• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.115.2-115.2
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• 2010

Autothermal reforming(ATR) processes of hydrocarbon liquids such as diesel fuels are spotlighted as methods to produce hydrogen for Fuel cell. However, the use of heavy hydrocarbons as feedstocks for hydrogen production causes some problems which increase the catalyst deactivation by the carbon deposition. Coking can be inhibited by increasing the water dissociation on the catalyst surface. This results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming leads to increase of undesirable hydrocarbons at reformed gases and subsequently decrease the performance. In this study, perovskite-based catalysts were investigated as alternatives to substitute the noble metal catalyst for the ATR of diesel. The investigated perovskite structure was based on LaCrO3. and metals were added at the A-site to enhance oxygen ion mobility, transition metals were doped on the B-site to enhance the reformation. Substituted Lanthanum chromium perovskite were made by aqueous combustion synthesis, which can produce high surface area. And for the homogeneous fuel supply, we made ultrasonic injection system for reforming. We compared durability of evaporation system and ultrasonic system for fuel injection.

• Journal of Hydrogen and New Energy
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• v.15 no.1
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• pp.1-11
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• 2004

Hybrid power systems with fuel cells and batteries have the potential to improve the operation efficiency and dynamic response. A proper load management strategy is important to better system efficiency and endurance in hybrid systems. In this paper, a fuzzy logic algorithm has been used to determine the fuel cell output power depending on the external required power and the battery state of charge(SoC). If the required power of the hybrid system is small and the SoC is small, then the greater part of the fuel cell power is used to charge the battery pack. If the required power is relatively big and the SoC is big, then fuel cell and battery are concurrently used to supply the required power. These IF-THEN operation rules are implemented by fuzzy logic for the energy management system of hybrid system. The strategy is evaluated by simulation. The results show that fuzzy logic can be effectively used to optimize the operational efficiency of hybrid system and to maintain the battery SoC properly.

• Journal of Hydrogen and New Energy
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• v.34 no.1
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• pp.8-16
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• 2023

In this work, we report basic performance test results of a lab-scale three phase alternative current (AC) arc plasma torch system for plasma gas reforming applications. The suggested system primarily consists of three graphite electrodes inclined at 12.5° to the central axis, a 𝞥 150 mm cylindrical gas path and a three phase-60 Hz AC power supply. At air flow rate of 50 Lpm and arc currents of 100-175 A, test results revealed that plasma resistances were decreasing from 1.08 Ω to 0.53 Ω with the increase of plasma power from 9.3 kW to 13.8 kW, causing the decrease of power factor and increase of the line voltages. However, the injected air can be heated quickly up to the temperatures of >1,200℃ when injecting AC arc plasma powers of >10 kW.

• Journal of Hydrogen and New Energy
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• v.23 no.4
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• pp.330-336
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• 2012

FCEV uses 250 ~ 450 V instead of using 12 V battery. High voltage vehicle can cause electric shock, fire and explosion accident. Therefore, it has potential factors that can cause hazard of safety for users. United states of America and Europe legislate regulations such as ECE R100, FMVSS 305 for regulating electrical safety during driving or after collision. The company manufacturing high voltage components must do advanced R&D about Method for improving and confirming the safety of high voltage. We develop the specific hardware components of high voltage wiring system for the power train system and power supply system of Hyundai Motors FCEV. This paper shows test method of insulative performance for securing the electrical safety of high voltage components such as power cable, connectors and buss-bar, and proposals the guide line value for human safety of FCEV according to the test result of our development components.

• Journal of the Korean Society of Marine Environment & Safety
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• v.29 no.1
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• pp.76-85
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• 2023

Demand for hydrogen as a renewable energy resource is increasing. However, unlike conventional fossil fuels, hydrogen requires a dedicated refueling station for fuel supply. A risk assessment of hydrogen refueling stations must be undertaken to secure the infrastructure. Therefore, in this study, a risk assessment for hydrogen refueling stations was conducted through both qualitative and quantitative risk assessments. For the qualitative evaluation, the hydrogen dispenser module was evaluated as two nodes using the hazard and operability (HAZOP) analysis. The risk due to filter clogging and high-pressure accidents was evaluated to be high according to the criticality estimation matrix. For the quantitative risk assessment, the Hydrogen Korea Risk Assessment Module (Hy-KoRAM) was used to indicate the shape of the fire and the range of damage impact, and to evaluate the individual and social risks. The individual risk level was determined of to be as low as reasonably practicable (ALARP). Additional safety measures proposed include placing the hydrogen refueling station about 100m away from public facilities. The social risk level was derived as 1E-04/year, with a frequency of approximately 10 deaths, falling within the ALARP range. As a result of the qualitative and quantitative risk assessments, additional safety measures for the process and a safety improvement plan are proposed through the establishment of a restricted area near the hydrogen refueling station.

• Journal of Hydrogen and New Energy
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• v.25 no.3
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• pp.271-279
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• 2014

A 25kW-class polymer electrolyte membrane (PEM) fuel cell system has been developed for the propulsion of a leisure boat. The fuel cell system was designed to satisfy various performance requirements, such as resistance to shock, stability under rolling and pitching oscillations, and durability under salinity condition, for its marine applications. Then, the major components including a 30kW-class PEM fuel cell stack, a DC-DC converter, a seawater cooling system, secondary battery packs, and balance of plants were developed for the fuel cell system. The PEM fuel cell stack employs a unique design structure called an anodic cascade-type stack design in which the anodic cells are divided into several blocks to maximize the fuel utilization without hydrogen recirculation devices. The performance evaluation results showed that the stack generated a maximum power of 31.0kW while maintaining a higher fuel utilization of 99.5% and an electrical efficiency of 56.1%. Combining the 30-kW stack with other components, the 25kW-class fuel cell system boat was fabricated for a leisure. As a result of testing, the fuel cell system reached an electrical efficiency of 48.0% at the maximum power of 25.6kW with stable operability. In the near future, two PEM fuel cell systems will be installed in a 20-m long leisure boat to supply electrical power up to 50kW for propelling the boat and for powering the auxiliary equipments.

• Journal of Electrochemical Science and Technology
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• v.7 no.2
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• pp.146-152
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• 2016

A combined system with PEMFC and reformer is introduced and optimized for the real use of this kind of system in the future. The hydrogen source to operate the PEMFC system is methanol, which needs two parts of methanol reforming reaction and preferential oxidation (PROX) for the hydrogen fuel process in the combined operation PEMFC system. With the optimized methanol steam reforming condition, we tested PROX reactions in various operation temperature from 170 to 270 ℃ to investigate CO concentration data in the reformed gases. Using these different CO concentration, PEMFC performances are achieved at the combined system. Pt/C and Ru promoted Pt/C were catalysts were used for the anode to compare the stability in CO contained gases. The alloy catalyst of PtRu/C shows higher performance and better resistance to CO than the Pt/C at even high CO amount of 200 ppm, indicating a promotion not only to the activity but also to the CO tolerance. Furthermore, in a system point of view, there is a fluctuation in the PEMFC operation due to the unstable fuel supply. Therefore, we also modified the methanol reforming by a scaled up reactor and pressurization to produce steady operation of PEMFC. The optimized system with the methanol reformer and PEMFC shows a stable performance for a long time, which is providing a valuable data for the PEMFC commercialization.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.05a
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• pp.29-32
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• 2009

This study is for development combustion test facility of liquid rocket engine system using hydrogen peroxide/kerosene as propellent. For this new facility, we construct thrust measure system, propellent supply system, control and data acquisition system. To perform 200N liquid rocket engine combustion test, operation scenario and sequence were designed. Result of combustion test propellents were supplied to engine stably and confirm of development combustion test facility very well.

• Proceedings of the KIEE Conference
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• 2008.10c
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• pp.218-220
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• 2008

Urban air quality, including carbon-dioxide emissions, and national energy security are related issues affecting the rail industry and transportation sector as a whole. They are related by the fact that (in the United States) 97-98% of the energy for the transport sector is based on oil, and more than 60% is imported. A fuelcell locomotive combines the environmental advantages of a catenary-electric locomotive with the higher overall energy efficiency and lower infrastructure costs of a diesel-electric. Catenaryelectric locomotives, when viewed as only one component of a distributed machine that includes an electricity-generating plant and transmission lines, are the least energy-efficient locomotive type. The natural fuel for a fuelcell is hydrogen, which can be produced from many renewable energies and nuclear energy, and thus a hydrogen-fuelcell locomotive will not depend on imported oil for its energy supply. This paper proposes a base models of Hybrid fuel cell/IPT railway vehicle power system, the necessary of this research.

• Journal of Hydrogen and New Energy
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• v.23 no.3
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• pp.264-273
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• 2012

In this paper, two types of integrated gasification combined cycle (IGCC) plants using either an air separation unit (ASU) or an ion transport membrane (ITM), which provide the oxygen required in the gasification process, were simulated and their thermodynamic performance was compared. Also, the influence of adopting a pre-combustion $CO_2$ capture in the downstream of the gasification process on the performance of the two systems was examined. The system using the ITM exhibits greater net power output than the system using the ASU. However, its net plant efficiency is slightly lower because of the additional fuel consumption required to operate the ITM at an appropriate operating temperature. This efficiency comparison is based on the assumption of a moderately high purity (95%) of the oxygen generated from the ASU. However, if the oxygen purity of the ASU is to be comparable to that of the ITM, which is over 99%, the ASU based IGCC system would exhibit a lower net efficiency than the ITM based system.