• 제목/요약/키워드: Hybrid polymer

검색결과 626건 처리시간 0.028초

복합구조 댐퍼를 적용한 고 감쇠 폴리머 콘크리트의 진동 특성에 관한 연구 (Vibrational Properties of High Damping Polymer Concrete with Hybrid Damper)

  • 김정진;최경석;위준우;석원균
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권5호
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    • pp.135-142
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    • 2020
  • 구조물을 구성하고 있는 콘크리트의 경우, 진동에 대한 감쇠성능이 작아, 구조물에서 발생하는 다양한 진동 문제를 해결하는데 어려움이 있으므로, 이러한 문제를 해결하기 위해, 최근 폴리머 콘크리트와 복합구조 댐퍼를 혼합하여 댐핑 성능을 크게 증가시킨 고 감쇠 시스템에 대한 연구가 활발히 진행되고 있다. 한편, 폴리머 콘크리트는 배합 시, 시멘트와 물을 사용하지 않아, 경화시간이 매우 짧고, 물리적 특성 및 동특성 등이 매우 우수하여 진동저감이 요구되는 건축구조물에의 폭넓은 활용이 기대되는 구조재료이며, 복합구조 댐퍼는 파이프 관 내부에 위치한 쇠구슬의 충돌에 따른 운동에너지 소산과 점성유체의 에너지 소산 방식을 통해 진동을 저감하는 구조시스템이라 할 수 있다. 본 연구에서는 폴리머 콘크리트와 복합구조 댐퍼의 물리적, 동적 특성을 일반 콘크리트와 비교하였는데, 물리적 특성의 경우, 폴리머 콘크리트가 탄성계수 및 강도 특성에서 상당히 우수한 결과를 보였으며, 특히 인장강도는 6.5~10배 이상 큰 차이를 보였다. 또한, 동적 특성의 경우도 폴리머 콘크리트는 일반 콘크리트 대비 동적강성은 25%, 감쇠비는 약 3배 정도 증가하였으며, 복합구조 댐퍼는 동적강성은 비슷한 경향을 보였지만 감쇠비는 3.5배 이상 증가하여, 일반 콘크리트보다 진동 감쇠성능이 우수한 것으로 나타났다.

개량형 가동보에 적용하기 위한 하이브리드 강판/GFRP 패널 게이트의 강판게이트 표면형상에 따른 휨 및 계면 부착 특성 평가 (Flexural and Interfacial Bond Properties of Hybrid Steel/Glass Fiber Reinforced Polymer Composites Panel Gate with Steel Gate Surface Deformation for Improved Movable Weir)

  • 김기원;권형중;김필식;박찬기
    • 한국농공학회논문집
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    • 제57권2호
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    • pp.57-66
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    • 2015
  • The purpose of this study was to improved the durability of a improved movable weir by replacing the improved movable weir's metal gate with a hybrid steel/glass fiber reinforced polymer composites panel gate. Because the metal gate of a improved movable weir is always in contact with water, its service life is shortened by corrosion. This study made four type of hybrid steel/glass fiber reinforced polymer composites panel gate with different steel gate surface deformation (control, sand blast, scratch and hole), flexural. Fracture properties tests were performed depending on the steel gate surface deformation. According to the test results, the flexural behavior, flexural strength and fracture properties of hybrid steel/glass fiber reinforced polymer composites panel gate was affected by the steel panel gate surface deformation. Also, the sand blast type hybrid steel/glass fiber reinforced polymer composites panel gate shows vastly superior flexural and fracture performance compared to other types.

Molecular Layer Deposition of Titanium Nitride Cross-linked Benzene Using Titaniumchloride and 1,4-Phenylenediamine

  • 한규석;양다송;김세준;성명모
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.305-305
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    • 2012
  • The organic-inorganic hybrid polymer thin films were deposited using the gas phase method which known as molecular layer deposition (MLD). Titaniumchloride (TiCl4) and 1,4-phenylenediamine (PD) were used as monomers to deposit hybrid polymer. Self-terminating nature of TiCl4 and PD reaction were demonstrated by growth rate saturation versus precursors dosing time. Infrared spectroscopic and X-ray photoelectron spectroscopy were employed to determine the chemical composition and state of hybrid polymer thin films. Layer by layer growth was showed by increasing UV-VIS absorption peak of hybrid polymer thin films.

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Preparation of Unsaturated Polyester-based Hybrid Gel-Coats Containing Urethane Acrylate and Their Coating Performance

  • Kim, Ji-Hee;Baek, Seung-Suk;Kim, Oh Young;Park, Dong Hyup;Hwang, Seok-Ho
    • Elastomers and Composites
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    • 제54권3호
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    • pp.247-251
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    • 2019
  • Two different urethane acrylates (mono-acrylate and di-acrylate) were used to prepare unsaturated polyester-based hybrid gel-coats. The physical properties and surface characteristics of these gel-coats were investigated on the basis of the content and type of urethane acrylate. The set-to-touch time increased and the physical properties (surface hardness and tensile strength) decreased with an increase in the urethane acrylate content. However, the type of urethane acrylate did not affect these parameters. It was found that the optimal urethane acrylate content for the application of unsaturated polyester-based hybrid gel-coats is ~10 wt%.

Fabrication of Pre-Exfoliated Clay Masterbatch via Exfoliation-Adsorption of Polystyrene Nanobeads

  • Khvan, Svetlana;Kim, Jun-Kyung;Lee, Sang-Soo
    • Macromolecular Research
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    • 제15권1호
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    • pp.51-58
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    • 2007
  • The approach studied in the present work produced an exfoliated state of clay layers via confinement of the charged nano-sized polystyrene (PS) beads within the gallery of swollen pristine clay. It was demonstrated that adsorption of the polymer nanobeads dramatically promotes expansion of the clay gallery. A comparative study of incorporation was conducted by employing organo-modified clay along with two different colloid polymer systems: electrostatically stabilized PS nanobeads and cationic monomer-grafted PS nanobeads. The mechanism of adsorption of the monomer-grafted polymer beads onto clay via cationic exchange between the alkyl ammonium group of the polymer nanobeads and the interlayer sodium cation of the layered silicate was verified by using several techniques. As distinct from the polymer nanobeads formed using conventional miniemulsion polymerization method, competitive adsorption of stabilizing surfactant molecules was be prevented by grafting the surface functional groups into the polymer chain, thereby supporting the observed effective adsorption of the polymer beads. The presence of surface functional groups that support the establishment of strong polymer-clay interactions was suggested to improve the compatibility of the clay with the polymer matrix and eventually play a crucial role in the performance of the final nanocomposites.

입자충전 초고분자량 폴리에틸렌의 마모특성 : 입자충전 방법의 효과 (Effect of Mixing Process on the Wear Properties of UHMWPE/Kaolin Composite)

  • 기남;이건웅;윤호규;박홍조;곽순종;김준경;박민
    • 폴리머
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    • 제26권6호
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    • pp.803-811
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    • 2002
  • 본 연구에서는 상이한 방법을 통하여 제조된 초고분자량 폴리에틸렌 (ultra high molecular polyethylene, UHMWPE)/카올린 복합재료의 마모 특성에 대하여 살펴보았다. 카올린 입자는 중합충전(in-situ polymerization)법과 분말 혼합법의 두 가지 상이한 방법을 통하 UHMWPE와 복합화되었으며 특히 분말 혼합법에서는 입자상으로 구성된 두 재료의 혼합 방법에 따른 입자 분산 및 마모 특성에 대하여 분석하였다. 제조된 복합재료의 마모실험에서 입자 충전에 의하여 내마모성이 크게 향상되었는데 연삭마모가 지배적인 마모기구였으며, 중합충전법이 내마모성 향상에 있어서 분말혼합법에 비하여 효과적이었다. 또한 충전된 입자의 분산 상태와 계면 특성이 내마모성 향상에 중요한 변수임을 확인할 수 있었다.

Colloidally stable organic-inorganic hybrid nanoparticles prepared using alkoxysilane-functionalized amphiphilic polymer precursors and mechanical properties of their cured coating film

  • Kim, Nahae;Li, Xinlin;Kim, Se Hyun;Kim, Juyoung
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.209-219
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    • 2018
  • Colloidally stable organic-inorganic (O-I) hybrid nanoparticles could be prepared using an alkoxysilanefunctionalized amphiphilic polymer (AFAP) precursor. O-I hybrid sols could maintain colloidal stability for six months even at 45% solid content and be coated onto glass as well as PET film to form transparent O-I hybrid films. The formation of O-I hybrid nanoparticles dispersed in cured coating films could be confirmed using scanning electron microscopy. The cured coating film showed 3H and 5H pencil hardness on PET and glass, respectively. Nanoindentation measurements also showed that their modulus and hardness was varied with the type of AFAP used in its preparation.

Interfacial Interaction in Silica or Silsesquioxane Containing Polyimide Nanohybrids

  • Ha, Chang-Sik
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.204-204
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    • 2006
  • The interfacial interaction along with microstructure and some properties of the polyimide(PI)/silica or polyimide/silsesquioxane hybrid nanocomposites will be discussed with reviewing recent publications including our own works. Poly(vinyl silsesquioxane) (PVSSQ), aminosilane (APS), and titania can effectively play vital roles to compatibilize the PI/silica hybrid composites by enhancing interfacial interaction or reducing agglomeration of large domains, which helps the formation of nanocomposites for the PI/silica hybrid system.

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혼성복합재료의 계면 특성 분석 (Characterization of Interface in Hybrid Composites)

  • 하창식;안기열;조원재
    • 접착 및 계면
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    • 제1권1호
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    • pp.47-55
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    • 2000
  • In this article, the characterization of the interface of hybrid composites was discussed. Interfacial interaction in organic/inorganic hybrid composites, especially silica-containing hybrids can be characterized by fluorescence spectroscopy, small angle X-ray scattering (SAXS), scanning electron microscopy (SEM), atomic force microscopy (AFM), and $^{29}Si$ NMR spectroscopy measurements.

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Gate dielectric based on organic-inorganic hybrid polymer in organic thin-film transistors

  • Lee, Seong-Hui;Jeong, Sun-Ho;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.727-729
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    • 2007
  • Inorganic-organic hybrid polymer provides various advantages including low-temperature process, high dielectric constant and direct photo-patterning. The hybrid dielectric was synthesized by the sol-gel process in which an acid-catalyzed solution of Si alkoxide and Zr alkoxide was used as a precursor. The electrical performance of transistors with hybrid dielectric was investigated.

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