by the peroxidase immobilised. The latter process caused an electrical current change, due to direct re-reduction of peroxidase by a direct electron transfer mechanism, which was measured to determine the herbicides in the sample. The optimal operational condition was found to be: $20\;{\mu}gl-1$ deglycosylated avidin loading to the working electrode and working potential +50 mV vs. Ag/AgCl. The total assay time was 15 min after sample addition. The detection limits for herbicides, atrazine and simazine, were found to be 3 ppb and 10 ppb, respectively.

• International Journal of Advanced Culture Technology
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• 제3권1호
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• pp.31-38
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• 2015

Coking accumulations via dry methane reforming (DMR) over 10NAM monolithic catalyst and pelletized catalyst was investigated. 10NAM catalyst was synthesized and coated on a wall of monolithic reactor. Pelletized catalyst of 10NAM was also prepared for the comparison. Consequently, catalyst was characterized by BET, $H_2-TPR$ and $H_2-TPD$. The catalytic reaction was undergone at $600^{\circ}C$ under atmospheric pressure and $CH_4$ to $CO_2$ reactant ratio of 1:2. The coking formation over spent catalyst was then carried out in the hydrogen flow using temperature programmed technique (TPH). According to the results, DMR over 10NAM monolithic catalyst exhibits a minimized coking formation comparing to the use of pelletized catalyst. This could be attributed to a prominent heat transfer efficiency of the monolithic catalyst.

• Bulletin of the Korean Chemical Society
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• 제29권7호
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• pp.1323-1325
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• 2008

The acetylene black (AB) was dispersed into water in the presence of dihexadecyl hydrogen phosphate (DHP) via ultrasonication, resulting in a stable and well-distributed AB/DHP suspension. After evaporation of water, an AB/DHP composite film-modified electrode was prepared. The electrochemical responses of $K_3$[Fe$(CN)_6$] at the unmodified electrode, DHP film-modified electrode and AB/DHP film-modified electrode were investigated. It is found that the AB/DHP film-modified electrode possesses larger surface area and electron transfer rate constant. Furthermore, the electrochemical behaviors of 1-naphthylacetic acid (NAA) were examined. At the AB/DHP film-modified electrode, the oxidation peak current of NAA remarkably increases. Based on this, a sensitive and convenient electrochemical method was proposed for the determination of NAA. The linear range is in the range from $4.0 {\times} 10^{-8}\;to\;5.0 {\times} 10^{-6}$ mol $L^{-1}$, and the detection limit is $1.0 {\times} 10^{-8}$ mol $L^{-1}$. Finally, this new sensing method was employed to determine NAA in several soil samples.

• 자원리싸이클링
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• 제5권4호
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• pp.17-24
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• 1996

The computer simulation model was established to verify the applicability of smelting reduction concept to treatment of industrial wastes which becomes issue on the enviromental and recycling view point. Computer simulation model provides as following results. The increase of post combustion ratio(PCR) and heat transfer efficiency of PC energy(HTE) is effective ways to save energy. But, in order to increase PCR, recovery efficiency of post combustion energy(HTE) have to be higher than 85% HTE considering refractory life and saving energy together. Coke is most useful fuel source because it shows lowest dependence of PCR and low hydrogen content. The quality of hot metal of current process would be expected to the similar level with that of blast furnace. The utilization of scrap and Al dross can be also possible to maximize the advantages of current process which is high temperature and chemical dilution with hot metal and slag. In case of scrap, energy consumption was slightly increases because of heating up energy of scrap. Consquently, current process concept provides the possibility of intergrating recycles of industrial wastes materials such as EAF slag, coke oven dust, life terminated acidic refractory, aluminium dross and scrap by smelting reduction process.