• Title/Summary/Keyword: Hydrogen Mixed Gas

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Effect of Manure Additives Mixed with Probiotics and Zeolite on Harmful Gas Production Released From Pig Slurry (생균제와 제올라이트를 혼합한 축분첨가제가 돈분 슬러리에서 발생하는 유해 가스 발생량에 미치는 영향)

  • Jang, Woo-Whan;Choi, In-Hag
    • Journal of Environmental Science International
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    • v.31 no.1
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    • pp.99-102
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    • 2022
  • The aim of this study was to investigate the effect of manure additives mixed with probiotics and zeolite on harmful gas production generated by pig slurry. A total of 180 crossbred pigs ([Yorkshire × Land race] × Duroc, live weight 70±3.21 kg) were allotted to a completely randomized design with 3 treatments and 3 replications (20 heads per replicate). The treatments consisted of 0% (control), 0.05% (T1), or 1% (T2) of manure additives mixed with probiotics and zeolite. Manure additives were added weekly to pig slurry pits (2 m × 4.5 m × 1.2 m) on a volumetric basis. For ammonia measured at both 10 cm and 90 cm above the pig slurry pit, a statistical significance (p<0.05) was found in probiotics and zeolite-treated manure additives at weeks 1 - 3, except for week 0. In addition, hydrogen sulfide levels measured at 10 cm above the pig slurry pit were not affected by the manure additive at weeks 0 and 1, but showed a significant statistical difference at weeks 2 and 3 (p<0.05). Therefore, supplementing pig slurry with 0.05% and 0.1% manure additives mixed with probiotics and zeolite was found to be effective in reducing environmental pollution in pig facilities.

Photocatal~ic Hydrogen Evolution with Platinum Loaded Cadmium-Iron-Sulfide Mixed Crystal Powders in Aque-ous Media

  • Jo, Cheol Rae;Park, Se Jin;Kim, Ha Seok
    • Bulletin of the Korean Chemical Society
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    • v.21 no.8
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    • pp.805-808
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    • 2000
  • Mixed crystal powders based on Cd,Fe, and S have been synthesized by varying the ratio of CdS and $FeS_2in$ order to find a suitable material usefuI for the effectivc conversion of solar energy. Hydrogen gas was evolved only with CdS/Ptby photocatal ytic reaction under white light in an aqueous 1 M sodiumsulfite solution. From electrochemical studies of semiconductor electrodes. itwas shown that the onset potential shifted to the positive direction and that the bandgap energy also decreased as the molar ratio of Fe increased. A hydrogen evolution mechanism in terms of the conduction band potential and hydrogen evolution potential is proposed.

A Study on the Driving Characteristics of Microbial Fuel Cell Using Mixed Strains in Domestic Wastewater (생활폐수 내 혼합균주를 이용한 미생물 연료전지의 구동 특성에 관한 연구)

  • KIM, SANG KYU;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.506-513
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    • 2021
  • The use of fossil fuels is a major contributor to the increase atmospheric greenhouse gas emissions. As such problems arise, interest in new and renewable energy devices, particularly fuel cells, is greatly increasing. In this study, various characteristics of mixed strains were observed in wastewater collected by the Jeonju Environment Office to investigate the effects of microorganisms on voltage generation and voltage generation of substrates, electrode materials, electrons, electron transport media, and ash microbial fuel cells. As a result of separately measuring the voltage generated during inoculation, the inoculation voltage of Escherichia coli K12 (E. coli K12) was 0.45 V, and the maximum inoculation voltage of the mixed strain was 1.2 V. Thereafter, voltage values were collected using a digital multimeter and the amount of voltage generated over time was measured. In the case of E. coli K12, the maximum voltage reached 0.45 V, and the cell voltage was maintained above 0.23 V for 140 hours. In contrast, for the mixed strain, the maximum voltage reached 1.2 V and the voltage was slowly decreased to 0.97 V. In addition, the degree of microbial adsorption to the electrod surface after the inoculation test was confirmed using a scanning electron microscope. Therefore, these results showed the possibility of purifying pollutants at the same time as power generation through the production of hydrogen ions using microorganisms and wastewater.

Biological Hydrogen Production from Mixed Waste of Food and Activated Sludge (음식물쓰레기와 폐활성슬러지의 혼합물로부터 혐기성 바이오 수소 생산)

  • Chung, Chong Min;Hong, Seok Won;Park, Chul Hee;Kim, Young O;Lee, Sang Hyup
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.571-580
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    • 2008
  • The influence of bacterial stress on anaerobic hydrogen-producing microorganisms was investigated in batch tests using serum bottles. Several physical and chemical stresses (i.e., heating, adding methane producing inhibitor and chemical acidification) were adapted as a pretreament of the seed sludge. In this experiment, the cultivation temperature were set at mesophilic ($35^{\circ}C$) and thermophilic conditions ($55^{\circ}C$) with adjusting pH at 5, 6, and 7 when using the mixture of food waste and activated sludge as a substrate. In conjunction with the pretreatment, hydrogen production was significantly enhanced as compared with that from untreated sludge. However, less biogas (hydrogen and methane) was produced without the pH control, resulted from the decrease of pH to below 4, mainly due to the formation of VFAs. Hydrogen and carbon dioxide gas were analyzed as main components of the biogas while methane not detected. With an application of chemical acidification, the highest hydrogen production value of 248 ml/l/day achieved at pH 7 and $35^{\circ}C$. In addition, more hydrogen gas produced when the ratio of butyric/acetic acid ratio increased. The optimum pH and temperature for hydrogen production were found to be 7 and $35^{\circ}C$, respectively.

Co-Gasification of Woodchip and Plastic Waste for Producing Fuel Gas (연료용 합성가스 생산을 위한 바이오매스와 폐플라스틱의 혼합가스화)

  • Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.3
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    • pp.75-80
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    • 2012
  • Gasification is a therm-chemical conversion process to convert various solid fuels into gaseous fuels under limited supply of oxygen in high temperature environment. Considering current availability of biomass resources in this country, the gasification is more attractive than any other technologies in that the process can accept various combustible solid fuels including plastic wastes. Mixed fuels of biomass and polyethylene pellets were used in gasification experiments in this study in order to assess their potential for synthesis gas production. The results showed that higher reaction temperatures were observed in mixed fuel compared to woodchip experiments. In addition, carbon monoxide, hydrogen, and methane concentrations were increased in the synthesis gas. Heating values of the synthesis gas were also higher than those from woodchip gasification. There are hundred thousand tons of agricultural plastic wastes generated in Korea every year. Co-gasification of biomass and agricultural plastic waste would provide affordable gaseous fuels in rural society.

A Study on Brown Gas Generator with Instantaneous Source Power Control (순시전원제어에 의한 수산화가스 발생장치에 관한 연구)

  • Jeon, Yoon-Seok;Lee, Sang-Yong;Mok, Hyung-Soo;Choe, Gyu-Ha
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.1093-1095
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    • 2003
  • The mixed gas of Hydrogen and Oxygen has obtained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. In this paper, Brown Gas Generator with Instantaneous source power control method is designed and relationship between brown gas quantities, efficiency and power condition is studied.

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The co-effect of $TiO_2$, Cu and Ni Powders for Enhancing the Hydrogen Generation Efficiency using Plasma Technology (플라즈마 반응기의 수소발생에 미치는 $TiO_2$, Cu, Ni 촉매제 영향)

  • Park, Jae-Yoon;Kim, Jong-Suk;Jung, Jang-Gun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.9
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    • pp.1599-1605
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    • 2008
  • The research was conducted in order to improve the hydrogen generation efficiency of the electrical plasma technology from tap water by using $TiO_2$ photocatalyst, mixed Cu - $TiO_2$ powder, and mixed Ni - $TiO_2$ powder as the catalysts. Experiments were performed with the pulsed power and nitrogen carrier gas. The result has shown that the hydrogen concentration with the presence of $TiO_2$ powder was created higher than that of without using photocatalyst. The hydrogen concentration with using $TiO_2$ was 3012ppm corresponding to the applied voltage of 16kV, while it without using the $TiO_2$ was 1464ppm at the same condition . The effect of $TiO_2$ powder was strongly detected at the applied voltages of 15kV and 16kV. This phenomena might be resulted from the co-effect of the pulsed power discharge and the activated state of $TiO_2$ photocatalyst. The co-effect of the mixed catalysts such as Cu-$TiO_2$ and Ni-$TiO_2$ (the mixed photocatalyst $TiO_2$ and transition metals) were also investigated. The experimental results showed that, Cu and Ni powder dopants were greatly enhancing the activity of the $TiO_2$ photocatalyst. Under these experimental conditions the extremely high hydrogen concentrations at the optimal point were produced as 4089ppm and 6630ppm, respectively.