• Journal of Electrochemical Science and Technology
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• 제3권2호
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• pp.72-79
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• 2012

$Li_2MnSiO_4$ was synthesized using the solid-state method under an Ar atmosphere at three different calcination temperatures (900, 950, and $1000^{\circ}C$). The optimization of the carbon coating was also carried out using various molar concentrations of adipic acid as the carbon source. The XRD pattern confirmed that the resulting $Li_2MnSiO_4$ particles exhibited an orthorhombic structure with a $Pmn2_1$ space group. Cyclic voltammetry was utilized to investigate the capacitive behavior of $Li_2MnSiO_4$ along with activated carbon (AC) in a hybrid supercapacitor with a two-electrode cell configuration. The $Li_2MnSiO_4$/AC cell exhibited a high discharge capacitance and energy density of $43.2Fg^{-1}$ and $54Whkg^{-1}$, respectively, at $1.0mAcm^{-2}$. The $Li_2MnSiO_4$/AC hybrid supercapacitor exhibited an excellent cycling stability over 1000 measured cycles with coulombic efficiency over > 99 %. Electrochemical impedance spectroscopy was conducted to corroborate the results that were obtained and described.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.422.2-422.2
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• 2016

스마트폰, 태블릿 등의 디바이스의 발전에 따라 휴대성이 매우 중요해졌다. 디바이스의 크기, 두께, 유연성에 관한 연구가 활발히 진행되고 있으며, 그 중에서도 energy storage device의 flexibility를 향상시키는 연구가 주목 받고 있다. Energy storage device의 성능 향상을 위해서는 power density를 높여야 하며 flexibility를 위해서는 전극판과 전극소재 간의 부착력을 증가시켜야 한다. 본 연구에서는, power density와 소재 간의 부착성을 개선시키기 위해 기존 graphene보다 표면적이 넓으며 power density가 좋고 전극판과의 부착성이 좋은 hybrid GNP-CNT를 사용하였다. 그리고 Ag NWs/CNT PET film 을 사용하여 전도성이 있는 flexible한 전극판을 사용하였다. SEM 측정을 통해 표면 분석을 하였고, sample에 패턴을 하고 Bending test를 하여 부착성을 확인하였다. 또한, CV curve를 측정하여 supercapacitor의 특성을 확인하였다. 향후, $MnO_2$ NWs를 hybrid GNP-CNT에 합성시킴으로 energy storage device의 energy density를 더욱 향상시키는 연구를 진행할 것이다.

• 전기학회논문지
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• 제59권1호
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• pp.65-69
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• 2010

Supercapacitors as novel energy storage devices between conventional capacitors and batteries, with more specific capacitance and energy densities than conventional capacitors and more power densities than batteries are to be used in many fields. And, social demand on fuel economy and reducing pollution needs equipment of new function such as energy storage system with good power performance, high cyclability and good energy efficiency. Supercapacitor is regarded as one of good alternatives for meeting the requirement of market with excellent power performance and high cyclability. This paper deals with the fundamental characteristics of supercapacitor unit and charge and discharge behavior of supercapacitor module for developing 42V hybrid energy storage system with lead acid battery and supercapacitor in order to adopt to 42V power net for vehicle.

• 한국생산제조학회지
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• 제25권4호
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• pp.307-311
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• 2016

Several types of supercapacitors have been developed for energy storage systems. Among them, the hybrid type has advantages such as a large capacitance per weight compared with the electric double-layer capacitator type. In this study, constant current charging and discharging tests were conducted for recently developed hybrid-type supercapacitors. Based on the experimental results, the capacitance and equivalent series resistance were obtained. The capacitance was larger than the designed capacitance at a low current but became small at a high current. In addition, the capacitance depended on the cell voltage. These results can be used to design an energy storage system.

• 조명전기설비학회논문지
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• 제28권12호
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• pp.18-29
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• 2014

This paper proposes the integration of photovoltaic (PV) and energy storage systems for sustained power generation. In this proposed system, whenever the PV system cannot completely meet load demands, the super capacitor provides power to meet the remaining load. A power management strategy is designed for the proposed system to manage power flows between PV array systems and supercapacitors (SC). The main task of this study was to design PV systems with storage strategies including MPPT with direct control and an advanced DC-link controller and to analyze dynamic model proposed for a PV-SC hybrid power generation system. In this paper, the simulation models for the hybrid energy system are developed using Matlab/Simulink, SimPowerSystems and Matlab/Stateflow tool. This is the key innovative contribution of the research paper. The system performances are verified by carrying out simulation studies using practical load demand profile and real weather data.

• 정보저장시스템학회논문집
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• 제9권1호
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• pp.22-27
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• 2013

In this paper we are presenting a architecture of Co ion decorated graphene oxide as an electrode for supercapacitor application. Graphene oxide, which is exfoliated by oxidant from graphite, is the material for solving the problem of mass production and coating on the surface of working electrode. The $Co^{2+}$ ions are coated by using layer by layer(LBL) method on graphene oxide foam. The metal ion decorated graphene oxide shows enhanced capacitance performance when tested as supercapacitor electrode, showing the specific capacitance of $827Fg^{-1}$.

• 드라이브 ㆍ 컨트롤
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• 제16권2호
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• pp.80-90
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• 2019

Fuel cell hybrid electric vehicle is an attractive solution to reduce pollutants, such as noise and carbon dioxide emission. This study presents an approach for energy management and control algorithm based on energetic macroscopic representation for a fuel cell hybrid electric vehicle that is powered by proton exchange membrane fuel cell, battery and supercapacitor. First, the detailed model of the fuel cell hybrid electric vehicle, including fuel cell, battery, supercapacitor, DC-DC converters and powertrain system, are built on the energetic macroscopic representation. Next, the power management strategy was applied to manage the energy among the three power sources. Moreover, the control scheme that was based on back-stepping sliding mode control and inversed-model control techniques were deduced. Simulation tests that used a worldwide harmonized light vehicle test procedure standard driving cycle showed the effectiveness of the proposed control method.

• 한국전기전자재료학회논문지
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• 제36권2호
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• pp.175-185
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• 2023

A hybrid supercapacitor is a promising energy storage device in view of its excellent capacitive performance. Commercial three-dimensional foam nickel (Ni) can be used as an ideal framework due to an interconnected network structure. However, its application as an electrode material for supercapacitors is limited due to its low specific capacity. Herein, we report a successful growth of MnO₂ on the surface of graphene by a one-step hydrothermal method; thus, forming a three-dimensional MnO₂-graphene-Ni hybrid foam. Our results show that the mixed structure of MnO₂ with nanoflowers and nanorods grown on the graphene/Ni foam as a hybrid electrode delivers the maximum specific capacitance of 193 F·g^-1 at a current density 0.1 A·g^-1. More importantly, the hybrid electrode retains 104% of its initial capacitance after 1,000 charge-discharge cycles at 1 A·g^-1; thus, showing the potential application as a stable supercapacitor electrode.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.266-266
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• 2009

For the development of hybrid supercapacitor, increasing energy density is one of the most crucial matters. Since the energy density is the function of capacitance and voltage, it is necessary to enhance energy density for increasing capacitance or voltage. For the high working voltage, it was to enforce Li ion free-doping to activated carbon. As a result, initial capacitance has increased by 11% than raw cell. But capacitance has decreased by Li ion re-solution to electrolyte for increase the number of cycle.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2009년도 추계학술대회 논문집
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• pp.285-289
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• 2009

In this paper, we propose to research the dynamic Matlab/Simulink model of supercapacitor bank(SCB) for a microgrid application. We demonstrated that this model id sufficient to design the control system of entire power storage system, SCB, the chopper and grid connected converter. The proposed dynamic model is simulated with the help of Matlab/$Simulink^{TK}$ in the MTG/PC/SCB hybrid energy system. The study results show that SCB have a good performance to curb power fluctuation in building microgrid application.