• Title/Summary/Keyword: Homogeneous liquid

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Densification and Electrical Conductivity of Plasma-Sprayed (Ca, Co)-Doped LaCrO3 Coating (플라즈마 스프레이 (Ca, Co)-Doped LaCrO3 코팅층의 치밀화 및 전기전도도)

  • Park, Hee-Jin;Baik, Kyeong-Ho
    • Korean Journal of Materials Research
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    • v.27 no.3
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    • pp.155-160
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    • 2017
  • Doped-$LaCrO_3$ perovskites, because of their good electrical conductivity and thermal stability in oxidizing and/or reducing environments, are used in high temperature solid oxide fuel cells as a gas-tight and electrically conductive interconnection layer. In this study, perovskite $(La_{0.8}Ca_{0.2})(Cr_{0.9}Co_{0.1})O_3$ (LCCC) coatings manufactured by atmospheric plasma spraying followed by heat treatment at $1200^{\circ}C$ have been investigated in terms of microstructural defects, gas tightness and electrical conductivity. The plasma-sprayed LCCC coating formed an inhomogeneous layered structure after the successive deposition of fully-melted liquid droplets and/or partially-melted droplets. Micro-sized defects including unfilled pores, intersplat pores and micro-cracks in the plasma-sprayed LCCC coating were connected together and allowed substantial amounts gas to pass through the coating. Subsequent heat treatment at $1200^{\circ}C$ formed a homogeneous granule microstructure with a small number of isolated pores, providing a substantial improvement in the gas-tightness of the LCCC coating. The electrical conductivity of the LCCC coating was consequently enhanced due to the complete elimination of inter-splat pores and micro-cracks, and reached 53 S/cm at $900^{\circ}C$.

Effect of Thermal Energy of In-Flight Particles on Impacting Behavior for NiTiZrSiSn Bulk Metallic Glass during Kinetic Spraying (비행입자의 열 에너지에 따른 NiTiZrSiSn 벌크 비정질 분말의 적층 거동)

  • Yoon, Sang-Hoon;Kim, Soo-Ki;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.25 no.3
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    • pp.37-44
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    • 2007
  • Mechanical and thermomechanical properties of the bulk metallic glass (BMG) are so unique that the deformation behavior is largely dependent on the temperature and the strain rate. Impacting behavior of NiTiZrSiSn bulk metallic glass powder during kinetic spraying was investigated in this study. Considering the impact behavior of the BMG, the kinetic spraying system was modified and attached the powder preheating system to make the transition from the inhomogeneous deformation to the homogeneous deformation of impacting BMG particle easy BMG splat formation is considered from the viewpoint of the adiabatic shear instability. It is suggested that the impact behavior of bulk metallic glass particle is determined by the competition between fracture and deformation. The bonding of the impacting NiTiZrSiSn bulk amorphous particle was primarily caused by the temperature-dependent deformation and fracture (local liquid formation) behavior.

Electrical Breakdown and Flashover Characteristics of Gaseous Helium at Cryogenic Temperature (극저온 헬륨가스의 절연파괴 및 연면방전 특성)

  • Kwag, Dong-Soon
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.3
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    • pp.38-42
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    • 2012
  • Fixtures such as bushings in terminations of high temperature superconducting(HTS) power cable systems are subjected to high voltages, which have to transition from ambient to cryogenic temperatures. As such it is imperative to ensure the integrity of the dielectrics under all operating conditions, including thermal aspects brought about by the passage of current. Gaseous helium(GHe) at high pressure is regarded as a potential coolant for superconducting cables. The dielectric aspects of cryogenic helium gas are both complex and demanding. In this experimental study we looked at the interface between a smooth epoxy surface and high pressure helium gas in a homogeneous electric field. The alternating current(AC) flashover voltages of epoxy samples are presented. The results have been analyzed by using Weibull statistics. In addition to the behavior of the epoxy in gaseous helium as a function of pressure and temperature we also present data of the characteristics of the epoxy in mineral oil and in liquid nitrogen($LN_2$). The breakdown characteristics of a uniform field gap in gaseous helium as a function of pressure and temperature under AC, direct current(DC) and lightning impulse voltages are also given. Electric field calculations have been made for one of the experimental geometries in an attempt to explain some of the anomalies in the experimental results.

Effect of Fuel Injector-type Spark Plug on Combustion Characteristics

  • Yeom, J.K.;Chung, S.S.
    • Journal of ILASS-Korea
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    • v.14 no.4
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    • pp.171-177
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    • 2009
  • This study proposes a new stratified charge system for low emission and ultra lean burn. In order to examine combustion characteristics of the new system, sparkplug with a hole at positive pole and a common CNG injector for injecting fuel were used in this study as injector-type spark plug. The new stratified charge system injects fuel of extremely small quantities and ignites mixture around sparkplug gap. Also, the system was fitted in a visualized constant volume chamber. Then, for analysis of the combustion characteristics, we examined combustion pressure, lean inflammable limit, and visualized combustion flame according to equivalence ratio by comparison with homogeneous charge (HC) method and the new stratified charge (SC) method. As results of this study, in the case of using this system, the propagation speed of initial flame was increased and total combustion period was reduced in the ultra lean burn in the same equivalence ratio. These phenomena occurred clearly under the conditions of lean equivalence ratio. Furthermore, the lean inflammable limit of mixture was extended by using the injector-type spark plug.

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A Study on Effect of the Intake Valve Timing and Injection Conditions on the PCCI Engine Performance (흡기밸브 닫힘 시기와 분사조건이 PCCI 엔진의 성능에 미치는 영향에 관한 연구)

  • Lee, Jae-Hyeon;Kim, Hyung-Min;Kim, Yung-Jin;Lee, Ki-Hyung
    • Journal of ILASS-Korea
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    • v.15 no.1
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    • pp.1-7
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    • 2010
  • As world attention has focused on global warming and air pollution, high efficiency diesel engines with low $CO_2$ emissions have become more attractive. Premixed diesel engines in particular have the potential to achieve the more homogeneous mixture in the cylinder which results in lower NOx and soot emission. Early studies have shown that the operation conditions such as the EGR, intake conditions, injection conditions and compression ratio are important to reduce emissions in a PCCI (Premixed Charge Compression Ignition) engine. In this study a modified cam was employed to reduce the effective compression ratio. While opening timing of the intake valve was fixed, closing timing of the intake valve was retarded $30^{\circ}$. Although Atkinson cycle with the retarded cam leads to a low in-cylinder pressure in the compression stroke, the engine work can still be increased by advanced injection timing. On that account, we investigated the effects of various injection parameters to reduce emission and fuel consumption; as a result, lower NOx emission levels and almost same levels of fuel consumption and PM compared with those of conventional diesel engine cam timing could be achieved with the LIVC system.

3-D Axisymmetric Fluid-Structure-Soil Interaction Analysis Using Mixed-Fluid-Element and Infinite-Element (혼합형 유체요소와 무한요소를 이용한 3차원 축대칭 유체-구조물-지반 상호작용해석)

  • 김재민;장수혁;윤정방
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.10a
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    • pp.257-266
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    • 1999
  • This paper presents a method of seismic analysis for a cylindrical liquid storage structure on/in horizontally layered half.space considering the effects of the interior fluid and exterior soil medium in the frequency domain. To capture the essence of fluid-structure-soil interaction effects effectively, a mixed finite element with two-field (u, p) approximation is employed to model the compressive inviscid fluid, while the structure and soil medium are presented by the 3-D axisymmetric finite elements and dynamic infinite elements. The present FE-based method can be applied to the system with complex geometry of fluid region as well as with inhomogeneous near-field soil medium, since it can directly model both the fluid and the soil. For the purpose of verification, dominant peak frequencies in transfer functions for horizontal motions of cylindrical fluid storage tanks with rigid massless foundation on a homogeneous viscoelastic half.space are compared with those by two different added mass approaches for the fluid motion. The comparison indicates that the Present FE-based methodology gives accurate solution for the fluid-structure-soil interaction problem. Finally, as a demonstration of versatility of the present study, a seismic analysis for a real-scale LNG storage tank embedded in layered half.space is carried out, and its member forces along the height of the structure are compared with those by an added mass approach developed by the present writers.

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Studies on Antioxidative Substances of Ganoderma lucidum (영지의 항산화성 물질에 관한 연구)

  • Chung, Dong-Ok
    • Korean Journal of Food Science and Technology
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    • v.24 no.5
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    • pp.497-503
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    • 1992
  • To study antioxidative activities of Ganoderma lucidum, its extracts were fractionated by various organic solvents with different polarity the extracts were purified by thin chromatography, silicagel column chromatography and preparative liquid chromatography. In antioxidative activity tests using thiocyanate method, TBA method and weighing method, fraction 5 from the hexane extract and fraction II from the methanol extract showed antioxidative activity. When the antioxidative activities were expressed as TBA value using a homogeneous liver extracte of rats, the relative antioxidative activities of fraction 5 and fraction II were increased by 13.0% and 54.6%, respectively.

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Deformation Behavior of a $Zr_{55}Al_{10}Ni_5Cu_{30}$ Bulk Metallic Glass at High Temperatures (고온에서 $Zr_{55}Al_{10}Ni_5Cu_{30}$ 벌크 유리금속의 변형거동)

  • Jeong, Young-Jin;Kim, Ki-Hyun;Oh, Sang-Yeob;Shin, Hyung-Seop
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.342-347
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    • 2004
  • The deformation behavior of a $Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass under tensile loading at different range of strain rates and temperatures between 680 K and 740 K were investigated. The variation in the deformation behavior of $Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass which resulted from the crystallization induced during testing was reported. The$Zr_{55}Al_{10}Ni_5Cu_{30}$ bulk metallic glass has showed either homogeneous or inhomogeneous deformation depending on test condition. It exhibited a maximum elongation of about 560 % at the condition of $407^{\circ}C{\times}\;10^{-4}/s$. The flow behavior exhibited three different types and the flow stress became lower at higher temperatures and lower strain rates. The increase of the time elapsed during heating resulted in the partial crystallization of bulk metallic glass phase and eventually strain hardening and brittle fracture.

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Numerical Analysis of Partial Cavitaing Flow Past Axisymmetric Cylinders (축대칭 실린더형상 주위 부분공동 유동의 전산해석)

  • Kim, Bong-Su;Lee, Byung-Woo;Park, Warn-Gyu;Jung, Chul-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.2
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    • pp.69-78
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    • 2009
  • Cavitating flow simulation is of practical importance for many hydraulic engineering systems, such as pump, turbine, nozzle, injector, etc. In the present work, a solver for cavitating flow has been developed and applied to simulate the flows past axisymmetric cylinders. Governing equations are the two-phase Navier-Stokes equations, comprised of continuity equation of liquid and vapor phase. The momentum equation is in the mixture phase. The solver employed an implicit, dual time, preconditioned algorithm in curvilinear coordinates. Computations were carried out for three axisymmetric cylinders: hemispherical, ogive, and caliber-0 forebody shape. Then, the present calculations were compared with experiments and other numerical results to validate the present solver. Also, the code has shown its capability to accurately simulate the re-entrant jet phenomena and ventilated cavitation. Hence, it has been found that the present numerical code has successfully accounted for cavitating flows past axisymmetric cylinders.

A Study on the Auto-ignition Combustion Characteristics of CH4-Air Pre-mixtures in Constant Volume Combustion Chamber (정적연소기를 이용한 메탄-공기 예혼합기의 자발화 연소특성에 관한 연구)

  • Lee, Jin-Soo;Lee, Hae-Chul;Cha, Kyung-Ok;Jung, Dong-Soo
    • Journal of ILASS-Korea
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    • v.10 no.2
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    • pp.41-47
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    • 2005
  • Exhaust gas emissions from internal combustion engines are one of the major sources of air pollution. And. it is extremely difficult to increase gasoline engine efficiency and to reduce NOx and PM(particulate matter) simultaneously in diesel combustion. This paper offers some basic concepts to overcome the above problems. To solve the problems, a recommended technique is CAI(controlled auto-ignition) combustion. In this paper. internal EGR(exhaust gas recirculation) effect is suggested to realize CAI combustion. An experimental study was carried out to achieve CAI combustion using homogeneous premixed gas mixture in the constant volume combustion chamber(CVCC). A flame trap was used to simulate internal EGR effect and to increase flame propagation speed in the CVCC. Flame propagation photos and pressure signals were acquired to verify internal EGR effect. Flame trap creates high speed burned gas jet. It achieves higher flame propagation speed due to the effect of geometry and burned gas jet.

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