• Title/Summary/Keyword: Homogenization Method

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Highly Homogeneous Carbon Nanotube-Polycaprolactone Composites with Various and Controllable Concentrations of Ionically-Modified-MWCNTs

  • Lee, Hae-Hyoung;Shin, Ueon-Sang;Jin, Guang-Zhen;Kim, Hae-Won
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.157-161
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    • 2011
  • For the fabrication of multifunctional biopolymer nanocomposites in the combination of carbon nanotubes (CNTs), recently increasing attention has been paid to an effective homogenization of CNTs within polymer matrices and a fine tuning of the concentration. We developed an efficient method to produce homogeneous CNT-polycaprolactone nanocomposites with various and controllable CNT concentrations using an ionically-modified multi-walled CNT, MWCNT-Cl. The modified MWCNTs could be homogeneously dispersed in tetrahydrofuran (THF). Polycaprolactone (PCL) as a biodegradable and biocompatible polymer was smoothly dissolved in the homogeneous MWCNT-Cl/THF solution without agglomeration of MWCNT-Cl. The physicochemical and mechanical properties of the resultant nanocomposites were examined and the biological usefulness was briefly assessed.

Axisymmetric Temperature Analysis of Ventilated Disk using Equivalent Parameters (등가상수를 이용한 벤트레이트 디스크의 축대칭 온도 해석)

  • 여태인
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.1
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    • pp.137-142
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    • 2003
  • In automotive brake systems, the frictional heat generated can cause high temperature at the interface of rotor and pad which may deteriorate the material properties of the sliding parts and can result in brake fade. Conventionally, a pie-shaped 3-dimentional model is adopted to calculate temperature of ventilated disk using finite element method. To overcome the difficulties in preparing 3D finite element model and reduce the computational time required, the ventilated rotor is to be analyzed, in this study, as an axisymmetric finite element model in which, taking into considerations the effects of cooling passages, a homogenization technique is used to obtain the equivalent thermal properties and boundary conditions for the elements placed at the vent holes. Numerical tests show the proposed procedure can be successfully applied in practice, replacing 3-dimensional thermal analysis of ventilated disk.

Redox Reaction of Multivalent Ions in Glass Melts

  • Kim, Kidong
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.83-91
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    • 2015
  • The redox reaction $M^{(x+n)+}+\frac{n}{2}O^{-2}{\rightleftarrows}M^{x+}+\frac{n}{4}O_2$ of multivalent ions in glass melts influences the melting process and final properties of the glass including the fining (removal of bubbles), infrared absorption and homogenization of melts, reaction between metal electrodes and melts or refractory and melts, and transmission and color of glass. In this review paper, the redox behaviors that occur frequently in the glass production process are introduced and the square wave voltammetry (SWV) is described in detail as an in situ method of examining the redox behavior of multivalent ions in the melt state. Finally, some voltammetry results for LCD glass melts are reviewed from the practical viewpoint of SWV.

Wave dispersion characteristics of porous graphene platelet-reinforced composite shells

  • Ebrahimi, Farzad;Seyfi, Ali;Dabbagh, Ali;Tornabene, Francesco
    • Structural Engineering and Mechanics
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    • v.71 no.1
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    • pp.99-107
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    • 2019
  • Wave propagation analysis of a porous graphene platelet reinforced (GPLR) nanocomposite shell is investigated for the first time. The homogenization of the utilized material is procured by extending the Halpin-Tsai relations for the porous nanocomposite. Both symmetric and asymmetric porosity distributions are regarded in this analysis. The equations of the shell's motion are derived according to Hamilton's principle coupled with the kinematic relations of the first-order shear deformation theory of the shells. The obtained governing equations are considered to be solved via an analytical solution which includes two longitudinal and circumferential wave numbers. The accuracy of the presented formulations is examined by comparing the results of this method with those reported by former authors. The simulations reveal a stiffness decrease in the cases which porosity influences are regarded. Also, one must pay attention to the effects of longitudinal wave number on the wave dispersion curves of the nanocomposite structure.

Comparison between analytic and numerical approaches to calculate screening current induced field in HTS magnet

  • Bang, Jeseok;Kim, Seokho;Kim, Jaemin;An, Soobin;Im, Chaemin;Hahn, Seungyong
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.45-49
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    • 2019
  • This paper reports comparison between analytic and numerical simulation approaches for calculation of screening current and screening current induced field in a high temperature superconductor magnet. Bean slab model is adopted to calculate screening current and SCF analytically, while the finite element method numerically. A case study of screening current and SCF calculation are conducted with a magnet, a 7 T 68 mm cold-bore multi-width no-insulation GdBCO magnet built and tested by Massachusetts Institute of Technology Francis Bitter Magnet Laboratory. In this study, we assume the magnet is dunked in liquid nitrogen at 77 K. Furthermore, the simulation results are compared in terms of computation time and accuracy. Finally, discussion on the different methods together with the comparison between the calculations and experiment is provided.

Prediction of Anisotropy and Formability of Lithium-ion Battery Pouch Sheet using Non-quadratic Yield Function (비이차 비등방 항복함수를 이용한 리튬-이온 배터리 파우치의 이방성 및 성형성 예측)

  • J. S. Kim;C. M. Moon;H.R. Lee;M. G. Lee
    • Transactions of Materials Processing
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    • v.32 no.3
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    • pp.136-144
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    • 2023
  • This study analyzed the mechanical behavior of lithium-ion battery pouch material and predicted its formability. A homogenization method was used to evaluate the physical properties of the pouch, and a new hardening model was developed. The yield function for the plastic model was optimized, and the anisotropic property was determined. Also, the forming limits were measured and predicted using the M-K forming limit diagram. Finally, a square cup drawing experiment confirmed the accuracy of the measured mechanical properties and the formability calculation.

Hierarchical multiscale modeling for predicting the physicochemical characteristics of construction materials: A review

  • Jin-Ho Bae;Taegeon Kil;Giljae Cho;Jeong Gook Jang;Beomjoo Yang
    • Computers and Concrete
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    • v.33 no.3
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    • pp.325-340
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    • 2024
  • The growing demands for sustainable and high-performance construction materials necessitate a deep understanding of their physicochemical properties by that of these heterogeneities. This paper presents a comprehensive review of the state-of-the-art hierarchical multiscale modeling approach aimed at predicting the intricate physicochemical characteristics of construction materials. Emphasizing the heterogeneity inherent in these materials, the review briefly introduces single-scale analyses, including the ab initio method, molecular dynamics, and micromechanics, through a scale-bridging technique. Herein, the limitations of these models are also overviewed by that of effectively scale-bridging methods of length or time scales. The hierarchical multiscale model demonstrates these physicochemical properties considering chemical reactions, material defects from nano to macro scale, microscopic properties, and their influence on macroscopic events. Thereby, hierarchical multiscale modeling can facilitate the efficient design and development of next-generation construction.

Improvement of Reverse-time Migration using Homogenization of Acoustic Impedance (음향 임피던스 균질화를 이용한 거꿀시간 참반사보정 성능개선)

  • Lee, Gang Hoon;Pyun, Sukjoon;Park, Yunhui;Cheong, Snons
    • Geophysics and Geophysical Exploration
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    • v.19 no.2
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    • pp.76-83
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    • 2016
  • Migration image can be distorted due to reflected waves in the source and receiver wavefields when discontinuities of input velocity model exist in seismic imaging. To remove reflected waves coming from layer interfaces, it is a common practice to smooth the velocity model for migration. If the velocity model is smoothed, however, the subsurface image can be distorted because the velocity changes around interfaces. In this paper, we attempt to minimize the distortion by reducing reflection energy in the source and receiver wavefields through acoustic impedance homogenization. To make acoustic impedance constant, we define fake density model and use it for migration. When the acoustic impedance is constant over all layers, the reflection coefficient at normal incidence becomes zero and the minimized reflection energy results in the improvement of migration result. To verify our algorithm, we implement the reverse-time migration using cell-based finite-difference method. Through numerical examples, we can note that the migration image is improved at the layer interfaces with high velocity contrast, and it shows the marked improvement particularly in the shallow part.

Physical Properties and Skin Penetration of Niosome Formulations Containing Minoxidil and Diaminopyrimidine Oxide (미녹시딜과 다이아미노피리미딘옥사이드 성분을 함유하는 니오좀 제형의 물성 및 피부투과)

  • Bo Kyung Kim;Won Hyung Kim;Kyung-Sup Yoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.49 no.2
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    • pp.127-139
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    • 2023
  • In this study, minoxidil, which is well known as a pharmaceutical raw material, and diaminopyrimidine oxide (DAO), which is a cosmetic raw material, were used as active ingredients to evaluate the physical properties of niosomes and compare the skin penetrations of artificial skin. To prepare niosomes of the size of nanoparticles, a high pressure homogenization method was used, and physical properties were evaluated with a zetasizer. The particle size of the noisome including the active ingredient was measured to be 99 to 123 nm according to HLB, and the zeta potential was measured in the range of -60 to -81 mV. Through DSC (differential scanning colorimetry), it was confirmed that minoxidil, a crystalline component, was uniformly dissolved in an amorphous state in niosomes. In order to confirm and compare skin penetration, it was measured by the in vitro Franz diffusion cell method, and the niosome formulation showed 3.4 times higher penetration for minoxidil and 11.1 times higher penetration for DAO than the control gel formulation. In addition, when comparing the skin penetration of minoxidil niosome and DAO niosome, a similar trend was shown, and the penetration amount of DAO was relatively high. The shapes of the niosome formulations with different HLB values were observed using Cryo-TEM, and it was confirmed that vesicles were formed in all of them and that they were intermediate between SUV (small unilamella vesicle) and LUV (large unilamella vesicle). Through this study, minoxidil, an effective drug for hair loss, and DAO, a cosmetic raw material, can be effectively delivered to the skin by encapsulating them in a noisome formulation.

A study on the determination of residual Antibiotics and Synthetic Antibacterial Agents in Meat(III) Simultaneous Gas Chromatography/Mass Spectrometry Analysis of Erythromycin and Tylosin (식육중의 잔류 항생.항균제의 검정에 관한 연구(III) Macrolide계 항생물질인 Erythromycin과 Tylosin의 Gas Chromatography/Mass Spectrometry 동시분석)

  • 류재천;송윤선;양종순;서지원;김명수;박종세
    • Journal of Food Hygiene and Safety
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    • v.8 no.1
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    • pp.17-23
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    • 1993
  • In an attempt to quantitate and qualitate residual antibiotics and antibacterial agents n meat simultaneously, we studied a gas chromatogrphy-mass spectrometry (GC/MS) analysis. For a simultaneous analysis of macrolide antibiotics such as erythromycin and tylosin in meat, the homogenization with MeOH, defatting with n-hexane, extraction with CHCl3, elution with CHCl3 : MeOH=2:1 from Sep-Pak silica cartridge, acid gydrolysis, back extraction with CHCl3, and quantitation by selected ion monitoring(SIM) mode after trimethylsilyl derivatization were performed. The recoveries of erythromycin and tylosin (CV,%) at 10 ppm fortification level were 90.59(4.89) and 45.91(0.20) , and the detection limits of those were 0.02 and 2.0 $\mu\textrm{g}$/g beef, respectively. From these results, the developed analytical method using GC/MS-SIM mode allows excellent detection and quantitation of residual macrolide antibiotics in meats, using complementary method with bio-assay.

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