• Title/Summary/Keyword: Higher Concentration

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Determination of Bioconcentration Factor on Carbamates (Carbamate계 농약의 생체농축계수 측정)

  • 민경진
    • Journal of Environmental Health Sciences
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    • v.20 no.4
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    • pp.80-89
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    • 1994
  • It was reported that BCF's (Bioconcentration Factor) on Carbaryl and BPMC in concentration of 1, 2, 5 and 10 ppm, previously. Carassius auratus(goldfish) was chosen as test organism. Carbamates in fish and in test water were extracted with n-hexane and acetonitrile. GC-ECD was used to detecting and quantitating of Carbamates. Also, partition coefficients were determined with Stir flask method. To evaluate environmental toxicological profiles of tested compounds, experimental concentration were 0.05, 0.1 and 0.5 ppm in contrast to previous report. It was considered that higher BCFs of BPMC due to its higher partition coefficient compared to Carbaryl. The obtained results were as follows: 1. It was possible to determine short term BCF of Carbaryl and BPMC through relatively simple procedure in environmental concentrations. 2. BCF$_3$ of Carbaryl in concentration of 0.05, 0.1 and 0.5 ppm were 4.666 $\pm$ 0.002, 3.622 $\pm$ 0.004, 1.200 $\pm$ 0.002 and BCF$_5$ were 3.897 $\pm$ 0.005, 4.219 $\pm$ 0.017 and 1.186 $\pm$ 0.054, respectively. In the case of BPMC in same condition, BCF$_3$ were 4.077 $\pm$ 0.014, 4.900 $\pm$ 0.005, 4.750 $\pm$ 0.009 and BCF$_5$ were 3.465 $\pm$ 0.010, 4.612 $\pm$ 0.011 and 4.075 $\pm$ 0.012, respectively. 3. Carbaryl concentration in fish extract was increased as increasing test concentration, but BCF were decreased as prolonging test period, especially dropped at 0.5 ppm. 4. In the case of BPMC, BCF were decreased as increasing test concentration, but the concentration in fish extract of 3-day test group was slightly higher than that of 5-day test group. 5. Higher BPMC concentration in fish extract was due to its higher partition coefficient to compared with Carbaryl. 6. Determined logP of Carbaryl and BPMC were 2.200 and 3.180. But the calculated BCF using suggested equation was so different that predict BCF. It is suggested that BCF's of Carbamates have to be determined by experiment.

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The Characteristics and Relationships of Learning Abilities by Brain Preference and EEG According to Elementary School Students Academic Achievement Level (초등학생의 학업성취수준에 따른 뇌 선호도와 뇌파에 의한 학습능력의 특성 및 관계)

  • Kim, Jin Seon;Shim, Jun Young
    • Korean Journal of Child Studies
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    • v.36 no.6
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    • pp.85-100
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    • 2015
  • This study divided elementary school 6th graders of into a higher academic achievement group (n=19) and a lower academic achievement group (n=19) in order to examine the tendency of left and right hemisphere preferences, characteristics and relationships of learning ability factors by means of EEG. For this purpose, brain waves in performing higher cognitive tasks for 5 min. were measured with a two-channel (Fp1, Fp2) EEG measurement system and hemisphere preference was measured by means of a questionnaire. Our results were as follows. First, hemisphere preference indicated that the higher group showed a left hemisphere tendency and the lower group indicated a right hemisphere tendency. Second, the first learning ability test found that the higher group performed its task rapidly with higher levels of concentration and cognitive strength and lower loading and the lower group conducted its task more slowly with lower levels of concentration and cognitive strength and higher loading. The second test showed that the higher group performed its task rapidly with lower levels of concentration.

Concentration of Fresh Gel from Aloe vera L. by Using Ultrafiltration Process (한외여과 공정에 의한 알로에 베라 겔 농축)

  • Baek, Jin-Hong;Kim, Sung-A;Lee, Shin-Young
    • KSBB Journal
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    • v.23 no.2
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    • pp.169-176
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    • 2008
  • The concentration of fresh gel from Aloe vera L. by using ulfrafiltration (UF) process was investigated and analyzed. The two membranes (organic and ceramic) with different molecular weight cut-off (MWCO) and modules (flat sheet and tubular) was used. Under optimum operation conditions, ceramic (zirconium dioxide) tubular membrane with MWCO of 50 kDa resulted in higher flux, less fouling, more turbid, higher total solid, higher polysaccharide and less aloin content. Optimum operation conditions were transmembrane pressure of 1.0 bar, feed velocity of 240 L/hr and temperature of $23^{\circ}C$. Volume concentration factor of aloe gel was 3.13 at permeate flux of $51.1\;L/m^2{\cdot}hr$ after processing time of 1.66 hr. Aloin in fresh aloe gel by UF process was effectively removed as permeate and bioactive polysaccharide content was 2.1 times higher than that of fresh aloe gel. These results allowed a very good level of concentration degree and polysaccharide content. Thus, ultrafiltration process of this study was suitable for the concentration of fresh aloe gel though the aloe concentrate showed both the viscosity decrease and partially separation of liquid layer during storage at $4^{\circ}C$.

Antimicrobial Susceptiblity of Brucella canis Isolated from Korea (국내 분리 Brucella canis의 항균제 감수성)

  • 김종완;이영주;탁연빈
    • Journal of Veterinary Clinics
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    • v.20 no.1
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    • pp.86-90
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    • 2003
  • Little is known to data about the in vitro activity of antimicrobial agents aganist Brucella cams (B cams) isolated from Korea. Our study aimed at determining the in vitro activities of 15 antimicrobial agents against 3 isolates and 52 isolates of B cams from dogs in 1994 and 2002, respectively. In minimal inhibitory concentration (MIC) study, minocycline and doxycycline showed the lowest MICs ( < 0.06-0.5 ug/ml). Gentamicin, streptomycin, ciprofloxacin, norfloxacin and rifampin showed MICs in the range of less than 1 ug/ml. Lincomycin and sulfisox azole showed the highest MICs ( > 32 ug/ml). Interestingly, MICs of macrolides (erythromycin, spiramycin, tylosin) against 52 isolates in 2002 were 16-64 times higher than that of 3 isolates in 1994. In minimal bactericidal concentration (MBC) study, gentamicin, streptomycin, ciprofloxacin and norfloxacin showed the lowest MBCs [0.12-1 ug/ml (1-2 times higher than MIC)], but minocycline and doxycycline showed the highest MBCs [8-32 ug/ml (128 times higher than MIC)]. Rifampin showed the MBCs in the range from 2 to 4 ug/ml (2-4 times higher than MIC).

Comparison of particle size distribution and particle number concentration measured by APS 3321 and Dust Monitor 1.108 (APS 3321과 Dust Monitor 1.108을 이용한 입자 크기분포 및 수농도 측정결과 비교)

  • Lim, Kyoung-Soo;Park, Hyun-Seol
    • Particle and aerosol research
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    • v.5 no.2
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    • pp.63-70
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    • 2009
  • The size distribution and number concentration of atmospheric aerosol were measured and compared using APS 3321 and Dust Monitor 1.108. The particle size distribution and number concentration measured by two devices were also compared at a particle generation system of standard PSL and fly ash. The number concentration of atmospheric aerosol measured by APS was higher than that by Dust Monitor in particle size range of less than $3.0{\mu}m$, but there was good accordance between them in particle size range of over $3.0{\mu}m$. In the particle generation system of PSL and fly ash, different measurement results were shown because the particle concentration was higher than that of atmospheric aerosol. The number concentration measured by Dust Monitor was higher than that by APS in most particle size ranges. However, the peak concentration of PSL particles measured by Dust Monitor was lower than that by APS. The difference of the collection efficiency in a scrubber by APS and Dust Monitor measurement was less than 10%, but in the particle size of $1.5{\mu}m$, it was over 20%.

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Nitritation Characteristics Depending on Influent Nitrogen Concentration in a Biological Aerated Filter (Biological Aerated Filter에서 유입 질소농도에 따른 아질산화 특성)

  • Yoo, Ik-Keun
    • Journal of Korean Society on Water Environment
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    • v.30 no.1
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    • pp.1-7
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    • 2014
  • The purpose of this study was to investigate the nitrification characteristics of biological aerated filter (BAF) packed with ceramic media, especially focusing on nitrite build-up during nitrification. When increasing the nitrogen load above $1.63kgNH_4{^+}-N/m^3{\cdot}d$, ammonium removal efficiency decreased to less than 60% and the nitrite ratio ($NO_2{^-}-N/NO_x-N$) of higher than 75% was achieved due to the inhibitory free ammonia (FA, $NH_3-N$) concentration and oxygen limitation. FA inhibition, however, is not recommended strategy to promote nitrite build-up since FA concentration in the reactor is coupled with decreased ammonium removal efficiency. Nitrite ratio in the effluent was also affected by aeration rate and influent ammonium concentration. Ammonium oxidation was enhanced at a higher aeration rate regardless of influent ammonium concentration but, the nitrite ratio was dependent on both aeration rate and influent ammonium concentration. While a higher nitrite ratio was obtained when BAFs were fed with $50mgNH_4{^+}-N/L$ of influent, the nitrite ratio significantly decreased for a greater influent concentration of $200-300mgNH_4{^+}-N/L$. Taken together, aeration rate, influent ammonium concentration and FA concentrations kept in the BAF were found to be critical variables for nitrite accumulation in the BAF system.

Studies on Biological Activity from Antler extract added Medical plants (한약재를 가미한 녹용추출물의 생리활성에 관한 연구)

  • An, Bong-Jeun;Lee, Jin-Tae;Kim, Sang-Chan;Lee, Im-Sik;Chung, Jong-Hun
    • Herbal Formula Science
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    • v.9 no.1
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    • pp.335-354
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    • 2001
  • This study was designed to investigate biological activity of antler extract added medical plants. The scavenging activity of DPPH radical was low scavenging activity at 0.01% concentration. But in the 0.05% and higher concentration, electron donating ability(EDA) is above 50% except Kongindangagam(48.5%) and significantly good above 70% in the 4 extracts. Superoxide dismutase(SOD)-like activity was 44.3% and 45.1% extracts of Ohjayenjongwhangami and M(market sample), Inhibition of xanthine oxidase were above 50% at 0.5% concentration except Boshingiwhangwhangami and from 62.4% to 84.9% in the 4 extracts. Inhibition rate of boshingiwhangwhangami was hasty increased from 33.5% to 77.5% at 1.0% concentration and others the higher concentration, the more increasing inhibition. Angiotension I-converting enzyme(ACE) inhibitory activities were high activity all of extracts. In the 0.5% concentration, ACE inhibition was above 80%. Especially 0.01% concentration of M was presented 81.8%. The study which conducted to investigate the effect of feeding antler extract group for 50 days on sperm concentration, Ca contents of serum, kidney and femur in rats was higher than that saline group.

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The Study on the High Nocturnal Concentration of Ground Level Ozone (야간 지표 고농도 오존에 관한 연구)

  • 김유근;홍정혜
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.6
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    • pp.545-554
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    • 1998
  • The diurnal variation of O3 concentration shows two peaks, the first peak at noontime and the secondary peak at night. In order to show why the secondary peak, high nocturnal O3 concentration, occurs without sunlight which is a essential factor of a photochemical response, the O3 concentration, several weather elements and synoptic weather map were used for June∼September at 1995, 1996. The mean concentration of high nocturnal O3 concentration days is higher by 5.4 ppb than that of low nocturnal O3 concentration days. The nocturnal O3 concentration is higher than that of diurnal O3 concentration during high nocturnal O3 concentration days, at July, 1995 and June, 1996. The high nocturnal O3 concentration is related to low air pressure, high cloud cover and high wind speed. The correlation coefficient, r. between nocturnal O3 concentration and wind speed, pressure and cloud cover is 0.387, -0.218, and 0.194, respeftiviely. It is interesting that the O3 concentration increases at Pusan when the typhoon passes by. The same result showed at Taegu when the typhoon FAYE passed by. According to the analysis of nocturnal O3 concentration for June∼September at 1995 and 1996, it seems that the high nocturnal O3 concentration relates to the trough and cyclones passing by Pusan.

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Characteristics of Concentration and Load of Nitrogen and Phosphorous in Paddy Field Areas (광역논에서의 질소 .인의 농도와 오염부하량 특성)

  • 김진수
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.41 no.4
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    • pp.47-56
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    • 1999
  • The concentration and load of T-N and T-P in paddy field areas in Chongwon, Chungbuk , Korea , were investigated during the irrigation period. The concentration of T-N and T-P in ponded water in paddies is higher than that in the irrigation, drainage and percolation waters. For T-N, the average concentration indrainage water was higher than that in irrigation water until end of Jung, But lower thereafter. The average T-N concentration in irrigation water was 2.3 ∼3.2mg/l and therefore the agricultural water quality standard at on-farm level for T-N should be established realistically . The expontial L(load)-Q(discharge) equations have higher coefficients of determination than the linear L-Q equations . Especially, the exponential L-Q equation of T_N showed a coefficient of determinatino of over 0.9 for irrigation water.

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A Study on the Size of Ultrafine Particles and Heavy Metal Concentrations in the Atmosphere (일반대기 중 극미세입자와 중금속 농도에 관한 연구)

  • Cho, Tea-Jin;Jeon, Hye-Li;Youn, Hyung-Sun;Lee, Mi-Young;Son, Bu-Soon
    • Journal of Environmental Health Sciences
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    • v.36 no.6
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    • pp.480-495
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    • 2010
  • This study evaluated the distribution of the concentrations of nano-particles and heavy metals (08-Pb, Cr, Zn, As, Fe, 09-Pb, Cr, Zn, Cu, Ni, Mn) in Seoul, Chungnam A and Gwangyang from August to December, in 2008 5 times each in the Seoul area, 5 times in and Chungnam A area and from August to November, in 2009 14 times in the Chungnam A area, 8 times in the Gwangyang area. The examined results showed high concentration level from $PM_1$ through $PM_{0.1}$ in all three areas. These results were obtained the concentration of particles by diameter and statistically significant in Stage5 (1.0-0.56 ${\mu}m$) from the result of conducting Kruskal-Wallis H test (p < 0.05). In the case of the heavy metal concentration included in 0.10-0.056 ${\mu}m$, 0.056 ${\mu}m$, the lead concentration of Chungnam Asan area was 6.49 ng/$m^3$ and 9.93 ng/$m^3$, which was higher than 3.05 ng/$m^3$ and 4.22 ng/$m^3$ of Seoul, respectively. The concentration of iron in Seoul was 9.28 ng/$m^3$ and 13.24 ng/$m^3$, that appeared higher than 2.38 ng/$m^3$ and 3.23 ng/$m^3$ of Chungnam A area, respectively. The concentration level was similar to other metals except lead and iron in Chungnam A area and Seoul. From the concentration of heavy metal included in 0.10-0.056 ${\mu}m$, 0.056 ${\mu}m$, the lead concentration of Chungnam A area was 0.31 ng/$m^3$ and 0.12 ng/$m^3$ while Gwangyang was 0.28 ng/$m^3$, 0.06 ng/$m^3$. Thus Chungnam A area showed higher lead concentration than Gwangyang. The manganese concentration of Chungnam A area was 0.12 ng/$m^3$ and 0.03 ng/$m^3$ while Gwangyang was 0.21 ng/$m^3$ and 0.08 ng/$m^3$. Therefore, the concentration of Gwangyang appeared higher than that of Chunnam A area. These two metals showed statistically significant in 0.056 ${\mu}m$ (p < 0.05, p < 0.01). Among the concentration of heavy metal in all regions, the result demonstrated that the order of higher concentration is arsenic > iron > zinc > chrome > lead > nickel > copper > manganese.