• Title/Summary/Keyword: High-temperature solar thermal

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The effect of thermal anneal on luminescence and photovoltaic characteristics of B doped silicon-rich silicon-nitride thin films on n-type Si substrate

  • Seo, Se-Young;Kim, In-Yong;Hong, Seung-Hui;Kim, Kyung-Joong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.141-141
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    • 2010
  • The effect of thermal anneal on the characteristics of structural properties and the enhancement of luminescence and photovoltaic (PV) characteristics of silicon-rich silicon-nitride films were investigated. By using an ultra high vacuum ion beam sputtering deposition, B-doped silicon-rich silicon-nitride (SRSN) thin films, with excess silicon content of 15 at. %, on P-doped (n-type) Si substrate was fabricated, sputtering a highly B doped Si wafer with a BN chip by N plasma. In order to examine the influence of thermal anneal, films were then annealed at different temperature up to $1100^{\circ}C$ under $N_2$ environment. Raman, X-ray diffraction, and X-ray photoemission spectroscopy did not show any reliable evidence of amorphous or crystalline Si clusters allowing us concluding that nearly no Si nano-cluster could be formed through the precipitation of excess Si from SRSN matrix during thermal anneal. Instead, results of Fourier transform infrared and X-ray photoemission spectroscopy clearly indicated that defective, amorphous Si-N matrix of films was changed to be well-ordered thanks to high temperature anneal. The measurement of spectral ellipsometry in UV-visible range was carried out and we found that the optical absorption edge of film was shifted to higher energy as the anneal temperature increased as the results of thermal anneal induced formation of $Si_3N_4$-like matrix. These are consistent with the observation that higher visible photoluminescence, which is likely due to the presence of Si-N bonds, from anneals at higher temperature. Based on these films, PV cells were fabricated by the formation of front/back metal electrodes. For all cells, typical I-V characteristic of p-n diode junction was observed. We also tried to measure PV properties using a solar-simulator and confirmed successful operation of PV devices. Carrier transport mechanism depending on anneal temperature and the implication of PV cells based on SRSN films were also discussed.

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Space Physics Sensor on KOMPSAT-1

  • Min, Kyoung-Wook;Choi, Young-Wan;Shin, Young-Hoon;Lee, Jae-Jin;Lee, Dae-Hee;Kim, Jhoon
    • Proceedings of the KSRS Conference
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    • 1998.09a
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    • pp.355-360
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    • 1998
  • A small package of plasma instruments, Space Physics Sensor, will monitor the space environment and its effects on microelectronics in the low altitude region as it operates on board the KOMPSAT-1 from 1999 over the maximum of the solar cycle 23. The Space Physics Sensor (SPS) consists of two parts: the Ionospheric Measurement Sensor (IMS) and the High Energy Particle Detector (HEPD). IMS will make in situ Measurements of the thermal electron density and temperature, and is expected to provide a global map of the thermal electron characteristics and the variability according to the solar and geomagnetic activity in the high altitude ionosphere of the KOMPSAT-t orbit. HEPD will measure the fluxes of high energy protons and electrons, monitor the single event upsets caused by these energetic charged particles, and give the information of the total radiation dose received by the spacecraft. The continuous operation of these sensors, along with the ground measurements such as incoherent scatter radars, digital ionosondes and other spacecraft measurements, will enhance our understanding of this important region of practical use for the low earth orbit satellites.

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Study on Thermal Efficiency according to Configuration Change and Contact Resistance of Solar Collector with Single Evacuated Tube-type (단일진공관 태양열집열기의 형상변화 및 접촉저항에 따른 집열효율 연구)

  • Choi, Bo-Won;Yang, Young-Joon
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.189-195
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    • 2014
  • The use of solar energy among renewable energy tends to increase because of its infinity and cleanness of resources. Even though the consumption rate of solar energy in our country is still low, however, in recent years, the research for solar energy have been widely conducted due to policy support of government. This study was performed to investigate the efficiency of heat collection using solar collector with single evacuated tube-type. As the results, the temperature of radiation fin for solar collector with single evacuated tube-type was lower in spite of high temperature of heat pipe compared that of double evacuated tube-type. In order to increase the efficiency of heat collection, it was confirmed that the loss of heat collection due to contact resistance as well as performance improvement for solar collector should be decreased.

Evaluation of the Outdoor Radiant Thermal Environment by Building Scale and Block Type of Office Building in Summer (사무소건물의 규모 및 배치유형에 따른 하기 옥외 복사열환경 평가)

  • Park, Su-Jin;Jung, Sun-Young;Yoon, Seong-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.29 no.6
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    • pp.81-87
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    • 2009
  • The purpose of this study is to evaluate of the outdoor thermal environment by building scale and block type as variable factors. In this study, 18 cases of office in central business district that have different condition are compared about their surface temperature, HIP(Heat Island Potential), and MRT(Mean Radiant Temperature). They are simulated with 3-dimension numerical simulation software named Hoyano-model. The output results contain visualized distribution chart and numerical data. The results of evaluation are as follows. (1)The surface temperature of the building becomes higher as building coverage ratio is higher but floor area ratio is lower. In same conditions, unified block type is maximum $3.2^{\circ}C$ higher than divided block type. (2)HIP shows different daily pattern as block type. During daytime, divided block type is much higher than unified block type but after sunset, it is changed. (3)MRT shows different distribution pattern as sunlight moves expecially at noon. (4)As the results of this study, cases that have high floor area ratio condition show lower surface temperature by tendency to stay low indoor temperature in office building and big rate of windows on building surface.

Intermediate band solar cells with ZnTe:Cr thin films grown on p-Si substrate by pulsed laser deposition

  • Lee, Kyoung Su;Oh, Gyujin;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.247.1-247.1
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    • 2016
  • Low-cost, high efficiency solar cells are tremendous interests for the realization of a renewable and clean energy source. ZnTe based solar cells have a possibility of high efficiency with formation of an intermediated energy band structure by impurity doping. In this work, ZnO/ZnTe:Cr and ZnO/i-ZnTe structures were fabricated by pulsed laser deposition (PLD) technique. A pulsed (10 Hz) Nd:YAG laser operating at a wavelength of 266 nm was used to produce a plasma plume from an ablated a ZnTe target, whose density of laser energy was 10 J/cm2. The base pressure of the chamber was kept at approximately $4{\times}10-7Torr$. ZnTe:Cr and i-ZnTe thin films with thickness of 210 nm were grown on p-Si substrate, respectively, and then ZnO thin films with thickness of 150 nm were grown on ZnTe:Cr layer under oxygen partial pressure of 3 mTorr. Growth temperature of all the films was set to $250^{\circ}C$. For fabricating ZnO/i-ZnTe and ZnO/ZnTe:Cr solar cells, indium metal and Ti/Au grid patterns were deposited on back and front side of the solar cells by using thermal evaporator, respectively. From the fabricated ZnO/ZnTe:Cr and ZnO/i-ZnTe solar cell, dark currents were measured by using Keithley 2600. Solar cell parameters were obtained under Air Mass 1.5 Global solar simulator with an irradiation intensity of 100 mW/cm2, and then the photoelectric conversion efficiency values of ZnO/ZnTe:Cr and ZnO/i-ZnTe solar cells were measured at 1.5 % and 0.3 %, respectively.

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A study on the n-CdS/p-InP solar cells (n-CdS/p-InP 태양전지에 관한 연구)

  • 송복식;최영복;한성준;문동찬;김선태
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.406-412
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    • 1995
  • A n-CdS thin films were evaporated by thermal evaporation method and their structure, optical transmission spectra and electrical characteristics were investigated. The photovoltaic characteristics of solar cells which were fabricated in optimum conditions measured. The evaporated CdS thin films showed in hexagonal structure and above 80% of optical transmission spectra regardless of impurity doping. The high quality thin films could be obtained at 150.deg. C temperature of substrate, which is useful for solar cell window layer with low resistivity of 6*10$\^$-2/(.ohm.-cm) by In doping We measured the electrical and optical characteristics of the n-CdS/p-InP heterojunction solar cells. The most efficient photovoltaic characteristics of heterojunction solar cells had the open circuit voltage of 0.66V, short circuit current density of 13.85mA/cm$\^$2/, fill factor of 0.576 and conversion efficiency of 8.78% under 60mW/cm$\^$2/ illumination.

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Estimation of Heat Transfer Characteristics for a Solar Chemical Reactor (고온 태양열 화학반응기 열전달 성능 평가)

  • Kang, Kyung-Mun;Lee, Ju-Han;Cho, Hyun-Suk;Seo, Tae-Beom
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2221-2226
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    • 2008
  • The objective of this paper is to describe the experimental and numerical investigation of the analysis of the heat transfer in a solar chemical reactor. These are compared about methane steam reforming process in the solar chemical reactor which was a volumetric absorber consisting of honeycomb and a multilayered catalyst supports. With this high operating temperature, convective heat loss, thermal fracture are important features for designing SCR. In order to estimate the system performance and to design the actual solar reactor with various conditions, CFD analysis was used in this study. The nickel oxide porous metal is inserted inside the solar chemical reactor to increase the conversion rate of the reforming reaction. Simulation has been carried out based on the experimental data. According to the simulation results, the optimum methane-steam mole ratio and thickness and numbers of catalyst supports were obtained.

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Impact of Solution-Processed BCP Buffer Layer on Efficient Perovskite Solar Cells (페로브스카이트 태양전지에서의 저온 용액 공정의 BCP 버퍼층 효과)

  • Jung, Minsu;Choi, In Woo;Kim, Dong Suk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.34 no.1
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    • pp.73-77
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    • 2021
  • Inorganic-organic hybrid perovskite solar cells have demonstrated considerable improvements, reaching 25.5% of certified power conversion efficiency in 2020 from 3.8% in 2009. In normal structured perovskite solar cells, TiO2 electron-transporting materials require heat treatment process at a high temperature over 450℃ to induce crystallinity. Inverted perovskite solar cells have also been studied to exclude the additional thermal process by using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as a non-oxide electron-transporting layer. However, the drawback of the PCBM layer is a charge accumulation at the interface between PCBM and a metal electrode. The impact of bathocuproin (BCP) buffer layer on photovoltaic performance has been investigated herein to solve the problem of PCBM. 2-mM BCP-modified perovskite solar cells were observed to exhibit a maximum efficiency of 12.03% compared with BCP-free counterparts (5.82%) due to the suppression of the charge accumulation at the PCBM-Au interface and the resulting reduction of the charge recombination between perovskite and the PCBM layer.

A comparing on the use of Centrifugal Turbine and Tesla Turbine in an application of Organic Rankine Cycle

  • Thawichsri, Kosart;nilnont, Wanich
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.58-66
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    • 2015
  • This paper aims to compare the use of Centrifugal Turbine and Tesla Turbine in an application of Organic Rankine Cycle (ORC) Machine using Isopentane as working fluid expanding. The working fluid has boiling point below boiling water and works in low-temperature sources between $80-120^{\circ}C$ which can be produced from waste heat, solar-thermal energy and geothermal energy etc. The experiment on ORC machine reveals that the suitability of high pressure pump for working fluid has result on the efficiency of work. In addition, Thermodynamics theory on P-h diagram also presented the effect of heat sources' temperature and flow rate on any work. Thus, the study and design on ORC machine has to concern mainly on pressure pump, flow rate and optimized temperature. Result experiment and calculate ORC Machine using centrifugal Turbine efficiency better than Tesla turbine 30% but Tesla Turbine is cheaper and easily structure. Further study on the machine can be developed throughout the county due to its low cost and efficiency.

Bendable Photoelectrodes by Blending of Polymers with $TiO_2$ For Low Temperature Dye-sensitized Solar Cells

  • Yu, Gi-Cheon;;Lee, Do-Gwon;Kim, Gyeong-Gon;Go, Min-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.319-319
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    • 2010
  • Dye-sensitized solar cells (DSSCs) based on plastic substrates have attracted much attention mainly due to extensive applications such as ubiquitous powers, as well as the practical reasons such as light weight, flexibility and roll-to-roll process. However, conventional high temperature fabrication technology for glass based DSSCs, cannot be applied to flexible devices because polymer substrates cannot withstand the heat more than $150^{\circ}C$. Therefore, low temperature fabrication process, without using a polymer binder or thermal sintering, was required to fabricate necked $TiO_2$. In this presentation, we proposed polymer-inorganic composite photoelectrode, which can be fabricated at low temperature. The concept of composite electrode takes an advantage of utilizing elastic properties of polymers, such as good impact strength. As an elastic material, poly(methyl methacrylate) (PMMA) is selected because of its optical transparency and good adhesive properties. In this work, a polymer-inorganic composite electrode was constructed on FTO/glass substrate under low temperature sintering condition, from the mixture of PMMA and $TiO_2$ colloidal solution. The effect of PMMA composition on the photovoltaic property was investigated. Then, the enhanced mechanical stability of this composite electrode on ITO/PEN substrate was also demonstrated from bending test.

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