• Journal of Korea Foundry Society
• /
• v.23 no.5
• /
• pp.268-275
• /
• 2003

The mechanism of the hydrogen gas pore formation was investigated in Lost Foam Casting of Al-alloy by reduced pressure test and real casting. The hydrogen gas pick-up was affected by the formed gas during the decomposition of polystyrene in addition to the liquid product. It depended on pouring temperature and a proper temperature of metal front gave the minimum hydrogen pick-up. At a low pouring temperature, the hydrogen went into the melt mainly from entrapped liquid product of polystyrene but pores were formed from the gas as well as the liquid product at a high pouring temperature. The mold flask evacuation down to 710torr decreased the gas porosity down by around 0.4% vol%. The entrapped decomposition product of polystyrene in the melt was observed through the visualization of filling behavior of Al alloy-melt with the high speed camera.

• Journal of the Korean Institute of Gas
• /
• v.17 no.5
• /
• pp.15-21
• /
• 2013

This study evaluated comparison of the risk according to the type of fuel by three-dimensional simulation tool(FLACS). The consequence analysis of fire explosion and jet-fire was carried out in the layout of a typical high-pressure gas filling stations using CNG, hydrogen and 30%HCNG. Under the same conditions, hydrogen had a 30kPa maximum overpressure, CNG had a 0.4kPa and HCNG had a 3.5kPa. HCNG overpressure was 7.75 times higher than the CNG measurement, but HCNG overpressure was only 11.7% compared to hydrogen. In case of flame propagation, hydrogen had a very fast propagation characteristics. On the other hand, CNG and HCNG flame propagation velocity and distance tended to be relatively safe in comparison to hydrogen. The estimated flame boundary distance by jet-fire of hydrogen was a 5.5m, CNG was a 3.4m and HCNG was a 3.9m.

• Journal of the Korean Institute of Gas
• /
• v.16 no.6
• /
• pp.87-101
• /
• 2012

In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

• Journal of the Korean Institute of Gas
• /
• v.26 no.3
• /
• pp.38-44
• /
• 2022

As the supply of hydrogen charging stations for hydrogen supply accelerates due to the hydrogen economy revitalization policy, the risk of accidents is also increasing. Since most hydrogen explosion accidents lead to major accidents, it is very important to secure safety when using hydrogen energy. In order to utilize hydrogen energy, it is essential to secure the safety of hydrogen storage containers used for production, storage, and transportation of liquid hydrogen. In this paper, in order to evaluate the structural safety of a hydrogen-filled pressure vessel, the behavioral characteristics of gas pressure were analyzed by finite element analysis. SA-372 Grade J / Class 70 was used for the material of the pressure vessel, and a hexahedral mesh was applied in the analysis model considering only the 1/4 shape because the pressure vessel is axisymmetric. A finite element analysis was performed at the maximum pressure using a hydrogen gas pressure vessel, and the von Mises stress, deformation, and strain energy density of the vessel were observed.

• Journal of the Korean institute of surface engineering
• /
• v.49 no.3
• /
• pp.286-300
• /
• 2016

Pd-Ag alloy membranes have attracted a great deal of attention for their use in hydrogen purification and separation due to their high theoretical permeability, infinite selectivity and chemical compatibility with hydro-carbon containing gas streams. For commercial application, Pd-based membranes for hydrogen purification and separation need not only a high perm-selectivity but also a stable long-term durability. However, it has been difficult to fabricate thin, dense Pd-Ag alloy membranes on a porous stainless steel metal support with surface pores free and a stable diffusion barrier for preventing metallic diffusion from the porous stainless steel support. In this study, thin Pd-Ag alloy membranes were prepared by advanced Pd/Ag/Pd/Ag/Pd multi-layer sputter deposition on the modified porous stainless steel support using rough polishing/$ZrO_2$ powder filling and micro-polishing surface treatment, and following Ag up-filling heat treatment. Because the modified Pd-Ag alloy membranes using rough polishing/$ZrO_2$ powder filling method demonstrate high hydrogen permeability as well as diffusion barrier efficiency, it leads to the performance improvement in hydrogen perm-selectivity. Our membranes, therefore, are expected to be applicable to industrial fields for hydrogen purification and separation owing to enhanced functionality, durability and metal support/Pd alloy film integration.

• Journal of the Korean Institute of Gas
• /
• v.27 no.3
• /
• pp.116-122
• /
• 2023

As the number of hydrogen filling stations for hydrogen supply increases with the progress of low-carbon eco-friendly energy policies, the risk of accidents is also increasing. Actual pressure vessels may have defects such as notches, pores, and inclusions that may occur during the manufacturing process. Therefore, it is necessary to evaluate the integrity of pressure vessels in the case where cracks exist in pressure vessels under internal pressure. In this paper, 3D finite element analysis was used to evaluate the structural safety of hydrogen-filled pressure vessels with surface cracks, and the shape of surface cracks was compared with the commonly used semi-elliptical shape. In the future, these results will be used to predict the remaining life of the pressure vessel in consideration of fracture mechanics.

• Applied Chemistry for Engineering
• /
• v.34 no.3
• /
• pp.307-312
• /
• 2023

In this study, a catalytic oxidation-heat recovery system was designed that can remove unreacted with a concentration of about 1% to 6% in the exhaust gas of hydrogen fuel cells and recover heat to ensure safety in the hydrogen economy. The safety system was devised by filling hydrogen oxidation catalysts at room temperature that can remove unreacted hydrogen without any energy source, and an exhaust-heat recovery device was integrated to efficiently recover the heat released from the oxidation reaction. Through CFD analysis, variations in pressure and fluid within the system were shown depending on the filling conditions of the hydrogen oxidation system. In addition, it was found that waste heat could be recovered by optimizing the temperature of the exhaust gas, flow rate, and pressure conditions within the heat recovery system and securing hot water above 40 ℃ by utilizing the exhaust gas oxidation heat source above 300 ℃. Through this study, it was possible to confirm the potential of utilizing hydrogen processes, which are applied in small to medium-sized systems such as hydrogen fuel cells, as a safety system by evaluating them at a pilot scale. Additionally, it could be a safety guideline for responding to unexpected hydrogen safety accidents through further pilot-scale studies.

• Journal of the Korean Institute of Gas
• /
• v.15 no.2
• /
• pp.1-8
• /
• 2011

In this research, the safety trends and technologies of HCNG, a mixture of hydrogen and natural gas, are analyzed. This is an attracting alternative fuels to meet the strengthened automotive exhaust gas emission standards. HCNG is very important opportunities and challenges in that it is available the existing CNG infrastructures, meets the strengthened emission standards, and the technical, social bridge of the coming era of hydrogen. It is essential for the commercialization of HCNG that hydrogen - compressed natural gas blended fuel for use in preparation of various safety considerations included accidents scenario, safety distance, hydrogen attack, ignition sources and fire detectors are examined. Risk assessments also are suggested as one of permission procedure for HCNG filling station.

• Transactions of the Korean hydrogen and new energy society
• /
• v.25 no.2
• /
• pp.161-172
• /
• 2014

Hydrogen, which can be produced from abundant and widely distributed renewable energy resources, seems to be a promising candidate for solving the concerns for improving energy security, urban air pollution, and reducing greenhouse gas emissions. The two primary motivating factors for hydrogen economy are fossil fuel supply limitations and concerns about global warming. But the safety issues associated with hydrogen economy need to be investigated and fully understood before being considered as a future energy source. Limited operating experience with hydrogen energy systems in consumer environments is recognised as a significant barrier to the implementation of hydrogen economy. To prevent unnecessary restrictions on emerging codes, standards and local regulations, safety policies based on real hazards should be developed. This article studies briefly the direct impact-distances from hazard events such as hydrogen release and jet fire, and damage levels from hydrogen gas explosion in a confined space. Based on the direct impact-distances indicated in the accident scenarios and consumer environments in Korea, the safety policies, which are related to hydrogen filling station, hydrogen fuel cell car, portable fuel cell, domestic fuel cells, and hydrogen town, are suggested to implement hydrogen economy. To apply the safety policies and overcome the disadvantages of prescriptive risk management, which is setting guidance in great detail to management well known risk but is not covering unidentified risk, hybrid risk management model is also proposed.

• Journal of the Korean Institute of Gas
• /
• v.27 no.3
• /
• pp.123-133
• /
• 2023

Commercial hydrogen fuel cell vehicles are charged by compressing gaseous hydrogen to high pressure and storing it in a storage tank in the vehicle. This process causes the temperature of the gas to rise, to ensure the safety to storage tanks, the temperature is limited. Therefore, a heat transfer model is needed to explain this temperature rise. The heat transfer model includes the convective heat transfer phenomenon, and accurate estimation is required. In this study, the convective heat transfer coefficient in the hydrogen fueling process was calculated and compared using various correlation equations considering physical phenomena. The hydrogen fueling process was classified into the fueling line from the dispenser to the tank inlet and the storage tank in the vehicle, and the convective heat transfer coefficients were estimated according to process parameters such as mass flow rate, diameter, temperature and pressure. As a result, in the case of the inside of the filling line, the convective heat transfer coefficient was about 1000 times larger than that of the inside of the storage tank, and in the case of the outside of the filling line, the convective heat transfer coefficient was about 3 times larger than that of the outside of the storage tank. Finally, as a result of a comprehensive analysis of convective heat transfer coefficients in each process, it was found that outside the storage tank was lowest in the entire hydrogen fueling process, thus dominated the heat transfer phenomenon.