• Title/Summary/Keyword: Hydrogen Storage System

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Performance of LNT Catalyst according to the Supply Condition of Hydrogen Reductants for Diesel Engine (디젤엔진에서 수소 환원제 공급 조건에 따른 LNT 촉매 성능)

  • Park, Cheol-Woong;Kim, Chang-Gi;Choi, Young;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.3
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    • pp.142-148
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    • 2009
  • The direct injection(DI) diesel engine has become a prime candidate for future transportation needs because of its high thermal efficiency. However, nitrogen oxides(NOx) increase in the local high temperature regions and particulate matter (PM) increases in the diffusion flame region within diesel combustion. Therefore, the demand for developing a suitable after treatment device has been increased. NOx absorbing catalysts are based on the concept of NOx storage and release making it possible to reduce NOx emission in net oxidizing gas conditions. This De-NOx system, called the LNT(Lean NOx Trap) catalyst, absorbs NOx in lean exhaust gas conditions and release it in rich conditions. This technology can give high NOx conversion efficiency, but the right amount of reducing agent should be supplied into the catalytic converter at the right time. In this research, a performance characteristics of LNT with a hydrogen enriched gas as a reductant was examined and strategies of controlling the injection and rich exhaust gas condition were studied. The NOx reduction efficiency is closely connected to the injection timing and duration of reductant. LNT can reduce NOx efficiently with only 1 % fuel penalty.

Research on the Safety and Health Management and Asphyxiation Gas Concentration in Ginger Storage Tunnel (생강 저장굴의 질식 가스 농도 및 안전보건 관리 방향에 관한 연구)

  • Kim, Hyocher;Lee, Minji;Kim, Insoo;Lee, Kyeongsuk;Seo, Mintae;Cha, Jongjin;Kim, Kyungran
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.2
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    • pp.222-229
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    • 2018
  • Objectives: The aim of this study was to evaluate gas concentrations such as oxygen in ginger storage tunnels, which are the causes of asphyxiation in confined spaces and suggest directions for safety and health management at ginger farms. Methods: Five farms in the Seosan and Taean areas which use underground ginger storage tunnels were chosen and examined with a walk-through survey and direct reading device for oxygen, hydrogen sulfide, ammonia, and carbon monoxide. Results: The oxygen concentration in the storage tunnels with no ventilation was found to be under 18% in summer, which may cause health effects. The concentration in those with ventilation was about 19%. The difference in temperature by measurement day had little effect on the concentration of oxygen. Conclusions: Even though some of farms had used compulsory ventilation systems, none of the farms visited possessed any direct reading device for oxygen. Warning systems using a direct reading device can be more effective, helpful, and required compared to ventilation, considering the difficulty and expense of periodical maintenance of ventilation systems and the fact that a farmer can be placed in danger when unaware of the malfunction of the ventilation system. In addition, a warning system may make farmers more cognitive of agricultural safety and health actions while a ventilation system can cause them to become passive and ignorant of workplace hazards.

Research Trend and Analysis of Altitude and Endurance for Fuel Cell Unmanned Aerial Vehicles (연료전지 무인항공기의 고도와 체공시간에 대한 특성 분석 및 최신 연구동향)

  • Cho, Seonghyun;Kim, Minjin;Son, Youngjun;Yang, Taehyun
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.4
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    • pp.393-404
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    • 2014
  • Unmanned aerial vehicles (UAVs) have been applied to not only military missions like surveillance and reconnaissance but also commercial missions like meteorological observation, aerial photograph, communication relay, internet network build and disaster observation. Fuel cells make UAVs eco-friendly by using hydrogen. Proton exchange membrane fuel cells (PEMFCs) show low operation temperature, high efficiency, low noise and high energy density and those characterisitcs are well fitted with UAVs. Thus Fuel cell based UAVs have been actively developed in the world. Recently, fuel cell UAVs have started to develope for high altitude UAVs because target altitude of UAVs is expanded upto stratosphere altitude. Long endurance of UAVs is essential to improve effects of the missions. Improvement of UAV endurance time could be fulfilled by developing a hydrogen fuel storage system with high energy density and reducing the weight of UAVs. In this paper, research trend and analysis of fuel cell UAVs are introduced in terms of their altitude and endurance time and then the prospect of fuel cell UAVs are shown.

Electrochemical Characteristics of Hybrid Cell Consisting of Li Secondary Battery and Supercapacitor (리튬이차전지와 슈퍼커패시터로 구성된 하이브리드 셀의 전기화학적 특성)

  • KIM1, SANGGIL;GIL, BOMIN;HWANG, GABJIN;RYU, CHEOLHWI
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.1
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    • pp.43-48
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    • 2019
  • This study investigates the electrochemical characteristics of the hybrid cell that combined the advantageous characteristics of Li secondary battery and supercapacitor, high energy density and high power density, respectively. Electrochemical behaviors of the hybrid cell was characterized by charge/discharge, cycle and impedance tests. The hybrid cell using Li secondary battery and supercapacitor had better discharge capacity and cycle performance than that of using Li secondary battery only. Proper design of such a hybrid cell system is expected to result in substantial benefits to the well being of the Li secondary battery. The hybrid cell involving Li secondary battery for high energy density and supercapacitor for high power density may be the possible solution for future energy storage system.

Review of Research Trend in Fuel Cell: Analysis on Fuel-Cell-Related Technologies in Electrode, Electrolyte, Separator Plate, Stack, System, Balance of Plant, and Diagnosis Areas (국내 연료전지 분야 연구동향 분석: 전극, 전해질, 분리판, 스택, 시스템, BOP, 진단분석 분야)

  • LEE, YOUNG DUK;KIM, JAE-YUP;YOO, DONG JIN;JU, HYUNCHUL;KIM, HANSANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.6
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    • pp.530-545
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    • 2020
  • This paper reviews and summarizes the fuel-cell-related studies those have been recently published in major Korean Citation Index journals, aiming at analyzing the research trend in fuel cell technologies. Six major journals are selected for the literature survey; 57 papers are chosen for the detailed analysis through a screening examination on the total 1,040 papers published during between 2018 and 2020. Papers are classified into six technical categories, such as i) electrode, ii) electrolyte, iii) bipolar plate and stack, iv) fuel cell system, v) balance of plant, and vi) diagnosis-related studies, and summarized by the experts in the relevant area. Through this paper, we provide a comprehensive review on the recent trends and progress in fuel-cell-related research work in Korea.

A Study on Design of Type IV Hydrogen Pressure Vessels with Filament Winding Method (필라멘트 와인딩 공법을 적용한 타입 IV 수소 압력용기 설계 연구)

  • Sungjin Ahn;Hyunbum Park
    • Journal of Aerospace System Engineering
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    • v.17 no.6
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    • pp.127-132
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    • 2023
  • In this study, designing of a Type 4 pressure vessel using the filament winding method was conducted. In order to prevent leakage in consideration of the design of the hydrogen storage tank, a liner was designed by applying high-density polyethylene (HDPE), and the composite structure was designed by stacking carbon/epoxy in the hoop and helical directions. As a theoretical approach, the angle of the helical fiber and fiber thickness of each hoop and helix were designed. The safety of the design was verified using the commercial software ANSYS.

Investigation of the Cryogenic Performance of the High Density Polyurethane Foam (고밀도 폴리우레탄 폼의 극저온 성능 분석)

  • Jeong-Hyeon Kim;Jeong-Dae Kim;Tae-Wook Kim;Seul-Kee Kim;Jae-Myung Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_3
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    • pp.1289-1295
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    • 2023
  • Polyurethane foam insulation required for storing and transporting cryogenic liquefied gas is already widely used as a thermal insulation material for commercial LNG carriers and onshore due to its stable price and high insulation performance. These polyurethane foams are reported to have different mechanical performance depending on the density, and the density parameter is determined depending on the amount of the blowing agent. In this study, density-dependent polyurethane foam was fabricated by adjusting the amount of blowing agent. The mechanical properties of polyurethane foam were analyzed in the room temperature and cryogenic temperature range of -163℃ at 1.5 mm/min, which is a quasi-static load range, and the cells were observed through microstructure analysis. The characteristics of linear elasticity, plateau, and densification, which are quasi-static mechanical behaviors of polyurethane foam, were shown, and the correlation between density and mechanical properties in a cryogenic environment was confirmed. The correlation between mechanical behavior and cell size was also analyzed through SEM morphology analysis. Polyurethane foam with a density of 180 kg/m3 had a density about twice as high as that of a polyurethane foam with a density of 96 kg/m3, but yield strength was about 51% higher and cell size was about 9.5% smaller.

THE EFFECTS OF CREEP AND HYDRIDE ON SPENT FUEL INTEGRITY DURING INTERIM DRY STORAGE

  • Kim, Hyun-Gil;Jeong, Yong-Hwan;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
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    • v.42 no.3
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    • pp.249-258
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    • 2010
  • Recently, many utilities have considered interim dry storage of spent nuclear fuel as an option for increasing spent fuel storage capacity. Foreign nuclear regulatory committees have provided some regulatory and licensing requirements for relatively low- and medium-burned spent fuel with respect to the prevention of spent fuel degradation during transportation and interim dry storage. In the present study, the effect of cladding creep and hydride distribution on spent fuel degradation is reviewed and performance tests with high-burned Zircaloy-4 and advanced Zr alloy spent fuel are proposed to investigate the effect of burnup and cladding materials on the current regulatory and licensing requirements. Creep tests were also performed to investigate the effect of temperature and tensile hoop stress on hydride reorientation and subsequently to examine the temperature and stress limits against cladding material failure. It is found that the spent fuel failure is mainly caused by cladding creep rupture combined with mechanical strength degradation and hydride reorientation. Hydride reorientation from the circumferential to radial direction may reduce the critical stress intensity that accelerates radial crack propagation. The results of cladding creep tests at $400^{\circ}C$ and 130MPa hoop stress performed in this study indicate that hydride reorientation may occur between 2.6% to 7.0% strain in tube diameter with a hydrogen content range of 40-120ppm. Therefore, it is concluded that hydride re-orientation behaviour is strongly correlated with the cladding creep-induced strain, which varies as functions of temperature and stress acting on the cladding.

CO Tolerance Improvement of MEA Using Metal Thin Film by Sputtering Method in PEM Fuel Cell (스퍼터링 공정으로 제조된 금속박막을 이용한 고분자전해질 연료전지 막-전극접합체의 일산화탄소에 대한 내구성 연구)

  • Cho, Yong-Hun;Yoo, Sung-Jong;Cho, Yoon-Hwan;Park, Hyun-Seo;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.279-282
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    • 2007
  • When reformer for fuel cell is used, CO in hydrogen gas leads to a seriously decreased membrane electrode assembly (MEA) performance by catalyst poisoning. The effect of CO on performance of modified MEA by sputtering method is studied in this paper. The experimental results show that sputtered Pt and Ru thin film improve a single cell performance of MEA and sputtered metal thin film has a CO tolerance. The air injection process on anode show improved CO tolerance test result. Moreover, Pt, Ru and PtRu thin film by sputtering had influence on the CO tolerance with air injection process.

Study on the control technique for the heat transportation system using metal hydride (수소저장합금을 이용한 열수송시스템 제어기술 연구)

  • Sim, K.S.;Kim, J.W.;Kim, J.D.;Myung, K.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.11 no.1
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    • pp.43-49
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    • 2000
  • The heat transportation from a complex of industry to a rural area needs more efficient method because the distance between them is usually more than 10km. Conventional heat transportation using steam or hot water via pipe line has limits in transportation distance (about 3~5 km) because of the heat loss and frictional loss in the pipe line. Metal hydride can absorb or discharge hydrogen through exothermic or endothermic reaction. After releasing hydrogen from metal hydride by means of the waste heat from industry, we can transport this hydrogen to urban area via pipe line. In urban areas, other metal alloy reacts with this hydrogen to form metal hydride and produces heat for heating. Cool heat is also obtained if it is possible to use metal hydride with low reaction temperature. Therefore, metal hydride can be used as a media for transportation and storage of heat. $MmNi_{4.5}Al_{0.5}Zr_{0.003}$, $LaNi_5$, $Zr_{0.9}Ti_{0.1}Cr_{0.6}Fe_{1.4}$, $MmNi_{4.7}Al_{0.1}Fe_{0.1}V_{0.1}$ alloys were selected for this purpose and the properties of those metal hydrides were discussed. The design and control techniques were proposed and discussed for this heat transportation system using metal hydride.

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