• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.62-68
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• 2006

High temperature electrolysis is a promising technology to produce massively hydrogen using renewable and nuclear energy. Solid oxide fuel cell materials are candidates as the components of steam electrolysers. However, the polarization characteristics of the typical electrode materials during the electrolysis have not been intensively investigated. In this study, NiO electrode was deposited on YSZ electrolyte by spin coat process and firing at $1300^{\circ}C$. Pt electrode was applied on the other side of the electrolyte to compare the polarization characteristics with those by NiO during electrolysis. The $H_2$ evolution rate was also monitored by measuring the electromotive force of Lambda probe and calculated by thermodynamic consideration. At low current density, Pt showed lower cathodic polarization and thus higher current efficiency than Ni, but the oxidation of Ni into NiO caused the increase of anodic resistance with increasing current density. High overpotential induced high power consumption to produce hydrogen by electrolysis.

• 대한기계학회논문집B
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• 제39권3호
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• pp.207-214
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• 2015

해양온도차발전용 터빈의 효율과 크기를 파악하기 위해 R134a를 작동유체로 하고 출력 5 kW인 반경류형 터빈의 설계가 수행되었다. 터빈입구온도 $25^{\circ}C$, 출구 정압 4.9 bar, 질량유량 1.16 kg/s 로 설정하고 평균유동해석을 수행하여 터빈의 회전수와 주요 치수를 결정하였다. 이들을 바탕으로, 3 차원 터빈 모델을 구축하였으며, 도출된 터빈회전수 12,820 rpm에 대하여 전산유체역학(CFD) 소프트웨어 ANSYS CFX를 이용하여 볼류트와 노즐을 포함하는 터빈 내부 유동장 특성과 효율이 조사되었다. 80%이상의 터빈 효율이 적정 범위 내의 노즐 안내깃 수(10-15 개)에서 제시되었으며, 가장 높은 터빈 효율은 15 개의 안내 깃에서 나타났다.

• 공업화학
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• 제9권1호
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• pp.94-100
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• 1998

천연가스의 주성분인 메탄의 마이크로웨이브 플라즈마 촉매반응에 의한 C2+ 탄화수소로의 전환반응을 고찰하였다. 플라즈마 출력의 증가(40~120 watt)와 유량이 감소(40~5mL/min)함에 따라서 메탄의 C2+ 생성물로의 전환율을 29.2%에서 42.2%로 향상되었으며, 촉매를 플라즈마와 함계 사용하여 에틸렌과 아세틸렌의 선택도를 향상시키는 동시에 높은 전환율을 유지할 수 있다. 실험에 사용한 여러 촉매중에는 Fe계의 촉매가 가장 높은 에틸렌의 선택도(30%)를 나타내었다. 실제 천연가스의 전환실험에서는 C2+ 생성물의 수율이 33.3%에서 46%의 범위를 보였다. 순수한 메탄이 원료였을 때 보다 높은 C2+ 수율이 얻어진 것은 천연가스가 메탄 보다 반응성이 높은 성분인 에탄과 프로판등을 함유하고 있기 때문으로 생각된다.

• 한국토양비료학회지
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• 제45권1호
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• pp.107-111
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• 2012

Eight marine sediments from Busan port in Korea were annually analyzed to examine the concentration distribution of dioxins from 2006 to 2010. Yearly mean concentration of dioxins ranged from 186.3 to $383.3pg\;g^{-1}$ in real values and 5.087 to 8.541 pg-TEQ (Toxicity equivalency) based on dry weight of samples. The dioxin concentration at the site near fishing market was the highest concentration among all sampling sites. Also the dioxin concentration at the sites with various pollutant sources such as large ships, sewage influx and thermal power station as well as fishing market was higher than that of the sites without specific pollutant sources. Another main factor that affects the dioxin concentration is topography characteristics of the bay. The bay has relatively high dioxin concentration because of the lack of the pollutant diffusion. This study demonstrated that the dioxin concentration in the site with pollutant sources and the lack of the pollutant diffusion was relatively high as compared with the other sites. As a result of contribution ratio of dioxin congeners, OCDD (Octachlorodibenzodioxin) in all sites was major contributor in real value, in contrast, dioxin congeners in TEQ values were dominated by 2,3,4,7,8-PeCDF.

• Journal of Welding and Joining
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• 제34권1호
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• pp.75-81
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• 2016

This study applied laser surface melting process using CW(Continuous wave) Yb:YAG laser and cold-work die steel SM45C and investigated microstructure and hardness. Laser beam speed, power and beam interval are fixed at 70 mm/sec, 2.8 kW and $800{\mu}m$ respectively. Depth of Hardening layer(Melting zone) was a minimum of 0.8 mm and a maximum of 1.0 mm that exceeds the limit of minimum depth 0.5 mm applying trimming die. In all weld zone, macrostructure was dendrite structure. At the dendrite boundary, Mn, Al, S and O was segregated and MnS and Al oxide existed. However, this inclusion didn't observe in the heat-affected zone (HAZ). As a result of interpreting phase transformation of binary diagram, MnS crystallizes from liquid. Also, it estimated that Al oxide forms by reacting with oxygen in the atmosphere. The hardness of the melting zone was from 650 Hv to 660 Hv regardless of the location that higher 60 Hv than the hardness of the HAZ that had maximum 600 Hv. In comparison with the size of microstructure using electron backscatter diffraction(EBSD), the size of microstructure in the melting zone was smaller than HAZ. Because it estimated that cooling rate of laser surface melting process is faster than water quenching.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.16.2-16.2
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• 2011

Graphene has attracted significant attention due to its unique characteristics and promising nanoelectronic device applications. For practical device applications, it is essential to synthesize high-quality and large-area graphene films. Graphene has been synthesized by eloborated mechanical exfoliation of highly oriented pyrolytic graphite, chemical reduction of exfoliated grahene oxide, thermal decomposition of silicon carbide, and chemical vapor deposition (CVD) on metal substrates such as Ni, Cu, Ru etc. The CVD has advantages over some of other methods in terms of mass production on large-areas substrates and it can be easily separated from the metal substrate and transferred to other desired substrates. Especially, plasma-enhanced CVD (PECVD) can be very efficient to synthesize high-quality graphene. Little information is available on the synthesis of graphene by PECVD even though PECVD has been demonstrated to be successful in synthesizing various carbon nanostructures such as carbon nanotubes and nanosheets. In this study, we synthesized graphene on $Ni/SiO_2/Si$ and Cu plate substrates with CH4 diluted in $Ar/H_2$ (10%) by using an inductively-coupled PECVD (ICPCVD). High-quality graphene was synthesized at as low as $700^{\circ}C$ with 600 W of plasma power while graphene layer was not formed without plasma. The growth rate of graphene was so fast that graphene films fully covered on substrate surface just for few seconds $CH_4$ gas supply. The transferred graphene films on glass substrates has a transmittance at 550 nm is higher 94%, indicating 1~3 monolayers of graphene were formed. FETs based on the grapheme films transferred to $Si/SiO_2$ substrates revealed a p-type. We will further discuss the synthesis of graphene and doped graphene by ICPVCD and their characteristics.

• 한국융합학회논문지
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• 제11권8호
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• pp.279-285
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• 2020

임산부의 출산 경험에 따른 구강보건에 대한 지식 및 실천도를 확인하고, 구강건강관리 실천도에 영향을 미치는 요인을 파악하고자 한다. 대전광역시 소재 산부인과에 내원 중인 임산부를 대상으로 2019년 3월 2일부터 30일까지 자기기입식 설문조사를 실시하였다. SPSS WIN(ver 19.0) 프로그램을 이용하여 임산부의 구강건강관리에 대한 지식도와 실천도는 출산 경험에 따라 t-test를 실시하였고, 실천도에 영향을 미치는 요인은 다중회귀분석을 실시하였다. 연구결과, 구강건강관리에 대한 지식도는 전신건강행위 문항에서 '출산 무경험인 임부'가 '출산 경험이 있는 임산부'보다 높게 나타났다. 임산부의 구강건강관리 실천도에 영향을 미치는 요인으로 교육수준, 임신 전 구강검진 및 치료 경험, 임신으로 인한 구강상태 변화 경험, 임산부의 구강건강관리 지식도로 나타났고, 설명력은 26.9%이었다. 따라서 임산부의 구강보건교육 대상 범위 확대와 실천율을 향상시킬 수 있는 구강보건교육 프로그램 개발이 필요하다.

• 한국가스학회지
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• 제5권1호
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• pp.15-20
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• 2001

저온 마이크로웨이브 플라즈마와 촉매반응에 의한 메탄올 활성화하여 C2+ 화합물과 수소로 전환하는 반응을 고찰하였다. 금속 촉매인 Fe, Ni과 귀금속 촉매인 Pt, Pd 계열의 촉매로 본 실험을 수행하였다 메탄의 유속이 $20ml\;min^{-1}$일때 플라즈마의 출력이 증가할수록 C2+ 생성물은 29에서 $42\%$로 증가하였으며 동시에 메탄의 커플링 반응에서 발생하는 수소는 0.6에서 0.65 몰분율을 나타내었다. 촉매는 플라즈마 영역 후단에 위치하였을 때, C2+ 생성물이 일정한 수율을 나타내는 반면 에틸렌과 아세틸렌의 선택도는 향상되었다. 플라즈마 반응후 ECR 전기장과 Pd-Ni 이원촉매를 위치했을 때 최고의 C2+ 수율은 $64\%$로 관찰되었다.

• Applied Biological Chemistry
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• 제25권4호
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• pp.218-223
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• 1982

밤(품종, 은기) 전부의 성상, 이화학적 특성 및 전분 겔의 노화속도를 조사하였다. 전분의 입자는 장축 및 단축의 비가 1.4 : 1인 불규칙한 타원형으로서 크기는 $2.9{\sim}21.4{\mu}$(평균 $10\;{\mu}$)이었다. X-ray 회절도는 $2{\theta}$가 $5.6^{\circ},\;15.3^{\circ},\;17.2^{\circ},\;22.0^{\circ},\;23.8^{\circ}$에서 peak를 보였으며, B형에 속하였다. 전분의 아밀로스 함량은 22.7%, 물 결합 능력은 81.5%, 호화온도는 $55^{\circ}C$이었다. 전분의 swelling은 $55^{\circ}C$까지는 큰 변화가 없었고, 이후 급격히 증가하였으나 $65^{\circ}C$ 이후에는 그 변화가 완만하였다. 아밀로그라프에 의한 전분의 호화는 농도(5 및 6%)에 관계없이 비슷한 양상을 보였으며, 최고 점도는 나타나지 않았다. 밤 전분은 입자간의 결합강도가 강하며, 열 및 shear force에 의한 swollen granule의 저항성이 큰 특징을 보였다. 전분 겔(건물중으로 45%)의 노화 시간상수(속도 상수의 역수)는 $21^{\circ}C$에서 1.68일이었다.

• International Journal of Safety
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• 제11권1호
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• pp.33-36
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• 2012

Examples and experiences of risk management on radiation under prolonged exposure situation are shown. The accident of the Fukushima dai-ichi nuclear power plant after the great east Japan earthquake (11 March, 2011) elevates background level of environmental radiation around the east Japan. For example, ambient dose equivalent rate around Tohkatsu area next to Tokyo located about 200 km-south from the plant, is about 0.1-0.6 micro-Sv $h^{-1}$ mainly due to $^{134}Cs$ and $^{137}Cs$ falling on the ground soil. This level is about double or up to ten times higher than the genuine natural level around the area. International Commission on Radiological Protection (ICRP) recommends how to face the existing exposure situation; that is the prolonged exposure situation. Referring to ICRP's reports and/or related international/domestic documents, we have been discussing and acting to gain public's safety and relief, who have a possibility to be exposed to prolonged lower-dose radiation. Here, we introduce our several experiences on risk management, especially focusing on risk communication, radiation education to public, and stakeholder involvements into making decision in local governments on radiation protection, relating to the accident.