• 한국수소및신에너지학회논문집
• /
• 제29권3호
• /
• pp.251-259
• /
• 2018

Metal hydride based hydrogen storage under moderate temperature and pressure gives the safety advantage over the gas and liquid storage methods. Still solid-state hydrogen storage including metal hydride is below the DOE target level for automotive applications, but it can be adapted to stationary or miliary application reasonably. In order to develop a modular solid state hydrogen storage system that can be applied to a distributed power supply system composed of renewable energy - water electrolysis - fuel cell, the heat transfer and hydrogen storage characteristics of the metal hydride necessary for the module system design were investigated using AB5 type metal hydride, LCN2 ($La_{0.9}Ce_{0.1}Ni_5$). The planetary high energy mill (PHEM) treatment of LCN2 confirmed the initial hydrogen storage activation and hydrogen storage capacity through surface modification of LCN2 material. Expanded natural graphite (ENG) addition to LCN2, and compression molding at 500 atm improved the thermal conductivity of the solid hydrogen storage material.

• 한국수소및신에너지학회논문집
• /
• 제28권6호
• /
• pp.712-720
• /
• 2017

As Korean government has activated the renewable portfolio standard (RPS) since 2012, producers have been seeking and using the various renewable resources to meet the RPS quota. One of these efforts, Power Bio-Fuel oil demonstration project is being conducted to check the operability and compatibility with fossil fuel, Fuel oil (B-C) from 2014. The oil is a mixture of vegetable oil and animal fat or fatty acid ester of them and should satisfy some specification to use the power generation. The oil's quality and combustion characteristics are different from conventional oil, Fuel oil (B-C) in current power plant facility. In this study, it was investigated the storage stability and malodor intensity of Bio-Fuel oil.

• Metals and materials international
• /
• 제24권6호
• /
• pp.1403-1411
• /
• 2018

Graphene (multilayer graphene) was chosen as an additive to improve the hydrogen uptake and release properties of magnesium (Mg). Five weight percent of graphene was added to pre-milled Mg by milling in hydrogen (reaction-involving milling). The hydrogen uptake and release properties of the graphene-added Mg were investigated. The activation of Mg-5graphene, which was prepared by adding 5 wt% graphene to Mg pre-milled for 24 h, was completed after the second cycle (cycle number, CN=2). Mg-5graphene had a high effective hydrogen-storage capacity (the quantity of hydrogen absorbed for 60 min) of 6.21 wt% at CN=3 at 593 K in 12 bar $H_2$. At CN=1, Mg-5graphene released 0.46 wt% hydrogen for 10 min and 4.99 wt% hydrogen for 60 min. Milling in hydrogen is believed to create defects (leading to facilitation of nucleation), produce cracks and clean surfaces (leading to increase in reactivity), and decrease particle size (leading to diminution of diffusion distances or increasing the flux of diffusing hydrogen atoms). The added graphene is believed to have helped the sample have higher hydrogen uptake and release rates, weakly but partly, by dispersing heat rapidly.

• 한국수소및신에너지학회논문집
• /
• 제33권6호
• /
• pp.607-615
• /
• 2022

In this study, economic analysis program was developed for economic evaluation of hydrogen production, storage/delivery, and utilization technologies as well as overseas import of hydrogen. Economic analysis program can be used for the estimation of the levelized cost of hydrogen for hydrogen supply chain technologies. This program include five hydrogen production technology on steam methane reforming and water electrolysis, two hydrogen storage technologies (high compressed gas and liquid hydrogen storage), three hydrogen delivery technologies (compressed gas delivery using tube trailer, liquid hydrogen, and pipeline transportation) and six hydrogen utilization technologies on hydrogen refueling station and stationary fuel cell system. In the case of overseas import hydrogen, it was considered to be imported from five countries (Austraila, Chile, India, Morocco, and UAE), and the transportation methods was based on liquid hydrogen, ammonia, and liquid organic hydrogen carrier. Economic analysis program that was developed in this study can be expected to utilize for planning a detailed implementation methods and hydrogen supply strategies for the hydrogen economy road map of government.

• 한국수소및신에너지학회논문집
• /
• 제28권4호
• /
• pp.361-368
• /
• 2017

Alanate-based materials, which were known to have high hydrogen storage capacity, were synthesized by mechanochemically metathesis reaction of metal chloride and sodium alanate without solvent. XRD patterns of synthesized materials showed that metathesis reaction of cations between metal chloride and sodium alanate was progressed favorably without any solvent. Magnesium alanate showed that 3.2 wt.% of hydrogen was evolved by the thermal decomposition. The addition of a small amount of Ti to the magnesium alanate greatly reduced hydrogen evolution temperature. Also, Ti doped magnesium alanate had a good regeneration property. Both the calcium and lithium-magnesium alanate showed the lower starting temperature of the two step hydrogen evolution and fast kinetics for the hydrogen evolution.

• 전기학회논문지P
• /
• 제67권2호
• /
• pp.94-99
• /
• 2018

Depending on how the energy storage system(ESS) is used in a system that can construct a microgrid by using an independent power source such as campus, surplus power can be generated that can not be charged to the ESS. For example, assuming that heat is supplied by a fuel cell in the case of a system in which thermal self-sustaining is prioritized, the fuel cell capacity required differs depending on the heat load. The amount of surplus power that can not be stored in the ESS will appear differently depending on the load operation of the fuel cell for each cycle. This power is hydrogenated through a water electrolytic device to present the amount of hydrogen energy that can be operated for each cycle. Therefore, this paper propose the possibility of utilizing University campus as a hydrogen station.

• International Journal of Naval Architecture and Ocean Engineering
• /
• 제5권4호
• /
• pp.559-568
• /
• 2013

Increased worldwide concerns about fossil fuel costs and effects on the environment lead many governments and scientific societies to consider the hydrogen as the fuel of the future. Many researches have been made to assess the suitability of using the hydrogen gas as fuel for internal combustion engines and gas turbines; this suitability was assessed from several viewpoints including the combustion characteristics, the fuel production and storage and also the thermodynamic cycle changes with the application of hydrogen instead of ordinary fossil fuels. This paper introduces the basic environmental differences happening when changing the fuel of a marine gas turbine from marine diesel fuel to gaseous hydrogen for the same power output. Environmentally, the hydrogen is the best when the $CO_2$ emissions are considered, zero carbon dioxide emissions can be theoretically attained. But when the $NO_x$ emissions are considered, the hydrogen is not the best based on the unit heat input. The hydrogen produces 270% more $NO_x$ than the diesel case without any control measures. This is primarily due to the increased air flow rate bringing more nitrogen into the combustion chamber and the increased combustion temperature (10% more than the diesel case). Efficient and of course expensive $NO_x$ control measures are a must to control these emissions levels.

• 한국수소및신에너지학회논문집
• /
• 제30권1호
• /
• pp.21-28
• /
• 2019

Reversible solid oxide fuel cell (ReSOC) system was integrated with waste steam for electrical energy storage in distributed energy storage application. Waste steam was utilized as external heat in SOEC mode for higher hydrogen production efficiency. Three system configurations were analyzed to evaluate techno-economic performance. The first system is a simple configuration to minimize the cost of balance of plant. The second system is the more complicated configuration with heat recovery steam generator (HRSG). The third system is featured with HRSG and fuel recirculation by blower. Lumped models were used for system performance analyses. The ReSOC stack was characterized by applying area specific resistance value at fixed operating pressure and temperature. In economical assessment, the levelized costs of energy storage (LCOS) were calculated for three system configurations based on capital investment. The system lifetime was assumed 20 years with ReSOC stack replaced every 5 years, inflation rate of 2%, and capacity factor of 80%. The results showed that the exergy round-trip efficiency of system 1, 2, 3 were 47.9%, 48.8%, and 52.8% respectively. The high round-trip efficiency of third system compared to others is attributed to the remarkable reduction in steam requirement and hydrogen compression power owning to fuel recirculation. The result from economic calculation showed that the LCOS values of system 1, 2, 3 were 3.46 ¢/kWh, 3.43 ¢/kWh, and 3.14 ¢/kWh, respectively. Even though the systems 2 and 3 have expensive HRSG, they showed higher round-trip efficiencies and significant reduction in boiler and hydrogen compressor cost.

• 한국수소및신에너지학회논문집
• /
• 제30권4호
• /
• pp.303-311
• /
• 2019

Reversible solid oxide fuel cell (RSOFC) has become a prospective device for energy storage and hydrogen production. Many studies have been conducted around the world focusing on system efficiency improvement and realization. The system should have not only high efficiency but also a certain level of simplicity for stable operation. External waste steam utilization was proved to remarkably increase the efficiency at solid oxide electrolysis system. In this study, RSOFC system coupled with waste steam was proposed and optimized in term of simplicity and efficiency. Ejector for fuel recirculation is selected due to its simple design and high stability. Three system configurations using ejector for fuel recirculation were investigated for performance of design condition. In parametric study, the system efficiencies at different current density were analyzed. The system configurations were simulated using validated lumped model in EBSILON(R) program. The system components, balance of plants, were designed to work in both electrolysis and fuel cell modes, and their off-design characteristics were taken into account. The base case calculation shows that, the system with suction pump results in slightly lower efficiency but stack can be operated more stable with same inlet pressure of fuel and air electrode.

• 한국수소및신에너지학회논문집
• /
• 제10권3호
• /
• pp.151-157
• /
• 1999

The development of hydrogen vehicles has been actively progressed in the developed countries such as U. S., Japan and Germany. The most important technology of using hydrogen fuel is to develope a compatible storage tank with respect to the fossil fuel tank. Among many storage methods, the liquid hydrogen is the most desirable state because of the lowest volume and weight. The metal hydride tank is too heavy and the compressed hydrogen tank is too bulky. Because of these reasons, it is the principal purpose to analyze the theoretical heat transfer for designing and manufacturing an actual $LH_2$ tank. The insulation methods of the room between inner and outer vessel are non-vacuum, vacuum, vacuum with MLI(Multi-Layer Insulation). According to the results of the numerically calculated heat leak through the walls of the $LH_2$ tank, the vacuum insulated tank has 20 times and the MLI tank has 5616 times less heat leak than the non-vacuum tank.