• 산업기술연구
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• 제41권1호
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• pp.25-30
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• 2021

Hydride-dehydride process for efficient recycling of tantalum (Ta) is used for manufacturer of Ta powder. In case of metal powder, Impurities as like nitride, oxygen, hydrogen is decreased of physical properties. For manufacture of Ta powder, control of theses impurities is important. In this study, to decreased of impurities on Ta powder using HDH process optimize dehydride condition. Dehydration behavior of Ta is depended on temperature, time, and atmosphere. Phase transition of Ta hydride is analyzed by X-ray diffraction (XRD). Concentration of hydrogen is decreased with temperature increased. At high temperature, concentration of hydrogen in Ta is similar according to time increased. Size and morphology of powder is not observed after dehydride. Ta powder, which is less than 20 um, concentration of hydrogen under 800 ppm is obtain.

• 자원리싸이클링
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• 제27권5호
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• pp.30-37
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• 2018

국내 발생하는 고순도 탄탈륨 스크랩을 재활용하기 위해 수소화-탈수소화법(HDH법)에 의한 탄탈륨 분말 제조 연구를 실시하였다. 탄탈륨은 연성 및 강도가 우수하며 융점 또한 높아 분말 제조가 어려운 금속으로 알려져 있다. 따라서 본 연구에서는 수소화를 통해 생성된 탄탈륨 수소화물을 이용하여 탄탈륨 분말을 제조하였다. $500^{\circ}C$, 5시간/$700^{\circ}C$, 3시간 수소화 조건에서 탄탈륨 수소화물이 생성되었고, 탄탈륨 내의 수소는 격자의 팽창 및 전위의 결함으로 작용하므로 탄탈륨 수소화물 분말을 제조하기에 용이하였다. Ring mill을 이용하여 1300 rpm, 30분 이상의 조건에서 $10{\mu}m$ 이하의 크기로 분쇄하였으며, 알곤 및 저진공 분위기에서 탈수소화 공정을 통해 수소 50 ppm 이하의 탄탈륨 분말을 제조하였다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.759-760
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• 2006

Ti-6Al-4V has low specific gravity, high corrosion resistance and superior mechanical properties but it is very difficult to control oxygen content in MIM process. It is necessary to use powders with coarse particle size to decrease oxygen content of powders, so feedstocks with poor fluidity and sintered bodies with lower density are obtained in such cases. Fine titanium hydride-dehydride powders were blended with atomized powders to accomplish higher fluidity and sintered density. Sintered bodies had higher sintered density and mechanical properties equivalent to those of wrought materials by controlling oxygen content less than 0.35mass%.

• 한국분말재료학회지
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• 제16권1호
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• pp.28-32
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• 2009

The activation temperatures and hydrogen sorption rates of $Ti_{80-X}Zr_{20}V_X$ alloys were evaluated at room temperature. The alloy powders were prepared by arc melting and then hydride-dehydride(HDH) process. The alloy powders were apt to activate by increase of vanadium in Ti-Zr-V alloys. The easy activation was explained in terms of surface oxygen content which decreased with increase of vanadium on Ti-Zr-V alloys.