• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2005년도 추계 학술대회논문집
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• pp.169-177
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• 2005

A high resolution scheme for solving gas-liquid two-phase flows with cavitation is described. This scheme uses the curvilinear coordinate grid and solves the density based momentum equations for mixture of gas-liquid medium with a preconditioning method to treat both compressible and incompressible flow characteristics. The present preconditioned method is based on the Runge-Kutta explicit finite-difference scheme, and is improved by using the diagonalization, the flux difference splitting and the MUSCL-TVD schemes to save computational effort and to increase stability and resolvability, especially at gas-liquid contact surfaces. A homogeneous equilibrium cavitation model is used to treat the gas-liquid two-phase medium in cavitating flow as a locally homogeneous pseudo-single-phase medium. Therefore, it is easy to solve cavitating flow, including wave propagation, large density changes and incompressible flow characteristic at low Mach number. Some numerical results obtained by the present scheme are shown.

• Bulletin of the Korean Chemical Society
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• 제31권10호
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• pp.2813-2818
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• 2010

A novel method was developed for the speciation of chromium in natural water samples based on homogeneous liquid-liquid extraction and determination by flame atomic absorption spectrometry (FAAS). In this method, Cr(III) reacts with a new Schiff's base ligand to form the hydrophobic complex, which is subsequently entrapped in the sediment phase, whereas Cr(VI) remained in aqueous phase. The Cr(VI) assay is based on its reduction to Cr(III) by the addition of sodium sulfite to the sample solution. Thus, separation of Cr(III) and Cr(VI) could be realized. Homogeneous liquid-liquid extraction based on the pH-independent phase-separation process was investigated using a ternary solvent system (water-tetrabutylammonium ion ($TBA^+$)-chloroform) for the preconcentration of chromium. The phase separation phenomenon occurred by an ion-pair formation of TBA and perchlorate ion. Then sedimented phase was separated using a $100\;{\mu}L$ micro-syringe and diluted to 1.0 mL with ethanol. The sample was introduced into the flame by conventional aspiration. After the optimization of complexation and extraction conditions such as pH = 9.5, [ligand] = $1.0{\times}10^{-4}\;M$, [$TBA^+$] = $2.0{\times}10^{-2}\;M$, [$CHCl_3$] = $100.0\;{\mu}L$ and [$ClO_4$] = $2.0{\times}10{-2}\;M$, a preconcentration factor (Va/Vs) of 100 was obtained for only 10 mL of the sample. The relative standard deviation was 2.8% (n = 10). The limit of detection was sufficiently low and lie at ppb level. The proposed method was applied for the extraction and determination of chromium in natural water samples with satisfactory results.

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.781-785
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• 2005

A fast and reliable method for the selective separation and preconcentration of $Cu^{2+}$ ions using homogeneous liquid-liquid extraction was developed. A new $\alpha$-dioxime derivative (2H-1,4-benzothioazine-2,3(4H)dionedioxime, Dioxime I) was synthesized and investigated as a suitable selective complexing ligand for $Cu^{2+}$ ions. Zonyl FSA (FSA) was applied as a phase-separator agent under the slightly acidic pH conditions. Under the optimal experimental conditions ([FSA] = 3.2% w/v, [THF] = 19.5% v/v, [Dioxime I] = 1.9 ${\times}\;10^{-3}$ M, and pH = 4.7), 10 ${\mu}g\;of\;Cu^{2+}$ in 5.2 mL aqueous phase could be extracted quantitatively into 80 $\mu$L of the sedimented phase. The maximum concentration factor was 65-fold. The limit of detection of the proposed method was 0.005 ng $mL^{-1}$. The reproducibility of the proposed method, on the 10 replicate measurements, was 1.3%. The influence of the pH, type and volume of the water-miscible organic solvent, concentration of FSA, concentration of the complexing ligand and the effect of different diverse ions on the extraction and determination of $Cu^{2+}$ ions were investigated. The proposed method was applied to the extraction and determination of $Cu^{2+}$ ion in different synthetic and natural water samples.

• 한국전산유체공학회지
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• 제12권2호
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• pp.53-62
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• 2007

A high resolution numerical method aimed at solving cavitating flow is proposed and applied to gas-liquid two-phase shock tube problem. The present method employs a finite-difference 4th-order Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL TVD scheme. By applying the homogeneous equilibrium cavitation model, the present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation and large density changes. The speed of sound for gas-liquid two-phase media is derived on the basis of thermodynamic relations and compared with that by eigenvalues. By this method, a Riemann problem for Euler equations of one dimensional shock tube was computed. Numerical results such as detailed observations of shock and expansion wave propagations through the gas-liquid two-phase media at isothermal condition and some data related to computational efficiency are made. Comparisons of predicted results and exact solutions are provided and discussed.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년도 학술대회
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• pp.215-220
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• 2008

A numerical method for gas-liquid two-phase flow is applied to solve shock-bubble interaction problems. The present method employs a finite-difference Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL-TVD scheme. A homogeneous equilibrium cavitation model is used. By this method, a Riemann problem for shock tube was computed for validation. Then, shock-bubble interaction problems between cylindrical bubbles located in the liquid and incident liquid shock wave are computed.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년 추계학술대회논문집
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• pp.215-220
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• 2008

A numerical method for gas-liquid two-phase flow is applied to solve shock-bubble interaction problems. The present method employs a finite-difference Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL-TVD scheme. A homogeneous equilibrium cavitation model is used. By this method, a Riemann problem for shock tube was computed for validation. Then, shock-bubble interaction problems between cylindrical bubbles located in the liquid and incident liquid shock wave are computed.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 하계학술발표대회 논문집
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• pp.142-147
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• 2008

This paper reports an analysis of self-pressurization in a closed cryogenic liquid storage system and its comparison with experimental data using liquid nitrogen. Partial equilibrium model(PEM), revised thermodynamic analysis of homogeneous model, has been applied for the pressurization in a closed tank. The vapor and liquid bulk temperature and the liquid-vapor interface temperature are separately calculated as their own representative values in this analysis. The analysis results of the partial equilibrium model are compared with the experimental data and other preceding homogeneous temperature models for validation.

• Transactions on Electrical and Electronic Materials
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• 제10권1호
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• pp.16-19
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• 2009

We have studied the liquid crystal alignment properties for various alignment methods on the homogeneous polyimide surface. Suitable liquid crystal alignment for one-side alignment cell on the polyimide surface by all alignment method was observed. Highly pre-tilt angle of the NLC for both-side rubbing cell was measured. But, low pre-tilt angle of the NLC for one-side ion beam and UV irradiation cell was observed. We consider that the pre-tilt angle of NLC for one-side ion beam and UV irradiation on the PI surface is lower than that of the PI surface with rubbing. Also, the suitable transmittance-voltage curves for the one-side rubbing TN-LCD on the PI surface with one-side UV irradiation were measured. Also, good response time characteristics of the one-side rubbing TN-LCD on the polyimide surface with one-side UV irradiation can be measured.

• 한국위성정보통신학회논문지
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• 제10권1호
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• pp.67-70
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• 2015

본 연구에서는 폴리이미드 박막위에서의 수직 및 수평배향에서 혼합액정의 배향 특성에 대해서 연구하였다. 혼합액정은 러빙을 이용하여 배향처리하였으며, 러빙에 사용된 폴리이미드 박막은 알킬기를 Side Chain으로 가진 수직배향용 배향막과 그렇지 배향막으로 나누어서 프리틸트각 특성을 측정하였다. 실험결과 혼합액정을 사용하여 양호한 배향상태를 얻을 수 있었으며, 고온에서의 열안 정성에서도 우수한 특성을 보이는 것을 알 수 있었다. 또한 프리틸트각의 발생 원리를 이해하기 위해서 접촉각 측정을 실시하였으며, 이 둘이 밀접한 상관관계를 갖고 있음을 알 수 있었다.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2007년도 추계 학술대회논문집
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• pp.249-257
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• 2007

A high resolution numerical method aimed at solving gas-liquid two-phase flow is proposed and applied to gas-liquid two-phase shock tube problem. The present method employs a finite-difference 4th-order Runge-Kutta method and Roe's flux difference splitting approximation with the MUSCL TVD scheme. By applying the homogeneous equilibrium cavitation model, the present density-based numerical method permits simple treatment of the whole gas-liquid two-phase flow field, including wave propagation and large density changes. The speed of sound for gas-liquid two-phase media is derived on the basis of thermodynamic relations and compared with that by eigenvalues. By this method, a Riemann problem for Euler equations of one dimensional shock tube was computed. Numerical results such as detailed observations of shock and expansion wave propagations through the gas-liquid two-phase media and some data related to computational efficiency are made. Comparisons of predicted results and exact solutions are provided and discussed.