• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.4079-4083
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• 2012

The mechanism of the cycloaddition reaction between singlet state dichlorosilylene germylidene ($Cl_2Si=Ge:$) and acetone has been investigated with B3LYP/6-$31G^*$ and B3LYP/6-$31G^{**}$ method, from the potential energy profile, we predict that the reaction has one dominant reaction pathway. The presented rule of the reaction is that the two reactants firstly form a Si-heterocyclic four-membered ring germylene through the [2+2] cycloaddition reaction. Because of the 4p unoccupied orbital of Ge atom in the Si-heterocyclic four-membered ring germylene and the ${\pi}$ orbital of acetone forming a ${\pi}{\rightarrow}p$ donor-acceptor bond, the Si-heterocyclic four-membered ring germylene further combines with acetone to form an intermediate. Because the Ge atom in the intermediate hybridizes to an $sp^3$ hybrid orbital after the transition state, then, the intermediate isomerizes to spiro-heterocyclic ring compound involving Si and Ge (P4) via a transition state.

• Bulletin of the Korean Chemical Society
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• v.28 no.6
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• pp.1031-1034
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• 2007

The R- and Z-substituent effects for the gas-phase thermal decompositions of carbamates, R2NC(=O)- OCH2CH2Z, have been investigated theoretically at B3LYP level with 6-31G(d) and 6-31++G(d,p) basis sets. Both the Z- and R-substituent effects on reactivity (ΔH≠) were well consistent with experimental results, although the R-substituent effect was underestimated theoretically. No correlations were found between activation enthalpies and reaction enthalpies. The substituent effects on reactivity seemed to be complicated at a glance, but were understandable by concurrent electronic and steric factors. Variations of bond lengths at TS structures were well correlated with the Taft's σ* values and the TS structures became tighter as the Zsubstituent became a stronger electron-acceptor (δσ* > 0). However the effects of R-substituents on the TS structures were much smaller when compared to those of Z-substituents.

• Membrane and Water Treatment
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• v.3 no.2
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• pp.113-121
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• 2012

Up-flow multi-layer bioreactor (UMBR) is a hybrid system using dual sludge that consists of an up-flow multi-layer bioreactor as anaerobic/anoxic suspended growth microorganisms followed by an aeration tank. The UMBR acts as a primary settling tank, anaerobic/anoxic reactor, thickener which requires low energy due to mixing by up-flow stream. This study focused on using a pilot UMBR plant with capacity of 20-30 $m^3$/day for domestic wastewater in HCMC. HRTs of UMBR and aeration tank were 4.8 h and 7.2 h, respectively. The average MLSS of UMBR ranged from 10,000-13,600 mg/l SS. Internal recycle rate and sludge return were 200-300% and 150-200%, respectively. The results obtained from this study at flow rate of 20 $m^3$/day showed that removal of COD, SS, TKN, N-$NH_4$, T-N, and color were 91%, 87%, 86%, 80%, 91% and 91%, respectively.

• Polymer(Korea)
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• v.37 no.1
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• pp.41-46
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• 2013

The glass transition temperature ($T_g$) and conversion (${\alpha}$) were measured for a diglycidyl ether of bisphenol A (DGEBA) epoxy/aromatic amine system incorporated with an organic-inorganic hybrid molecule, polyhedral oligomeric silsesquioxane (POSS). Samples isothermally cured at varying cure temperatures and times were analyzed by differential scanning calorimetry (DSC). $T_g$ vs. ln (time) data at an arbitrary reference were superposed by time-temperature shifts for the kinetically controlled reaction, and the shift factors were used to calculate an Arrhenius activation energy. Influence of POSS was investigated from $T_g$ vs. ${\alpha}$ data, which in turn were fitted with DiBenedetto equation.

• Journal of the Optical Society of Korea
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• v.16 no.3
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• pp.247-255
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• 2012

Daylighting has a very effective role in reducing power consumption and improving indoor environments in office buildings. Previously, it was not under consideration as a major source of renewable energy due to poor reliability in the design. Optical fiber as a transmission medium in the daylighting system demands uniform distribution of light to solve cost, heat, and efficiency issues. Therefore, this study focuses on the uniform distribution of sunlight through the fiber bundle and to the interior of the building. To this end, two efficient approaches for the fiber-based daylighting system are presented. The first approach consists of a parabolic mirror, and the second approach contains a Fresnel lens. Sunlight is captured, guided, and distributed through the concentrator, optical fibers, and lenses, respectively. At the capturing stage, uniform illumination solves the heat problem, which has critical importance in making the system cost-effective by introducing plastic optical fibers. The efficiency of the system is increased by collimated light, which helps to insert maximum light into the optical fibers. Furthermore, we find that the hybrid system of combining sunlight and light emitting diode light gives better illumination levels than that of traditional lighting systems. Simulation and experimental results have shown that the efficiency of the system is better than previous fiber-based daylighting systems.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.2
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• pp.139-146
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• 2011

The ventilation performance of a vertical exhaust duct system in the high riser public house has been evaluated by a commercial software, Fluid Flow, which solves pressure losses through the duct system including bathroom fans and a hybrid roof fan. During the numerical simulations, outdoor wind condition and stack effects in summer and winter were considered as well as the operating conditions of a basement damper and the roof fan. The results show that the bathroom ventilation in summer is the most unsatisfactory. The opening of the basement damper has a problem that the polluted air in the lower floors is exhausted to the underground parking lot, not to the rooftop. If the basement damper is closed, the exhaust flow rate in the lower floors is not sufficient due to the strong flow resistance in the long vertical duct even though the roof fan is under operating.

• Applied Science and Convergence Technology
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• v.23 no.2
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• pp.72-82
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• 2014

Lithium-ion batteries (LIBs) have become popular electrochemical devices. Due to the unique advantages of LIBs in terms of high operating voltage, high energy density, low self-discharge, and absence of memory effects, their application range, which was primarily restricted to portable electronic devices, is now being extended to high-power applications, such as electric vehicles (EVs) and hybrid electrical vehicles (HEVs). Among various anode materials, $Li_4Ti_5O_{12}$ (LTO) is believed to be a promising anode material for high-power LIBs due to its advantages of high working potential and outstanding cyclic stability. However, the rate performance of LTO is limited by its intrinsically low electronic conductivity and poor $Li^+$ ion diffusion coefficient. This review highlights the recent progress in improving the rate performance of LTO through doping, compositing, and nanostructuring strategies.

• Journal of Communications and Networks
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• v.17 no.2
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• pp.133-144
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• 2015

In this paper, we introduce a system and a set of algorithms for disseminating popular content to a large group of wireless clients spread over a wide area. This area is partitioned into multiple cells and there is a base station in each cell which is able to broadcast to the clients within its radio coverage. Dissemination of information in the proposed system is hybrid in nature: Each base station broadcasts a fraction of information in the form of random linear combinations of data blocks. Then the clients cooperate by exchanging packets to obtain their desired messages while they are moving arbitrarily over the area. In this paper, fundamental trade-offs between the average information delivery completion time at the clients and different parameters of the system such as bandwidth usage by the base stations, average energy consumption by the clients and the popularity of the spread information are studied. Moreover different heuristic algorithms are proposed to control and maintain a balance over these trade-offs. Also, the more complicated case of multiple sessions where each client is interested in an arbitrary subset of sessions is considered and two variants of the basic dissemination algorithm are proposed. The performance of all the proposed algorithms is evaluated via extensive numerical experiments.

• Proceedings of the KIEE Conference
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• 2009.04b
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• pp.6-8
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• 2009

This paper presents the novel implementation of memetic algorithm with GA (Genetic Algorithm) and MADS (Mesh Adaptive Direct Search), which is applied for optimal design methodology of electric machine. This hybrid algorithm has been developed for obtaining the global optimum rapidly, which is effective for optimal design of electric machine with many local optima and much longer computation time. In particular, the proposed memetic algorithm has been forwarded to optimal design of direct-driven PM wind generator for maximizing the Annual Energy Production (AEP), of which design objective should be obtained by FEA (Finite Element Analysis). After all, it is shown that GA combined with MADS has contributed to reducing the computation time effectively for optimal design of PM wind generator when compared with purposely developed GA implemented with the parallel computing method.

• Journal of Electrical Engineering and Technology
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• v.9 no.2
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• pp.523-531
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• 2014

Brushless Dual-Mechanical-Port Electrical Machine (BLDMPEM) is a new type of motor designed for Hybrid Electric Vehicle (HEV), which contains two mechanical ports and two electric ports. Compared with Dual-Mechanical-Port Electrical Machine (DMPEM), the brushless structure brings higher reliability and easier maintenance. In this paper, the model of BLDMPEM is discussed. In Chapter 2, the energy flow and mathematical model of BLDMPEM are analyzed. Then a novel three-phase half-bridge controlled rectifier topology and its control strategy for cruising mode of HEV based on BLDMPEM are proposed in Chapter 3. Compared with the Field Oriented Control (FOC) strategy of BLDMPEM, the proposed method does not require accurate motor parameters, and it is much simpler and easier to be implemented. At last, simulation and experiment results show the feasibility and validity of the proposed strategy.