• 제목/요약/키워드: Hybrid polymer

검색결과 626건 처리시간 0.022초

광촉매 반응기용 세라믹 막에의 TiO2 층 형성과 성능평가 (In-situ TiO2 Formation and Performance on Ceramic Membranes in Photocatalytic Membrane Reactor)

  • 리즈완 아마드;김진규;김종학;김정환
    • 멤브레인
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    • 제27권4호
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    • pp.328-335
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    • 2017
  • 메조포러스 공극구조를 갖는 광촉매 멤브레인은 다양한 환경기술에 적용될 수 있다. 본 연구에서는 $TiO_2$ 층을 형성시킨 광촉매 반응기용 세라믹 멤브레인을 개발하고 이를 염색용액 처리에 적용하였다. 높은 공극률과 균질성을 지닌 $TiO_2$ 광촉매층을 그라프트 공중합체를 사용하여 제조하였다. 멤브레인은 광촉매 반응기와 멤브레인 여과를 결합시킨 하이브리드 광촉매 반응기에 성공적으로 적용하였다. 실험결과 정렬된 구조의 $TiO_2$ 층이 $Al_2O_3$ 지지체에 형성되었다. $TiO_2$ 층 형성 후 제조된 세라믹 분리막의 순수 투과도는 형성된 광촉매 층 저항으로 감소하였다. 정렬된 구조의 $TiO_2$ 층은 UV 결합 시 5시간 안에 완벽한 염색용액 분해를 달성시킬 수 있었다. 광촉매 멤브레인의 염색용액 분해는 Langmuir-Hinshelwood 흡착 모델로 잘 설명할 수 있었다. 또한 $TiO_2$ 층이 고정화된 세라믹 멤브레인의 model Congo Red에 대한 1차 속도상수는 $Al_2O_3$ 지지체 단독인 경우에 비해 약 6배 정도 큰 값을 나타내었다(0.0081 vs. $0.0013min^{-1}$).

UPS 파워 팩 내부 연료전지의 냉각특성에 대한 수치 해석 (A Study on Numerical Analysis for Internal PEMFC Cooling of Power Pack for UPS)

  • 송준석;김병헌
    • 한국산학기술학회논문지
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    • 제18권4호
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    • pp.527-535
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    • 2017
  • 연료전지 배터리 하이브리드 UPS용 연료전지 파워 팩 내부에 설치한 연료전지의 화학반응에 의해 생성되는 열을 제거하는데 어려움이 있다. 열을 제거하지 못할 경우 연료전지의 내구성과 성능에 영향을 끼쳐 수명 단축의 원인이 된다. UPS용 연료전지 파워 팩 제작을 위하여 연료전지의 적절한 냉각 방법을 선정하고 제시하는 것이 본 연구의 목표이다. 냉각방법 선정을 위해 냉각 성능에 영향을 주는 각각의 설계 인자를 변화시키면서 연구를 수행하였다. 전산해석은 상용프로그램인 COMSOL Multiphysics로 수행하였다. 먼저 연료전지 스택의 냉각 팬의 위치를 상단과 하단에 배치했을 때 1 kW급 연료전지 스택 표면온도를 비교하였으며, 각각의 위치에 따른 냉각 팬의 회전속도를 2,500, 3,000, 3,500, 4,000 RPM으로 변경하여 적절한 냉각 팬의 속도를 결정하였다. 또한 파워 팩 외부에서 내부로 들어오는 공기의 입구인 그릴의 타공면적을 달리하여 내부로 들어오는 공기의 유량이 냉각에 미치는 영향을 비교하였다. 본 연구는 UPS용 연료전지 파워 팩 내부 연료전지의 열관리 기술개발에 효과적으로 활용될 수 있을 것으로 판단된다.

전기 방사를 이용한 1D / 2D 하이브리드 구조 고활성 MoS2 / CNF 수소 발생 촉매의 합성 및 특성 분석 (MoS2/CNFs derived from Electrospinning and Heat treatment as the Efficient Electrocatalyst for Hydrogen Eovlution Reaction in Acidic Solution)

  • 이정훈;박유세;장명제;박성민;이규환;최우성;최승목;김양도
    • 대한금속재료학회지
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    • 제56권12호
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    • pp.885-892
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    • 2018
  • Molybdenum disulfide ($MoS_2$) based electrocatalysts have been proposed as substitutes for platinum group metal (PGM) based electrocatalyst to hydrogen evolution reaction (HER) in water electrolysis. Here, we studied $MoS_2/CNFs$ hybrid catalyst prepared by electrospinning method with heat treatment for polymer electrolyte membrane(PEM) water electrolysis to improve the HER activity. The physicochemical and electrochemical properties such as average diameter, crystalline properties, electrocatalitic activity for HER of synthesized $MoS_2/CNFs$ were investigated by the Scanning Electron Microscope (SEM), X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Raman Spectroscopy (Raman) and Linear Sweep Voltammetry (LSV). The as spun ATTM/PVP nanofibers were prepared by sol-gel and electrospinning method. Subsequently, the $MoS_2/CNFs$ was dereived from reduction heat treatment of ATTM at the ATTM/PVP nanofibers and carbonization heat treatment. Synthesized $MoS_2/CNFs$ electrocatalyst had an average diameter of $179{\pm}30nm$. We confirmed that the $MoS_2$ layers in $MoS_2/CNF$ electrocatalyst consist of 3~4 layers from the Raman results. In addition, We confirmed that the $MoS_2$ layers in $MoS_2/CNF$ catalyst consist of 7.47% octahedral 1T phase $MoS_2$, 63.77% trigonal prismatic 2H phase $MoS_2$ with 28.75% $MoO_3$ through the XRD, Raman and XPS results. It was shown that $MoS_2/CNFs$ had the overpotential of 0.278 V at $10mA/cm^2$ and tafel slope of 74.8 mV/dec in 0.5 M sulfuric acid ($H_2SO_4$) electrolyte.

무정제 단일벽 탄소나노튜브와 은나노와이어가 적층으로 코팅된 투명전도성 고분자 필름의 전기 전도성, 광학 투과도 및 산화안정성 (Electrical Conductivity, Optical Transmittance, and Oxidation Stability of Transparent Conductive Polymer Film Coated With Layered Pristine Single-walled Carbon Nanotube and Silver Nanowire)

  • 이영실
    • Korean Chemical Engineering Research
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    • 제61권3호
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    • pp.456-462
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    • 2023
  • 탄소나토튜브를 투명 전극에 활용하기 위한 필수요소인 정제과정없이 무정제 단일벽 탄소나노튜브(single-walled carbon nanotube, SWCNT)와 은나노와이어(silver nanowire) 분산액을 제조하여 폴리에틸렌 테레프탈레이트(polyethylene terephthalate, PET) 필름에 바 코팅을 이용하여 전기전도성 투명전극을 제조하였다. PET 기판 위에 SWCNT 및 은 나노와이어를 각각 포함하는 코팅층을 상호 교차시켜 적층함으로서 은나노와이어의 전기 전도도와 투과도를 극대화시키고 헤이즈 (haze)가 증가되는 단점을 극복하기 위해 SWCNT를 도입하였고, 무정제 SWCNT내에 존재하는 금속 촉매의 산화에 의해서 항온항습 테스트 후 저항이 급격하게 증가하는 문제를 은 나노와이어가 전기적 네트워크 형성에 기여하여 산화에 대한 안정성을 확보할 수 있었다. SWCNT함량이 0.025 wt% 인 분산액을 PET 기판에 먼저 코팅하고 그 위에 은 나노와이어의 함량이 0.05 wt%인 분산액을 코팅한 투명전극의 시트 저항은 47 Ω/□, 투과도는 96.72%, 헤이즈는 1.93% 로 전기적 광학적 특성이 우수하게 나왔고, 산화 안정성 평가를 위한 항온 항습 실험 후 시트 저항의 변화율이 6.4% 로 적게 나타나서 장기적 사용에 적합하다는 것을 알 수 있었다. 무정제 SWCNT 사용함으로 저비용, 친환경 하이브리드 투명전극을 상업적으로 활용 가능한 수준의 제품이 개발되었다.

Flowable 및 microfill 복합레진으로 충전된 제 5급와동에서 load cycling 전,후의 미세변연누출 비교 (MICROLEAKAGE OF MICROFILL AND FLOWABLE COMPOSITE RESINS IN CLASS V CAVITY AFTER LOAD CYCLING)

  • 강석호;김오영;오명환;조병훈;엄정문;권혁춘;손호현
    • Restorative Dentistry and Endodontics
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    • 제27권2호
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    • pp.142-149
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    • 2002
  • Low-viscosity composite resins may produce better sealed margins than stiffer compositions (KempScholte and Davidson, 1988: Crim, 1989). Plowable composites have been recommended for use in Class V cavities but it is also controversial because of its high rates of shrinkage. On the other hand, in the study comparing elastic moduli and leakage, the microfill had the least leakage (Rundle et at. 1997) Furthermore, in the 1996 survey of the Reality Editorial Team, microfills were the clear choice for abfraction lesions. The purpose of this study was to evaluate the microleakage of 6 compostite resins (2 hybrids, 2 microfills, and 2 flowable composites) with and without load cycling. Notch-shaped Class V cavities were prepared on buccal surface of 180 extracted human upper premolars on cementum margin. The teeth were randomly divided into non-load cycling group (group 1) and load cycling group (group 2) of 90 teeth each. The experimental teeth of each group were randomly divided into 6 subgroups of 15 samples. All preparations were etched, and Single bond was applied. Preparations were restored with the following materials (n=15) : hybrid composite resin [Z250(3M Dental Products Inc. St. Paul, USA), Denfil(Vericom, Ahnyang, Korea)], microfill [Heliomolar RO(Vivadent, Schaan, Liechtenstein), Micronew(Bisco Inc. Schaumburg, IL, USA)], and flowable composite[AeliteFlo(Bisco Inc. Schaumburg, IL, USA), Revolution(Kerr Corp. Orange, CA, USA)]. Teeth of group 2 were subjected to occlusal load (100N for 50,000 cycles) using chewing simulator(MTS 858 Mini Bionix II system, MTS Systems Corp. Minn. USA). All samples were coated with nail polish 1mm short of the restoration, placed in 2% methylene blue for 24 hours, and sectioned with a diamond wheel. Enamel and dentin/cementum margins were analyzed for microleakage on a sclale of 0 (no leakage) to 3 (3/3 of wall). Results were statistically analyzed by Kruscal-Wallis One way analysis, Mann-Whitney U-test, and Student-Newmann-Keuls method. (p = 0.05) Results : 1. There was significantly less microleage in enamel margins than dentinal margins of all groups (p<0.05) 2. There was no significant between six composite resin in enamel margin of group 1. 3. In dentin margin of group 1, flowable composite had more microleakage than others but not of significant differences. 4. there was no significant difference between six composite resin in enamel margin of group 2. 5. In dentin margin of group 2, the microleakage were R>A =H=M>D>Z. But there was no significant differences. 6. In enamel margins, load cycling did not affect the marginal microleakage in significant degree. 7. In enamel margins, load cycling did affect the marginal microleakage only in Revolution. (p<0.05).

설비공학회 분야의 최근 연구 동향 : 2015년 학회지 논문에 대한 종합적 고찰 (Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2015)

  • 이대영;김사량;김현정;김동선;박준석;임병찬
    • 설비공학논문집
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    • 제28권6호
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    • pp.256-268
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    • 2016
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2015. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering were carried out in the areas of flow, heat and mass transfer, cooling and heating, and air-conditioning, the renewable energy system and the flow inside building rooms. Research issues dealing with air-conditioning machines and fire and exhausting smoke were reduced. CFD seems to be spreading to more research areas. (2) Research works on heat transfer area were carried out in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the economic analysis of GHG emission, micro channel heat exchanger, effect of rib angle on thermal performance, the airside performance of fin-and-tube heat exchangers, theoretical analysis of a rotary heat exchanger, heat exchanger in a cryogenic environment, the performance of a cross-flow-type, indirect evaporative cooler made of paper/plastic film. In the area of pool boiling and condensing, the bubble jet loop heat pipe was studied. In the area of industrial heat exchangers, researches were performed on fin-tube heat exchanger, KSTAR PFC and vacuum vessel at baking phase, the performance of small-sized dehumidification rotor, design of gas-injection port of an asymmetric scroll compressor, effect of slot discharge-angle change on exhaust efficiency of range hood system with air curtain. (3) In the field of refrigeration, various studies were carried in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, a cold-climate heat pump system, $CO_2$ cascade systems, ejector cycles and a PCM-based continuous heating system were investigated. In the alternative refrigeration/energy system category, a polymer adsorption heat pump, an alcohol absorption heat pump and a desiccant-based hybrid refrigeration system were investigated. In the system control category, turbo-refrigerator capacity controls and an absorption chiller fault diagnostics were investigated. (4) In building mechanical system research fields, eighteen studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, and renewable energies, piping in the buildings. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which can improve the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the user and location awareness technology applied dimming lighting control system, the lighting performance evaluation for light-shelves, the improvement evaluation of air quality through analysis of ventilation efficiency and the evaluation of airtightness of sliding and LS window systems. The subjects of building energy were worked on the energy saving estimation of existing buildings, the developing model to predict heating energy usage in domestic city area and the performance evaluation of cooling applied with economizer control. The studies were also performed related to the experimental measurement of weight variation and thermal conductivity in polyurethane foam, the development of flame spread prevention system for sandwich panels, the utilization of heat from waste-incineration facility in large-scale horticultural facilities.