• 한국수소및신에너지학회논문집
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• 제23권1호
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• pp.83-92
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• 2012

Syngas combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using simulated syngas and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction conditions and no NO emission at oxidation conditions. Moreover, OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration with temperature. However, fuel conversion and $CO_2$ selectivity increased and CO emission decreased as pressure and gas residence time increased.

• 한국수소및신에너지학회논문집
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• 제22권6호
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• pp.878-883
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• 2011

Effect of flow uniformity on the reaction characteristics of a catalytic combustor for high temperature fuel cell system has been experimentally investigated in the present study. One of the most important factor in designing catalytic combustion is to avoid hot spot in catalysts. In this regard, it is very important to secure flow uniformity of combustor inlet. A couple of perforated plates were applied at the front of catalyst region as flow uniformity device with minimal pressure drop. Results show that the velocity and temperature profile became more uniform when applying the flow uniformity device. CO and $CH_4$ emissions at the combustor exit were decreased and the average exit temperature was slightly increased with the flow uniformity device.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.78-79
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• 2008

In this paper, poly 3C-SiC thin films were grown on $SiO_2$/Si by atmospheric pressure chemical vapor deposition (APCVD) using HMDS, $H_2$, and Ar gas at $1100^{\circ}C$ for 30 min, respectively. And then, palladium films were deposited on poly 3C-SiC by RF magnetron sputter. Thickness, uniformity, and quality of these samples were performed by SEM. Crystallinity and preferred orientationsof palladium were analyzed by XRD. And Pd/poly 3C-SiC schottky diodes were fabricated and characterized by current-voltage measurements. Its electric current density Js and barrier height voltage were measured as $2\times10^{-3}$ A/$cm^2$, 0.58 eV, respectively. And these devices operated about $350^{\circ}C$. From results, Pd/poly 3C-SiC devices are promising for high temperature hydrogen sensor and applications.

• 한국수소및신에너지학회논문집
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• 제26권5호
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• pp.499-506
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• 2015

Recently the Korean government announced its decision to select the $3^{rd}$ proposal, which targets reducing $CO_2$ by 37% of the BAU level by 2030, for the Intended Nationally Determined Contribution (INDC). According to this proposal, natural gas (or equivalent gas) combined cycle (NGCC) are suggested as alternatives for conventional pulverized coal (PC). In this study, we analyzed the environmental, economic, and energy mixing aspects of synthetic natural gas combined cycle(SNGCC) using NETL material (2011~2012 version) and other domestic materials (2014 version). We found the following conclusions: 1) Considering carbon capture and storage (CCS) integration, $CO_2$ emission factors of SNGCC and supercritical PC are the same. However, 60% of $CO_2$ from SNGCC is produced as high pressure and high purity (99%) gas, making it highly suitable for CCS, which is now strongly supported by the government. 2) Based on the economic analysis for SNGCC using domestic materials and comparison with NGCC, it was found that the settlement price of SNGCC was 30% lower than that of NGCC.

• 한국기계가공학회지
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• 제17권6호
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• pp.158-163
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• 2018

Major producers have already built compressors since World War I and have been monopolizing all domestic and overseas markets based on the accumulated technology, and the dependency of the manufacturers over the entire industry is deepening. Therefore, it is expected that the technological gap with developed countries will be larger without development of the related technology. Therefore, it is necessary to develop a unique technology for a new type of high efficiency compression system. In this study, we present localization of Hydraulic Compressor which can meet the technical trends such as cost reduction, efficiency improvement, environmental friendliness, wide operating range, low capacity / high capacity compatibility, size reduction, easy operation and easy maintenance.

• Carbon letters
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• 제1권2호
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• pp.53-59
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• 2000

The synthetic methods for high yield of multiwalled carbon nanotube (MWNT) and singlewalled carbon nanotube (SWNT) with high purity by arc discharge have been investigated. MWNTs were synthesized under different pressures of helium and the gas mixture of argon and hydrogen. Relatively high pressure of 300-400 torr was required for high yield MWNTs synthesis at low bias voltage of about 20 V and 55 A, whereas low pressure of about 100 torr was required for SWNTs. The introduction of hydrogen gases during the synthesis of MWNTs improved the yield and purity of the samples. The SWNTs were synthesized by the assistance of a small amount of mixture of transition metals, which played as a catalyst during the formation process. The purity and yield of SWNTs were higher at a lower pressure and enhanced by mixing more components of the transition metals.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.685-693
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• 2011

에너지기후시대에 신에너지원 발굴, 저탄소 녹색성장의 일환으로 석탄 IGCC기술이 개발 중에 있다. 본 연구는 IGCC기술 중 가스화기에서 생산된 합성가스를 가스터빈에 직접 주입시 생길 수 있는 문제점을 미리 파악하고, 그 연소특성자료를 축적하기 위해 수행되었다. GE7EA연소기를 대상으로한 상압 및 고압연소실험을 통해 합성가스의 기본적인 연소특성을 파악하였으며, 수소화염이 과다한 NOx발생의 원인임을 파악하고, 질소희석을 통해 NOx배출량을 제어할 수 있음을 확인하였으며, 연소진동은 크게 발생치 않음을 확인하였다. 본 연구를 통해 축적된 시험 데이터는 2015년에 국내 최초로 준공예정인 태안 IGCC플랜트에 연소진단시스템 및 최적화 기술적용시 활용된 예정이다.

• 한국수소및신에너지학회논문집
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• 제26권3호
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• pp.287-293
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• 2015

The current study has investigated the effects of biodiesel blended with gasoline on the spray characteristics in a Constant Volume Combustion Chamber (CVCC). With the concentration of 5, 10, 15 and 20% by volume, biodiesel was blended with commercial gasoline and performed on the macroscopic visualization test. Pure gasoline and biodiesel were also tested as the reference. The shadowgraph technique was conducted in the constant volume chamber. The spray images were recorded by a high speed video camera with frame speed 10,000 frame per second. Fuel injection was set at 800, 1000 and 1,350 bar with the simulated speed 1,500 and 2,000 rpm. The back pressure was controlled at 20 bar. The spray angle and penetration tip were measured and analyzed by using the image processing. At the high injection pressure, the spray penetration length with the simulated speed 1,500 rpm showed that B100 was lower than GB00-20 whereas the spray penetration length with the simulated speed 2,000 rpm exhibited that GB blends and B100 were insignificantly different. Due to biodiesel concentration, its effects on spray angles were observed throughout injection periods (T1, T2 and T3). At the simulated speed 1,500 rpm, the spray angle of GB blends and B100 presented the same pattern following injection timing. In addition, when the simulated speed increased to 2,000 rpm the different spray angle of all blends disappeared at main injection (T3).

• 한국수소및신에너지학회논문집
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• 제23권4호
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• pp.346-352
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• 2012

The properties of methane oxidation were studied in this research over transition metal containing $CeO_2$ (TM/$CeO_2$, TM=Ni, Co, Cu, Fe) with TM content of 5 wt. % at atmospheric pressure. The characteristics of catalysts were investigated by various characterization techniques, including XRD, GC, SEM and EPMA analyses. The catalytic tests were carried out in a fixed Rmix ratio of 1.5 ($CH_4/O_2$) in a fixed-bed reactor operating isothermally at atmospheric pressure. Only the Ni/$CeO_2$ catalysts showed syngas production above $400^{\circ}C$ via typical partial oxidation reaction whereas other catalysts induced complete oxidation resulting in the production of $CO_2$ and $H_2O$ in whole reaction temperature range. From the quantitative analysis on carbon deposition after catalytic tests, Cu/$CeO_2$ was found to show the highest resistance on carbon deposition. Therefore Cu can be proposed as an efficient catalyst element which can be combined with a conventional Ni-based SOFC anode to enhance the carbon tolerance.

• 한국재료학회지
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• 제28권11호
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• pp.653-658
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• 2018

$ZrO_2$ is a candidate material for hip and knee joint replacements because of its excellent combination of biocompatibility, corrosion resistance and low density. However, the drawback of pure $ZrO_2$ is a low fracture toughness at room temperature. One of the most obvious tactics to cope with this problem is to fabricate a nanostructured composite material. Nanomaterials can be produced with improved mechanical properties(hardness and fracture toughness). The high-frequency induction heated sintering method takes advantage of simultaneously applying induced current and mechanical pressure during sintering. As a result, nanostructured materials can be achieved within very short time. In this study, W and $ZrO_2$ nanopowders are mechanochemically synthesized from $WO_3$ and Zr powders according to the reaction($WO_3+3/2Zr{\rightarrow}W+3/2ZrO_2$). The milled powders are then sintered using high-frequency induction heating within two minutes under the uniaxial pressure of 80MPa. The average fracture toughness and hardness of the nanostructured W-3/2 $ZrO_2$ composite sintered at $1300^{\circ}C$ are $540kg/mm^2$ and $5MPa{\cdot}m^{1/2}$, respectively. The fracture toughness of the composite is higher than that of monolithic $ZrO_2$. The phase and microstructure of the composite is also investigated by XRD and FE-SEM.