• Title/Summary/Keyword: Hybrid material

Search Result 1,180, Processing Time 0.03 seconds

Organic-Inorganic Hybrid Thermoelectric Material Synthesis and Properties

  • Kim, Jiwon;Lim, Jae-Hong
    • Journal of the Korean Ceramic Society
    • /
    • v.54 no.4
    • /
    • pp.272-277
    • /
    • 2017
  • Organic-inorganic hybrid thermoelectric materials have obtained increasing attention because it opens the possibility of enhancing thermoelectric performance by utilizing the low thermal conductivity of organic thermoelectric materials and the high Seebeck coefficient of inorganic thermoelectric materials. Moreover, the organic-inorganic hybrid thermoelectric materials possess numerous advantages, including functional aspects such as flexibility or transparency, low cost raw materials, and simplified fabrication processes, thus, allowing for a wide range of potential applications. In this study, the types and synthesis methods of organic-inorganic thermoelectric hybrid materials were discussed along with the methods used to enhance their thermoelectric properties. As a key factor to maximize the thermoelectric performances of hybrid thermoelectric materials, the nanoengineering to control the nanostructure of the inorganic materials as well as the modification of the organic material structure and doping level are considered, respectively. Meanwhile, the interface between the inorganic and organic phase is also important to develop the hybrid thermoelectric module with excellent reliability and high thermoelectric efficiency in addition to its performance in various electronic devices.

Electrochemical Behavior Depending on Designed-Anode and Cathodes of Hybrid Supercapacitors (하이브리드 슈퍼커패시터의 음극 및 양극 설계에 따른 전기화학적 거동)

  • Shin, Seung-Il;Lee, Byung-Gwan;Ha, Min-Woo;An, Geon-Hyoung
    • Korean Journal of Materials Research
    • /
    • v.29 no.12
    • /
    • pp.774-780
    • /
    • 2019
  • The performance of Li-ion hybrid supercapacitors (asymmetric-type) depends on many factors such as the capacity ratio, material properties, cell designs and operating conditions. Among these, in consideration of balanced electrochemical reactions, the capacity ratio of the negative (anode) to positive (cathode) electrode is one of the most important factors to design the Li-ion hybrid supercapacitors for high energy storing performance. We assemble Li-ion hybrid supercapacitors using activated carbon (AC) as anode material, lithium manganese oxide as cathode material, and organic electrolyte (1 mol L-1 LiPF6 in acetonitrile). At this point, the thickness of the anode electrode is controlled at 160, 200, and 240 ㎛. Also, thickness of cathode electrode is fixed at 60 ㎛. Then, the effect of negative and positive electrode ratio on the electrochemical performance of AC/LiMn2O4 Li-ion hybrid supercapacitors is investigated, especially in the terms of capacity and cyclability at high current density. In this study, we demonstrate the relationship of capacity ratio between anode and cathode electrode, and the excellent electrochemical performance of AC/LiMn2O4 Li-ion hybrid supercapacitors. The remarkable capability of these materials proves that manipulation of the capacity ratio is a promising technology for high-performance Li-ion hybrid supercapacitors.

Efficacy of supplementary cementitious material and hybrid fiber to develop the ultra high performance hybrid fiber reinforced concrete

  • Sharma, Raju;Bansal, Prem Pal
    • Advances in concrete construction
    • /
    • v.8 no.1
    • /
    • pp.21-31
    • /
    • 2019
  • The rich recipe of ultra high performance concrete (UHPC) offers the higher mechanical, durability and dense microstructure property. The variable like cement/sand ratio, amount of supplementary cementitious material, water/binder ratio, amount of fiber etc. alters the UHPC hardened properties to any extent. Therefore, to understand the effects of these variables on the performance of UHPC, inevitably a stage-wise development is required. In the present experimental study, the effect of sand/cement ratio, the addition of finer material (fly ash and quartz powder) and, hybrid fiber on the fresh, compressive and microstructural property of UHPC is evaluated. The experiment is conducted in three phases; the first phase evaluates the flow value and strength attainment of ingredients, the second phase evaluates the efficiency of finer materials (fly ash and quartz powder) to develop the UHPC and the third phase evaluate the effect of hybrid fiber on the flow value and strength of ultra high performance hybrid fiber reinforced concrete (UHP-HFRC). It has been seen that the addition of fly ash improves the flow value and compressive strength of UHPC as compared to quartz powder. Further, the usage of hybrid fiber in fly ash contained matrix decreases the flow value and improves the strength of the UHP-HFRC matrix. The dense interface between matrix and fiber and, a higher amount of calcium silicate hydrate (CSH) in fly ash contained UHP-HFRC is revealed by SEM and XRD respectively. The dense interface (bond between the fiber and the UHPC matrix) and the higher CSH formation are the reason for the improvement in the compressive strength of fly ash based UHP-HFRC. The differential thermal analysis (DTA/TGA) shows the similar type of mass loss pattern, however, the amount of mass loss differs in fly ash and quartz powder contained UHP-HFRC.

CSG-based Representation for Free-form Heterogeneous Object Modeling (임의 형상의 복합재 모델링을 위한 CSG 기반 표현)

  • Shin, K.H.;Lee, J.K.
    • Korean Journal of Computational Design and Engineering
    • /
    • v.11 no.4
    • /
    • pp.235-245
    • /
    • 2006
  • This paper proposes a CSG-based representation scheme for heterogeneous objects including multi-material objects and Functionally Graded Materials (FGMs). In particular, this scheme focuses on the construction of complicated heterogeneous objects guaranteeing desired material continuities at all the interfaces. In order to create various types of heterogeneous primitives, we first describe methods for specifying material composition functions such as geometry-independent, geometry-dependent functions. Constructive Material Composition (CMC) and corresponding heterogeneous Boolean Operators (e.g. material union, difference, intersection. and partition) are then proposed to illustrate how material continuities are dealt with. Finally, we describe the model hierarchy and data structure for computer representation. Even though the proposed scheme alone is sufficient for modeling all sorts of heterogeneous objects, the proposed scheme adopts a hybrid representation between CSG and decomposition. That is because hybrid representation can avoid the unnecessary growth of binary trees.

Electrochemical Characteristics of Hybrid Capacitor and Pulse Performance of Hybrid Capacitor / Li-ion Battery (Hybrid Capacitor의 전기화학적 특성 및 Hybrid Capacitor / Li-ion Battery의 펄스 방전 특성)

  • Lee, Sun-Young;Kim, Ick-Jun;Moon, Seong-In;Kim, Hyun-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.18 no.12
    • /
    • pp.1133-1138
    • /
    • 2005
  • In this study, we have prepared, as the pluse power source, a commercially supplied Li-ion battery with a capacity of 700 mAh and AC resistivity of 60 md at 1 kHz and nonaqeous asymmetric hybrid capacitor composed of an activated carbon cathode and MCMB anode, and have examined the electrochemical characteristics of hybrid capacitor and the pulse performances of parallel connected hybrid capacitor/Li-ion battery source. The nonaqueous asymmetric hybrid capacitors constituted with each stack number of pairs composed of the cathode, the porous separator and the anode electrode were housed in Al-laminated film cell. The 10 stacked hybrid capacitor, which was charged and discharged at a constant current at 0.25 $mA/cm^2$ between 3 and 4.3 V, has exhibited the capacitance of 108F and the lowest equivalent series resistance was 32 $m{\Omega}$ at 1 kHz. On the other hand, the enhanced run time of Li-ion battery assisted by the hybrid capacitor was obtained with increasing of current density and pulse width in Pulse mode. The best improvement, $84\;\%$ for hybrid capacitor/Li-ion battery was obtained in the condition of a 7C-rate pulse (100 msec)/0.5C-rate standby/$10\;\%$ duty cycle.

Electrochemical Characteristics of Carbon/Carbon Hybrid Capacitor and Li-ion Battery/Hybrid Capacitor Combination (Carbon계 Hybrid Capacitor의 전기 화학적 기술 및 Li-ion Battery의 혼성 동력원 특성)

  • Lee, Sun-Young;Kim, Ick-Jun;Moon, Seong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.597-598
    • /
    • 2005
  • Recently, the performance of portable electric equipment can often improved by a Li-ion battery assisted by a supercapacitor. A supercapacitor can provide high power density as well as a low resistance in the hybrid system. In this study, we have prepared, as the pluse power souce, a commercially supplied Li-ion battery with a capacity of 700mAh and AC resistivity of $60m\Omega$ at 1kHz and nonaqeous asymmetric hybrid capacitor composed of an activated carbon cathode and MCMB anode, and have examined the electrochemical characteristics of hybrid capacitor and the pulse performances of parallel connected battery/hybrid capacitor source. The nonaqueous asymmetric hybrid capacitor, the stacks of 10 pairs of the cathode, the porous separator and the anode electrode were housed in Al-laminated film cell. The hybrid capacitor, which was charged and discharged at a constant current at $0.25mA/cm^2$ between 3 and 4.3V, has exhibited the capacitance of 100F. And the equivalent series resistance was $32m\Omega$ at 1kHz. By combining a Li-ion battery and a hybrid capacitor, the pulse performance of battery can be improved 23% in run time under a pulse discharge of 7C-rate.

  • PDF

Electromagnetothermoelastic behavior of a rotating imperfect hybrid functionally graded hollow cylinder

  • Saadatfar, M.;Aghaie-Khafri, M.
    • Smart Structures and Systems
    • /
    • v.15 no.6
    • /
    • pp.1411-1437
    • /
    • 2015
  • The electro-magneto- thermo-elastic behavior of a rotating functionally graded long hollow cylinder with functionally graded piezoelectric (FGPM) layers is analytically analyzed. The layers are imperfectly bonded to its inner and outer surfaces. The hybrid cylinder is placed in a constant magnetic field subjected to a thermo-electro-mechanical loading and could be rested on a Winkler-type elastic foundation. The material properties of the FGM cylinder and radially polarized FGPM layers are assumed to be graded in the radial direction according to the power law. The hybrid cylinder is rotating about its axis at a constant angular velocity. The governing equations are solved analytically and then stresses, displacement and electric potential distribution are calculated. Numerical examples are given to illustrate the effects of material in-homogeneity, magnetic field, elastic foundation, applied voltage, imperfect interface and thermo-mechanical boundary condition on the static behavior of a FG smart cylinder.

A Method to Estimate the Weight-reduction of Hybrid Bodyshells by Material Substitution (소재대체에 의한 하이브리드형 차체구조의 경량화 예측 방법)

  • Cho, Hyun-Jik;Koo, Jeong-Seo
    • Journal of the Korean Society for Railway
    • /
    • v.9 no.6 s.37
    • /
    • pp.635-643
    • /
    • 2006
  • In this paper, a theorectical approach is studied to predict structural performances and weight-reduction rates of hybrid bodyshells in case that the materials of roof structures are substituted. To determine other light-weight materials to be substituted for the original roof materials, bending and twisting deformations are considered under constant stiffness and strength conditions, which derive some new weight-reduction indices from a structural performance point of view. The indices derived to estimate the weight-reduction can be utilized as a good criterion at the conceptual design for material substitution of the roofs.

The Determination of Elastic Constant for Ceramic Forming Material by Hybrid Method (하이브리드 방법에 의한 세라믹 성형재료의 탄성계수 결정)

  • Park Myong Kyun;Koo Bon Sung
    • Journal of the Korea Safety Management & Science
    • /
    • v.7 no.1
    • /
    • pp.211-222
    • /
    • 2005
  • The ceramic forming materials are getting more important recently since they are used widely in repairing metal structures, welded metal structures and mechanical components etc. The determination of elastic constants for ceramic coating materials takes much time and efforts in experiment due to the brittleness of ceramic material itself. The aim of this research is to determine the Young's Modulus for ceramic metal coating material. In order to achieve the goal, the hybrid method which uses impulse hammer technique for experimental method and modal analysis of finite element method for computational method was used. The results show good agreement with existing experimental data on Young's Modulus.

Effects of Solution Treatment Temperatures on Microstructure and Mechanical Properties of TIG-MIG Hybrid Arc Additive Manufactured 5356 Aluminum Alloy

  • Zuo, Wei;Ma, Le;Lu, Yu;Li, Shu-yong;Ji, Zhiqiang;Ding, Min
    • Metals and materials international
    • /
    • v.24 no.6
    • /
    • pp.1346-1358
    • /
    • 2018
  • A novel additive manufacturing method with TIG-MIG hybrid heat source was applied for fabricating 5356 aluminum alloy component. In this paper the microstructure evolution, mechanical properties and fracture morphologies of both as-deposited and heat-treated component were investigated, and how these were affected by different heat-treated temperature. The as-deposited microstructure showed dominant equiaxed grains with second phase, and the size of them is coarse in the bottom region, medium in the middle region and fine in the top region owing to different thermal cycling conditions. Compared with as-deposited microstructure, the size of grain becomes large and second phases gradually dissolve in the matrix as heat-treated temperature increase. Different microstructures determine the mechanical properties of component. Results show that average ultimate tensile strength enhances from 226 to 270 MPa and average microhardness increases from 64.2 to 75.3 HV0.1 but ductility decreases from 33 to 6.5% with heat-treated temperature increasing. For all components, the tensile properties are almost the same in the vertical direction (Z) and horizontal direction (Y) due to equiaxed grains, which exhibits isotropy, and the mechanisms of these are analyzed in detailed. In general, the results demonstrate that hybrid arc heat source has the potential to fabricate aluminum alloy component.