• 제목/요약/키워드: Hybrid ceramic

검색결과 263건 처리시간 0.035초

마이크로파 혼합 가열에 의한 $Al-Al_2O_3$ 분말성형체의 산화와 소결 (The Oxidation and Sintering of $Al-Al_2O_3$ Powder Mixture by using Microwave (Hybrid) Heating)

  • 박정현;안주삼
    • 한국세라믹학회지
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    • 제32권3호
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    • pp.331-340
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    • 1995
  • Microwave (Hybrid) Heating (MHH) was used to oxidize and sinter Al-Al2O3 powder mixture. For 25 v/o Al specimen and 35 v/o Al specimen, the total processing to produce low-shrinkage reaction bonded alumina was carried out within 1 hour even though conventional furnace process took more than 10 hours. Compared with conventional fast firing process, MHH process increased more than 40% oxidation at the same temperature, and these high oxidation rates were thought to be caused by the surface ohmic current on Al particles.

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Diarylethene이 첨가된 저융점 유-무기 하이브리드 유리의 광변색 특성 (Photochromism of Diarylethene-Doped Organic-Inorganic Hybrid Low Melting Glass)

  • 김지경;김명정;박성제;류봉기
    • 한국세라믹학회지
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    • 제43권1호
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    • pp.28-32
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    • 2006
  • Diarylethene in photochromic materials was doped in organic-inorganic hybrid low-melting glasses were synthesized through a nonaqueous acid-base reaction process, which consists of network units including a small number of bridging oxides. The organic phase is a dichlorodimethylsilane while the inorganic phase is a tin(II) chloride. Diarylethene was incorporated into the glasses without any degradation of its functionality. The open form of diarylenthene, which is converted from the opening one upon UV-irradiation, is change to the closed form visible light-irradiation. The rate constant of the photochemical reaction is $31.78\times10^{-3}s^{-1}$ with 400 W UV lamp irradiation.

Application of ANN modeling for oily wastewater treatment by hybrid PAC-MF process

  • Abbasi, Mohsen;Rasouli, Yaser;Jowkar, Peyman
    • Membrane and Water Treatment
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    • 제9권4호
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    • pp.285-292
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    • 2018
  • In the following study, Artificial Neural Network (ANN) is used for prediction of permeate flux decline during oily wastewater treatment by hybrid powdered activated carbon-microfiltration (PAC-MF) process using mullite and mullite-alumina ceramic membranes. Permeate flux is predicted as a function of time and PAC concentration. To optimize the networks performance, different transfer functions and different initial weights and biases have been tested. Totally, more than 850,000 different networks are tested for both membranes. The results showed that 10:6 and 9:20 neural networks work best for mullite and mullite-alumina ceramic membranes in PAC-MF process, respectively. These networks provide low mean squared error and high linearity between target and predicted data (high $R^2$ value). Finally, the results present that ANN provide best results ($R^2$ value equal to 0.99999) for prediction of permeation flux decline during oily wastewater treatment in PAC-MF process by ceramic membranes.

Carbonation of Circulating Fluidized Bed Combustion Fly Ash with Hybrid Reaction

  • Lee, Ki Gang;Bae, Soon Jong
    • 한국세라믹학회지
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    • 제55권2호
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    • pp.160-165
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    • 2018
  • This paper investigates the reaction rate of $CO_2$ storing carbonation hybrid reaction by comparing the behavior of carbonation between $Ca(OH)_2$ and fly ash with that of CFBC (Circulating Fluidized Bed Combustion) containing plenty of Free-CaO. Because fly ash with CFBC contains a lot of unreacted CaO, it cannot be used as a raw material for concrete admixtures and its usages are limited. To reuse such material, we stabilized unreacted CaO by carbonation and investigated the carbonation rate. We used a pH meter and a thermometer to check the rate of the carbonization. Also, we set the contents of fly ash with CFBC, $Ca(OH)_2$, flow and fluid of $CO_2$, respectively, to 100 g, 50 g, 100 ~ 1000 cc/min and 400 g based on the content of Free-CaO. We used carbonated water instead of water, and added an alkaline activator to promote the carbonation rate. As a result, the addition of the alkaline activator and carbonated water promoted the rate of carbonation via a hybrid reaction.

$Al_2O_3/SiC$ Hybrid-Composite에서 SiC에 질화물 코팅의 영향 (The Effect of Nitride Coating on SiC Platelet in $Al_2O_3/SiC$ Hybrid-Composite)

  • 이수영;임경호;전병세
    • 한국세라믹학회지
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    • 제34권4호
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    • pp.406-412
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    • 1997
  • Al2O3/SiC hybrid-composite has been fabricated by the conventional powder process. The addition of $\alpha$-Al2O3 as seed particles in the transformation of ${\gamma}$-Al2O3 to $\alpha$-Al2O3 provided a homogeneity of the microstructure. The grain growth of Al2O3 are significantly surpressed by the addition of nano-size SiC particles. Dislocation were produced due to the difference of thermal expansion coefficient between Al2O3 and SiC and piled up on SiC particles in Al2O3 matrix, resulting in transgranular fracture. The high fracture strength of the composite was contributed to the grain refinement and the transgranular fracture mode. The addition of SiC platelets to Al2O3/SiC nano-composite decreased the fracture strength, but increased the fracture toughness. Coated SiC platelets with nitrides such as BN and Si3N4 enhanced fracture toughness much more than non-coated SiC platelets by enhancing crack deflection.

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Wastewater treatment using a hybrid process coupling adsorption on marl and microfiltration

  • Maimoun, Bakhta;Djafer, Abderrahmane;Djafer, Lahcene;Marin-Ayral, Rose-Marie;Ayral, Andre
    • Membrane and Water Treatment
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    • 제11권4호
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    • pp.275-282
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    • 2020
  • Hranfa's marl, a local natural mineral, is selected for the decontamination by adsorption of aqueous effluents in textile industry. Its physicochemical characterization is first performed. It is composed mainly of Calcite, Quartz, Ankerite and Muscovite. Its specific surface area is 40 ㎡ g-1. Its adsorption performance is then tested in batch conditions using an industrial organic dye, Bemacid Red E-TL, as a model pollutant. The measured adsorption capacity of Hranfa's marl is 16 mg g-1 which is comparable to that of other types of natural adsorbents. A hybrid process is tested coupling adsorption of the dye on marl in suspension and microfiltration. An adsorption reactor is inserted into the circulation loop of a microfiltration pilot using ceramic membranes. This makes possible a continuous extraction of the treated water provided that a periodic replacement of the saturated adsorbent is done. The breakthrough curve obtained by analyzing the dye concentration in the permeate is close to the ideal one considering that no dye will cross the membrane as long as the adsorbent load is not saturated. These first experimental data provide proof of concept for such a hybrid process.

마이크로파 가열을 이용한 Ni-Zn 페라이트의 소결 (Sintering of Ni-Zn Ferrites by Microwave Hybrid Heating)

  • 김진웅;최승철;이재춘;오재희
    • 한국세라믹학회지
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    • 제39권7호
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    • pp.669-674
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    • 2002
  • 마이크로파(2.45GHz, 700w) 에너지를 이용한 마이크로웨이브 하이브리드 소결법으로 90$0^{\circ}C$~107$0^{\circ}C$의 온도 범위에서 Bi$_2$O$_3$와 CuO가 함유된 Ni-Zn 페라이트를 소결하고 이 결과를 일반 소결법으로 소결된 시편과 비교하였다. 각 소결체의 공정 시간은 20~$25^{\circ}C$/min의 승온속도에서 60분 이내에 마칠 수 있었다. XRD분석결과 Ni-Zn페라이트의 단일상만이 관찰되었으며 일반 소결보다 빠른 시간에 소결이 진행되었다. 97$0^{\circ}C$에서 15분 소결 했을 때 소결밀도는 98%로 최대값을 나타내었으며, 모든 소결체의 소결밀도는 90% 이상의 소결 밀도를 나타내었다. 마이크로 하이브리드 소결법으로 소결된 시편과 일반 소결법으로 소결된 시편을 비교하면 소결 특성은 비슷한 결과를 얻을 수 있었다. 마이크로파 에너지를 이용한 소결법은 일반 소결법에 비하여 짧은 시간 안에 공정을 완료할 수 있으므로 공정 시간과 에너지 절약 측면에서 유효한 공정으로 판단된다.

Effects of Heterostructure Electrodes on the Reliability of Ferroelectric PZT Thin Films

  • Kim, Seung-Hyun;Woo, Hyun-Jung;Koo, Chang-Young;Yang, Jeong-Seung;Ha, Su-Min;Park, Dong-Yeon;Lee, Dong-Su;Ha, Jo-Woong
    • 한국세라믹학회지
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    • 제39권4호
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    • pp.341-345
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    • 2002
  • The effect of the Pt electrode and the $Pt-IrO_2$ hybrid electrode on the performance of ferroelectric device was investigated. The modified Pt thin films with non-columnar structure significantly reduced the oxidation of TiN diffusion barrier layer, which rendered it possible to incorporate the simple stacked structure of Pt/TiN/poly-Si plug. When a $Pt-IrO_2$ hybrid electrode is applied, PZT thin film properties are influenced by the thickness and the partial coverage of the electrode layers. The optimized $Pt-IrO_2$ hybrid electrode significantly enhanced the fatigue properties with minimal leakage current.