• Title/Summary/Keyword: Hydrogen Contents

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A Study on the Combustion Characteristics with Hydrogen Contents of SNG Fuel in Low-Swirl Combustor (저선회 연소기에서 합성천연가스(SNG) 연료의 수소함량에 따른 연소 특성 연구)

  • JEONG, HWANGHUI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.181-189
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    • 2017
  • This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

Effect of Cr and Mo Contents on Hydrogen Embrittlement of Tempered Martensitic Steels (템퍼드 마르텐사이트강의 수소취성에 미치는 Cr 및 Mo 함량의 영향)

  • Sang-Gyu, Kim;Jae-Yun, Kim;Hee-Chang, Sin;Byoungchul, Hwang
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.466-473
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    • 2022
  • The effect of Cr and Mo contents on the hydrogen embrittlement of tempered martensitic steels was investigated in this study. After the steels with different Cr and Mo contents were austenitized at 820 ℃ for 90 min, they were tempered at 630 ℃ for 120 min. The steels were composed of fully tempered martensite with a lath-type microstructure, but the characteristics of the carbides were dependent on the Cr and Mo contents. As the Cr and Mo contents increased, the volume fraction of film-like cementite and prior austenite grain size decreased. After hydrogen was introduced into tensile specimens by electrochemical charging, a slow strain-rate test (SSRT) was conducted to investigate hydrogen embrittlement behavior. The SSRT results revealed that the steel with lower Cr or lower Mo content showed relatively poor hydrogen embrittlement resistance. The hydrogen embrittlement resistance of the tempered martensitic steels increased with increasing Mo content, because the reduction in the film-like cementite and prior austenite grain size plays an important role in improving hydrogen embrittlement resistance. The results indicate that controlling the Cr and Mo contents is essential to achieving a tempered martensitic steel with a combination of high strength and excellent hydrogen embrittlement resistance.

THE EFFECT OF HYDROGEN AND OXYGEN CONTENTS ON HYDRIDE REORIENTATIONS OF ZIRCONIUM ALLOY CLADDING TUBES

  • CHA, HYUN-JIN;JANG, KI-NAM;AN, JI-HYEONG;KIM, KYU-TAE
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.746-755
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    • 2015
  • To investigate the effect of hydrogen and oxygen contents on hydride reorientations during cool-down processes, zirconium-niobium cladding tube specimens were hydrogen-charged before some specimens were oxidized, resulting in 250 ppm and 500 ppm hydrogen-charged specimens containing no oxide and an oxide thickness of $0.38{\mu}m$ at each surface. The nonoxidized and oxidized hydrogen-charged specimens were heated up to $400^{\circ}C$ and then cooled down to room temperature at cooling rates of $0.3^{\circ}C/min$ and $8.0^{\circ}C/min$ under a tensile hoop stress of 150 MPa. The lower hydrogen contents and the slower cooling rate generated a larger fraction of radial hydrides, a longer radial hydride length, and a lower ultimate tensile strength and plastic elongation. In addition, the oxidized specimens generated a smaller fraction of radial hydrides and a lower ultimate tensile strength and plastic elongation than the nonoxidized specimens. This may be due to: a solubility difference between room temperature and $400^{\circ}C$; an oxygen-induced increase in hydrogen solubility and radial hydride nucleation energy; high temperature residence time during the cool-down; or undissolved circumferential hydrides at $400^{\circ}C$.

Antioxidative Activity in Jeolpyun Containing Cnidium officinale M Extract (천궁 추출물 첨가 절편의 항산화활성)

  • Park, Kyung-Sook
    • The Korean Journal of Food And Nutrition
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    • v.35 no.4
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    • pp.259-267
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    • 2022
  • The purpose of this study was to evaluate the antioxidative activities of jeolpyun containing Cnidium officinale M extract (2%, 4%, 6%, 8%) by total polyphenol contents, electron donating ability on 2,2-diphenyl-1-picrylhydrazyl (DPPH), scavenging ability of superoxide anion radical and decomposing ability of hydrogen peroxide. In chromaticity analysis, the brightness significantly decreased with increasing Cnidium officinale M extract content. Jeolpyun containing 8% Cnidium officinale M extract revealing the highest value for the redness and the yellowness, 1.07, 12.70, respectively. The total polyphenol contents of jeolpyun containing 8% Cnidium officinale M extract were the highest content of 4,213 ㎍ gallic acid equivalent (GAE)/mL. The total polyphenol contents revealed significant difference (p<0.05). Jeolpyun containing 8% Cnidium officinale M extract revealing the highest electron donating ability (83.55%). The electron donating abilities were significantly related at p<0.05. The scavenging abilities of superoxide anion radical for jeolpyun containing 4% Cnidium officinale M extract revealed the highest ability (0.01676). There was no significant difference. The hydrogen peroxide decomposing ability for jeolpyun containing 8% Cnidium officinale M extract revealed the most hydrogen peroxide decomposing ability (-0.193) and the hydrogen peroxide decomposing ability revealed a significant difference (p<0.05).

Metabolism of $^{14}C$ Glycine-Glucose Melanoidin and Soybean Sauce ($^{14}C$ Glycine-Glucose Melanoidin 과 양조간장의 대사)

  • 문갑순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.2
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    • pp.333-339
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    • 1994
  • The metabolic transit of three samples( 14C glycine-glyucose melanoidin, glycine-glucose melanoidin and soybean sauce ) were studied on rats. The radioactivity of various organs and excreta intubated 14C glycine-glucose melanoidin on rats at various intervals(1, 3, 8, 12, 24, 48, 72 and 96 hrs were detected . And the brown pigment contents and hydrogen donating activities in the excreta which is obtained from three samples were detected during the 7 days after intubated. The total amount of 14C excreted in the fecese were 53% meaning that the rest of 47% melanoidin seemed to be retained in the body or metabolized . The radioactive compound showed a small retention in the liver and kidney. The brown pigment contents and hydrogen donating activities in the urine and feces increased proportionally to the activity of 14C. When the soybean sauce and glycine glucose melanoidin were intubated, the brown pigment contents excreted in the feces were found to be the highest after 1 st day of intubation. In the urine, the model melanoidin was excreted mostly after 3 days of intubation. The brown pigment contents and hydrogen donating activities of three samples of excreta agreed with each other. The soybean sauce retained longer than model melanoidin in the body is telling that it might have antioxidative activity in vivo.

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Antioxidative Activity of Jeolpyun Containing Smilacis chinae R. Extract (토복령 추출물 첨가 절편의 항산화 활성)

  • Park, Kyung-Sook
    • The Korean Journal of Food And Nutrition
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    • v.34 no.5
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    • pp.537-544
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    • 2021
  • In this study, antioxidative activities of Jeolpyun containing Smilacis chinae R. extract powder (2%, 4%, 6%, 8%) were evaluated using total polyphenol contents, electron donating ability on 2,2-diphenyl-1-picrylhydrazyl (DPPH) and decomposing ability of hydrogen peroxide. In chromaticity analysis, the brightness significantly decreased with increasing Smilacis chinae R. extract powder content. Jeolpyun containing 6% Smilacis chinae R. extract powder revealed the highest value (9.67±0.603) for the redness and 2% Smilacis chinae R. extract powder was the highest value (14.20±0.917) for the yellowness. Total polyphenol contents of Jeolpyun containing 8% Smilacis chinae R. extract powder were the highest content of 17,320±390.38 ㎍ gallic acid equivalent/mL (GAE/mL). Total polyphenol contents were significant relation at p<0.05. Electron donating ability for Jeolpyun containing 8% Smilacis chinae R. extract powder revealed the highest electron donating ability (74.24±0.827%). Electron donating abilities revealed significant difference (p<0.05). Jeolpyun containing 6% Smilacis chinae R. extract powder revealed the most hydrogen peroxide decomposing ability (-3.38±1.44) and hydrogen peroxide decomposing ability revealed significant difference (p<0.05).

Relationship Between Relative Water Content and Ascorbate Redox Enzymes Activity in Lettuce Leaves Subjected to Soil Water Stress (토양 수분 Stress에 따른 상추의 엽중 상대수분 함량과 아스코브산 관련 효소 활성도)

  • Kang, Sang-Jae;Park, Man
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.1
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    • pp.32-39
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    • 2013
  • The relationship between relative water contents of lettuce leaves and biochemical activities in lettuce was examined in this study to explore an adaptation response of lettuce to water stress from soils. Soil water contents and relative water contents of leaves were positively related to show $R^2$=0.8728. Hydrogen peroxide contents of leaves rapidly increased with reduction of soil water content, whereas soluble protein contents and dry matters rapidly decreased. And chlorophyll a and b contents of leaves decreased with increase in carotenoid content. Furthermore, the activities of ascorbate peroxidase (APX), monodehydroascorbate reductase (MDHAR), and dehydroascorbate reductase (DHAR) increased dramatically, and mRNA transcript levels of APX, MDHAR and DHAR also increased. Relationship of relative water content of lettuce leaves to hydrogen peroxide, to ascorbate peroxidase activity, to dehydroascorbate reductase activity, and to monodehydroascorbate reductase activity was shown to be positively correlated. It is highly plausible from this study that these enzyme activities could be developed as an indicator of water states in soils.

Measurement of hydrogen content in a-C:H films prepared by ECR-PECVD (ECR-PECVD 방법으로 증착된 a-C:H 박막의 수소함량 측정)

  • 손영호;정우철;정재인;김인수;배인호
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.119-126
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    • 2001
  • Hydrogenated amorphous carbon (a-C:H) films were deposited by ECR-PECVD (electron cyclotron resonance-plasma enhanced chemical vapor deposition) method with deposition conditions such as ECR plasma source power, gas composition of methane and hydrogen, deposition time and substrate bias voltage. The hydrogen content in the films has been measured by ERDA (elastic recoil detection analysis) using 2.5 MeV $He^{++}$ ion beam. From the results of AES (Auger electron spectroscopy), RBS (Rutherford backscattering spectrometry) and ERDA, the composition elements of deposited film were confirmed the carbon atom and the hydrogen atom. It was observed by FTIR (Fourier transform infrared) that the hydrogen contents in the film varied according to the deposition conditions. In deposition condition of substrate bias voltage, the hydrogen contents were decreased remarkably because the amount of dehydrogenation in films was increased as the substrate bias voltage increased. In the rest deposition conditions, the hydrogen contents in the film were measured in the range 45~55%.

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The Long Term Effect of Buchu (Chinese chives) Diet on ROS Formation in the Liver and Skin Tissue of ICR mice (장기간의 부추식이가 ICR 마우스의 간과 피부조직의 활성산소종 생성에 미치는 영향)

  • 문갑순;이민자
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.3
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    • pp.444-449
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    • 2003
  • To investigate the long term effect of buchu (Chinese chives) diet on ROS formation in the liver and stin tissue of ICR mice, one of control, 2% or 5% buchu-added diet was fed to ICR mice for 12 months. Superoxide anion (O2ㆍ), hydrogen peroxide($H_2O$$_2$) and hydroxyl radical (ㆍOH) contents were measured in cytosol, microsome, mitochondria of liver and skin of mice, respectively. Behu diet showed a significant decrease of superoxide anion, hydrogen peroxide and hydroxyl radical contents in liver and skin tissues compared to control diet, and this effect is especially higer at 5% than at 2% buchu diet level. ICR mice showed an age-dependent increase in ROS contents, while the group fed buchu diet decreased its ROS contents significantly and ROS contents of liver appeared to be 2 fold higher than skin. The results of the present study suggest that antioxidative components and sulfur-compounds in buchu diet appear to be responsible for the inhibition of ROS formation in ICR mice.