• 대한화학회지
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• 제20권4호
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• pp.277-279
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• 1976

은 전극을 지시전극으로 하고 표준칼로멜 전극을 기준전극으로 하여 전압플로위회로를 이용하여 수용액에서 2,5-dimercapto-1,3,4-thiadiazole에 의한 구리의 전위차 적정법을 연구하였다. 이 시약은 구리의 전위차 적정 정량에 뛰어나게 이용할 수 있었고 여러가지 가리움제를 사용하여 다른 이온들의 존재하에 대기중에서 미량의 구리를 직접 적정할 수 있었다.

• Journal of information and communication convergence engineering
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• 제1권2호
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• pp.67-69
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• 2003

The experimental studies for the etch properties of the oxide grown on silicon substrate, which is in diluted hydrogen fluoride (HF) solution, are presented. Using different ion implantation dosages, dopants and energies, silicon substrate was implanted. The wet etching in diluted HF solution is used as a mean of wafer cleaning at various steps of VLSI processing. It is shown that the wet etch rate of oxide grown on various implanted silicon substrates is a strong function of ion implantation dopants, dosages and energies. This phenomenon has never been reported before. This paper shows that the difference of wet etch rate of oxide by ion implantation conditions is attributed to the kinds and volumes of dopants which was diffused out into $SiO_2$ from implanted silicon during thermal oxidation.

• Bulletin of the Korean Chemical Society
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• 제6권5호
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• pp.304-308
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• 1985

Morphological structure of tin oxide thin films was examined by transmission electron microscopy. TEM samples were prepared by chemical etching in hydrogen fluoride solution: firstly floating for 2-3 minutes in acid solution, then suspending on water found to be useful for the preparation of TEM samples. Electron micrographs showed the size of grains of the tin oxide crystal was dependent upon the temperature of the film preparation. Dopant concentration and heating time also influence the grain size. The resistivity of tin oxide material was explained by grain size and grain boundaries in a limited temperature and dopant concentration ranges.

• Archives of Plastic Surgery
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• 제35권4호
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• pp.407-412
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• 2008

Purpose: Hydrofluoric acid(HF) is one of the most dangerous mineral acids with the dissociated fluoride ions. The initial corrosive burn is caused by free hydrogen ion, and the second and more severe burn is caused by penetration of fluoride ions into subcutaneous tissues. Silver is a cation producing dressing, an effective antimicrobial agent, but older silver-containing formulations are rapidly inactivated by wound environment, requiring frequent replenishment. But, $Acticoat^{(R)}$ is a relatively new form of silver dressing which helps avoid the problems of earlier agents. The aim of this study is to evaluate effects of $Acticoat^{(R)}$, silver-containing dressing on the treatment for HF injury wound. Methods: From september 2006 to september 2007, the study was carried out with 10 patients who had HF partial thickness burns. $Acticoat^{(R)}$ dressing and 10% calcium gluconate wet gauze dressings in 10 cases. As a principle, in the emergency treatment, partial or complete removal of the nail and early bullectomy along with copious washing with normal saline was done, depending on the degree of HF invasion of the wound. Wound was dressed with $Acticoat^{(R)}$ and 10% calcium gluconate solution. The effect of dressing was investgated by serial bacterial culture and wound exudates assessment. Results: We therefore reviewed 10 cases of HF-induced chemical burns and treatment principle. The 10 cases who came to the hospital nearly immediately after the injury healed completely without sequelae. Conclusion: As the industrial sector develops, the use of HF is increasing more and more, leading to increased incidences of HF-induced chemical burns. The education of patients regarding this subject should be empathized accordingly. In conclusion, $Acticoat^{(R)}$ dressing is a better choice for HF partial thickness burn injuries because of shorter healing time, less pain and more comfortable dressing.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2001년도 춘계학술발표논문집
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• pp.18-25
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• 2001

A new wood-degrading fungus Trichophyton rubrum LKY-7 secretes a high level of laccase in a glucose-peptone liquid medium. The production of laccase by the fungus was barely induced by 2,5-xylidine. The laccase has been purified to homogeneity through three chromatography steps in an overall yield of 40%. The molecular mass of the purified laccase was about 65 kDa by sodium dodecyl sulfate polyacrylamide gel electrophoresis. The purified laccase had the distinct blue color and had basic spectroscopic features of a typical blue laccase: two absorption maxima at 278 and 610 nm and a shoulder at 338 nm. The N-terminus of the laccase has been sequenced, revealing high homology to laccases from wood-degrading white-rot fungi such as Ceriporiopsis subvermispora. The enzyme had a "low" redox potential (0.5 V vs normal hydrogen electrode), yet it was one of the most active laccases in oxidizing a series of representative substrates/mediators. Compared with other fungal laccases, the laccase has a very low Km value with ABTS [2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid] as a substrate and a very high Km value with violuric acid as a substrate. The laccase has the isoelectric point of 4.0. The laccase had very acidic optimal pH values (pH 3-4) while it was more stable at neutral pH than at acidic pH. The laccase oxidized hydroquinone faster than catechol and pyrogallol. The oxidation of tyrosine by the laccase was not detectable under the reaction conditions. The laccase was strongly inhibited by sodium azide and sodium fluoride. fluoride.

• 대한임상독성학회지
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• 제13권2호
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• pp.78-86
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• 2015

Purpose: The purpose of this study is to understand what kinds of chemical substances have been used annually and to investigate incidents that occurred due to chemical hazard release and to analyze statistically clinically chemical injury patients who visited one regional emergency medical center in Gumi city with documented references review. Methods: Annual chemical waste emission quantity (Kg/Year) (Cwep) was reproduced using national web site data governed by the Ministry of Environment and 5 years (from 1 .Jan. 2010 to 31. Dec. 2014) of medical records of chemical injury patients who visited our emergency department were reviewed retrospectively. By applying exclusion criteria, 446 patients of 460 patients were selected. Results: Dichloromethane, Toluene, Trichloroethylene, and Xylene were always included within Top 5 of Cweq. Six cases of chemical incidents were reported and in 3 of 6 cases involving Hydrogen fluoride were included during the study period. Male gender and twenties were the most prevalent group. Injury evoking chemicals were Hydrogen fluoride, unknown, complex chemicals (over 2 substances) in sequence. The most frequent site of wounds and injuries was the respiratory tract. Gas among status, intoxication among diagnosis, and discharge among disposition was most numerous in each group. Conclusion: There have been no uniform clinical protocols for chemical wounds and injuries due to various kinds of chemicophysical properties and ignorance of antidotes. Therefore conduct of a multicenter cohort study and experiments for ruling out chemicals according to chemicophysical priority as well as development of antidotes and clinical protocols for chemical injury patients is needed.

• 청정기술
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• 제18권3호
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• pp.301-306
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• 2012

급성장하고 있는 태블릿 PC와 스마트 폰과 같은 모바일 기기들은 제품 표면 보호를 위해 강한 소재인 터치스크린패널을 장착하고 있다. 따라서, 화학강화유리의 수요는 증가하게 되었고, 수요가 증가함에 따라 화학강화유리의 폐기량도 증가하게 되었다. 이 연구의 목적은 물질전과정평가(material life cycle assessment, MLCA) 기법을 사용하여 터치스크린패널에 사용되는 화학강화유리의 환경영향평가를 하는 것이다. MLCA의 소프트웨어로는 그란타의 씨이에스(CES), 시마프로(SimaPro), 가비(Gabi)를 사용하였다. 씨이에스 소프트웨어(CES software)를 통하여 2.7, 5.7, 10.3 inch 두께의 화학강화유리의 환경영향평가를 2가지 경우(폐기, 재사용)를 고려하여 수행하였다. 그 결과, 2.7, 5.7, 10.3 inch 화학강화유리를 재사용할 경우에 사용되는 에너지 값과 $CO_2$값은 폐기할 경우에 비해 약 51.4%, 46.6% 감소하는 것을 확인하였다. 시마프로 소프트웨어(SimaPro software)를 통해서는 11가지 영향범주를 평가하였는데, 11가지 영향범주 중에서 화석연료(fossil fuels), 무기물(inorganics)과 기후변화(climate change)가 주된 환경부하의 원인으로 나타났다. 그리고 가비(Gabi) 소프트웨어를 통해서 환경영향의 주된원인이 안티몬(antimony), 불화수소(hydrogen fluoride)라는 것을 알 수 있었다.

• 한국토양비료학회지
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• 제40권1호
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• pp.31-35
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• 2007

농작물 안전생산 및 대기환경 개선을 위한 기초 자료로 활용하기 위하여 유해가스에 의한 농작물 피해원인을 구명하였다. 작물 피해현지에서 유해가스에 의한 피해증상을 조사하였으며, 작물체중 유해성분 함량을 분석하였다. 또한, 2004년 경북지역 농공단지에서 발생한 작물피해 사례에 대한 피해원인 구명을 위하여 조사지역의 피해발생 당시 기상자료 및 오염원에서의 배출가스 농도를 적용한 오염물질 확산을 제시하였다. 주요 작물의 암모니아가스 피해증상은 잎 끝으로부터 백색으로 고사하며, 저농도의 경우에는 적갈색 반점이 나타나는 특징을 보였고 화훼류의 경우에는 꽃보다 잎의 피해가 심하게 나타났다. 불소가스 피해증상은 잎의 선단이나 가장자리 부분에 나타나는 특성이 있다. 또한, 유해가스로 인한 작물피해 현지 사례에서 피해 지역의 아황산가스 등농도(等濃度) 분포를 조사한 결과, 조사지역은 발생원으로부터 발생된 아황산가스 영향을 받고 있으며, 특히 계절별로는 기상요인에 따른 여름철의 피해가 우려되었다.

• 한국수자원학회논문집
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• 제56권12호
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• pp.845-853
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• 2023

최근 화학사고 증가와 함께 사고로 인한 재해에 대한 건수가 2012년부터 계속적으로 증가하고 있으며 국내 화학물질 사고 대표 사례인 구미 불산 사고를 보았을 때, 사고현장에 적용 가능한 기술이 미흡하여 피해가 확산되었다는 결과가 발생하였다. 따라서 본 논문에서 수질오염사고 대응체계를 위치기반에 맞춰 화학사고 발생 시 수환경에서 실시간 대응을 위한 위치기반의 지표측정방식의 GPS전자부자를 이용한 대체지표 추적에 대한 측정방법과 그에 대한 연구결과를 소개하고자 한다. 연구대상지는 불산사고가 발생했었던 지역인 구미시를 대상으로 김천시와 구미시 등 2개 시 로 이루어진 감천을 선정하였고 해당 대상지에 수질-수리 측정을 통해 GPS전자부자를 이용한 대체추적물질 추적에 대한 실험을 진행하였다. 이를 통해 GPS전자부자를 이용한 추적자실험에 있어 수질-수리 측정이 동시에 가능하며, 특히 해당 연구결과를 통해 GPS 전자부자를 활용한다면 하천 분야에서의 유출사고에 대한 재난대응체계에 상당히 도움이 될 것으로 사료된다.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.175-175
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• 2006

Considering the number of chemosensors that have been developed for the sensing of metal ions, only a few chemosensors for fluoride anion have been described in the literature that are based on fluorescent or chromogenic responses. We performed colorimetric anion sensing based on the binding of anion analytes with hydrogen donor group in polymer backbone resulting in naked-eye color change and fluorescent quenching. Our challenges using hydrogen donor moiety was designed effectively are continuing in order for high selectivity and sensitivity for ultimate applications such as fluid solution sensing in biomolecules and gas vapor sensing.