• Title/Summary/Keyword: High-Pressure Environment

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Separation and Recovery of $SF_6$ Gas from $N_2/SF_6$ Gas Mixtures by using a Polymer Hollow Fiber Membranes (고분자 중공사 분리막을 이용한 $N_2/SF_6$ 혼합가스로부터 $SF_6$의 분리 및 회수)

  • Lee, Hyun-Jung;Lee, Min-Woo;Lee, Hyun-Kyung;Lee, Sang-Hyup
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.1
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    • pp.47-53
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    • 2011
  • $SF_6$ (Sulfur hexafluoride) possesses high GWP (Global Warming Potential) as sepcified by the IPCC (Intergonvernmental Panel of Climate Change). Recently, the recovery-separtion of $SF_6$ research area, including permeation properties studies using various membrane's materials and the practical operation of recovery-separtion using membrane of waste $SF_6$ gas is in the initial state. The separation efficiency of a single $SF_6$ and waste $SF_6$ mixture was evaluated using a PSF (polysulfone), PC (tetra-bromo polycarbonate) and PI (polyimide) hollow fiber membranes. According to the results of single gases permeation properties, PI membrane has the highest permselectivity of $N_2$ gas in $N_2/SF_6$ gas. Under the condition of P=0.5 MPa, the highest concentration of recovered $SF_6$ is 95.6 vol % in the separation experiment of $SF_6/N_2$ mixture gas by PC membrane. Under the operation pressure of P=0.3 MPa at a fixed retentate flow rate fixed of 150 cc/min, the maximum recovery efficiency of $SF_6$ is up to 97.8% by PSF membrane. From the results above, it is thought that the separation and recovery technique of $SF_6$ gas using membrane will be used as the representative eco-technology in the $SF_6$ gas treatment in the future.

On the Observation of Sandstorms and Associated Episodes of Airborne Dustfalls in the East Asian Region in 2005 (2005년 동아시아 지역에서 발생한 모래폭풍과 먼지침전(황사)의 관측)

  • Kim, Hak-Sung;Chung, Yong-Seung
    • Journal of the Korean earth science society
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    • v.30 no.2
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    • pp.196-209
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    • 2009
  • Occurrences of sandstorms in the deserts and loess of Mongolia and northern China and associated dustfall episodes in the Korean Peninsula were monitored during the period January through December, 2005. False colour images were made by directly receiving the NOAA Advanced Very High Resolution Radiometer (AVHRR) data, and the distribution and transport of sandstorms were analyzed. The ground concentrations for PM10, PM2.5 and visibility of the dustfall episodes (PM10 concentration over $190{\mu}g\;m^{-3}$) were analyzed at Cheongwon, located midway in South Korea, and in the leeward direction of the place of origin of the sandstorms. Variations in the concentrations of $O_3,\;NO_2$, CO and $SO_2$ were also compared with dust concentrations in the dustfall episodes. Fewer occurrences of strong sandstorms in the place of origin were observed in 2005, due largely to the accumulation of snow and mild fluctuations of high and low pressure systems in the place of origin, thereby accounting for a low frequency of dustfall episodes in Korea, compared with those during the period 1997-2005. A total of 7 dustfall episodes were monitored in Korea in 2005 that lasted 11 days. In summer, sandstorms occurred less frequently in the source region in 2005 due to high humidity and milder winds, thereby causing no dustfall episodes in Korea. In case the sandstorms occurring at the place of source head directly to Korea without passing through large cities and industrial areas of China, the PM2.5 concentrations were measured at 20% or lower than the PM10 concentrations. However, when the sandstorms headed to Korea via the industrial areas of eastern China, where they pick up anthropogenic air pollutants, the PM2.5 concentrations were at least 25% higher of the PM10 concentrations. On the other hand, over 5 cases were observed and analyzed in 2005 where the PM10 concentrations of sand dust originating from the deserts were measured at $190{\mu}g\;m^{-3}$ or lower, falling short of the level of a dustfall episode.

Hydrothermal Alteration and Mineralogy of Alunite and Kaolinite in the Ogmae Deposit, Southwest Jeonnam (전남(全南) 옥매산광상(玉埋山鑛床)의 열수변질작용(熱水變質作用) 및 광석광물(鑛石鑛物)에 대한 광물학적(鑛物學的) 연구)

  • Kim, Young Hee;Moon, Hi-Soo;Kim, Jong Hwan;You, Jang Han;Kim, In Joon
    • Economic and Environmental Geology
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    • v.23 no.3
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    • pp.287-308
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    • 1990
  • The Ogmae alunite-kaolinite deposit occurs in acidic tuff, the Hwangsan Tuff, of upper Crataceous age in the Haenam volcanic field, SW Jeonnam. This deposit characterized by advanced argillic alteration formed $71.8{\pm}2.8{\sim}73.9{\pm}2.8$ Ma ago in very shallow depth environment with acid-sulfate solution. Wallrock alteration can be classified into four zones from the center to the margin of the deposit: alunite, kaolinite, illite, and silicified zone. The mineral assemblage in the alunite zone, ore zone, is alunite-quartz-pyritekaolinite. Consideration of stability relation of these minerals suggests that the maximum alteration temperature is estimated at about $250^{\circ}C$ with solution pH of 3 or below assuming that pressure does not exceed 0.3 Kb. Alunite occurs as two different types; replacement and vein-type deposit. The former one consists of fine grained alunite and the later one coarse grained and relatively pure alunite that formed by open space filling. Isomorphous substitution of Na for K in these two types of alunites range 0 to 40 %, indicating that Na/K ratio in the solution is spontaneously changed during the alteration process. Alunite which has higher Na substitution probably formed in an earlier stage while the solution sustain high Na/K ratio. K-Ar age of alunites indicate that the replacement alunite formed earlier($73.9{\pm}2.8Ma$) than the vein-type alunite($71.8{\pm}2.8Ma$). The ${\delta}^{34}S$ value of pyrite and alunite indicate that those minerals formed at isotopically nonequillibrium state. The ${\delta}^{16}O$ and ${\delta}D$ values, of kaolintics 5.0 to 9.0‰ and -54 to -99‰, respectively, indicate that those are formed by hydrothermal solution having magmatic origin which have been diluted by low ${\delta}D$ meteoric water.

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Atmospheric Pressure Plasma Treatment of Aqueous Bisphenol A Solution (비스페놀 A 수용액의 대기압 플라즈마 처리)

  • Jo, Jin-Oh;Choi, Kyeong Yun;Gim, Suji;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.311-318
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    • 2015
  • This work investigated the plasma treatment of aqueous bisphenol A (BPA) solution and mineralization pathways. For the effective contact between plasmatic gas and aqueous BPA solution, the plasma was created inside a porous ceramic tube, which was uniformly dispersed into the aqueous solution through micro-pores of the ceramic tube. Effects of the gas flow rate, applied voltage and treatment time on the decomposition of BPA were examined, and analyses using ultraviolet (UV) spectroscopy, ion chromatography and gas chromatography-mass spectrometry were also performed to elucidate mineralization mechanisms. The appropriate gas flow rate was around $1.0L\;min^{-1}$; when the gas flow rate was too high or too low, the BPA decomposition performance at a given electric power decreased. The increase in the voltage improves the BPA decomposition due to the increased electric power, but the energy required to remove BPA was similar, regardless of the voltage. Under the condition of $1.0L\;min^{-1}$ and 20.8 kV, BPA at an initial concentration of $10L\;min^{-1}$ (volume : 1 L) was successfully treated within 30 min. The intermediates produced by the attack of ozone and hydroxyl radicals on BPA were further oxidized to stable compounds such as acetate, formate and oxalate.

Evaluation of microbiological, cellular and risk factors associated with subclinical mastitis in female buffaloes

  • de Oliveira Moura, Emmanuella;do Nascimento Rangel, Adriano Henrique;de Melo, Maria Celeste Nunes;Borba, Luiz Henrique Fernandes;de Lima, Dorgival Morais Junior;Novaes, Luciano Patto;Urbano, Stela Antas;de Andrade Neto, Julio Cesar
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.9
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    • pp.1340-1349
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    • 2017
  • Objective: This study aimed to evaluate the microbiological and cellular milk profile for the diagnosis of subclinical mastitis in female buffaloes and to assess risk factors for predisposition of the disease. Methods: Analyses were carried out by standard plate count (SPC), identification of species and antibiotic resistance, somatic cell count (SCC), electrical electrical conductivity of milk (ECM), and lactoferrin content in milk. Teat cups were swabbed to evaluate risk factors, observing hyperkeratosis, milking vacuum pressure and cleanliness of the site. Hence, 30 female buffaloes were randomly selected (15 from a group in early lactation and 15 in late lactation). Results: The most common bacteria in the microbiological examination were Staphylococcus spp., Streptococcus spp. and Corynebacterium sp. In the antibiotic sensitivity test, 10 (58.82%) of the 17 antibiotics tested were sensitive to all isolates, and resistant bacteria were Streptococcus uberis, Streptococcus dysgalactiae, Streptococcus haemolyticus, and Escherichia coli. It was observed that positive samples in the microbiological examination showed total bacterial count between $9.10{\times}10^3$ to $6.94{\times}10^6$ colony forming units/mL, SCC between 42,000 to 4,320,000 cells/mL and ECM ranging from 1.85 to 7.40 mS/cm. It was also found that the teat cups had high microbial counts indicating poor hygiene, and even faults in the cleanliness of the animals' waiting room were observed. It is concluded that values of SCC above 537,000 cells/mL and ECM above 3.0 mS/mL are indications of mammary gland infection for this herd; however, the association of these values with a microbiological analysis is necessary to more accurately evaluate the health status of mammary glands with subclinical mastitis. Conclusion: Through phenotypic characterization of bacteria involved in the samples, the genera Staphylococcus spp., Streptococcus spp., and Corynebacterimum bovis were the most prevalent in this study. Faults in environment and equipment hygienization are factors that are directly associated with mastitis.

An Experimental Study of the Fuel Additive to Improve the Performance of a 2-Stroke Large Diesel Engine (2행정 대형 디젤엔진의 성능향상을 위한 연료첨가제의 실험적 연구)

  • Ryu, Younghyun;Lee, Youngseo;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.6
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    • pp.620-625
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    • 2015
  • In an effort to reduce the onset of global warming, the International Maritime Organization Marine Environment Protection Committee (IMO MEPC) proposed the reduction in ship speeds as a way of lowering the proportion of carbon dioxide ($CO_2$) in the Green House Gas emissions from ships. To minimize fuel costs, shipping companies have already been performing slow steaming for their own fleets. Specifically, the slow steaming approach has been adopted for most ocean-going container lines. In addition, because of the increased marine fuel cost that is required to enable increased capacity, there is an urgent need for more advanced fuel-saving technologies. Therefore, in this present study, we propose a fuel-cost reduction method that can improve the performance of diesel engines. We introduce a predetermined amount (0.025% of the amount of fuel used) of fuel additive (oil-soluble calcium-based organometallic compound). For improved experimental accuracy, as the test subjects, we utilize a large two-stroke diesel engine installed in land plants. The loads of the test engine were classified as low, medium, and high (50, 75, and 100%, respectively). We compare the engine performance parameters (power output, fuel consumption rate, p-max, and exhaust temperature) before and after the addition of fuel additives. Our experimental results, confirmed that we can realize fuel-cost savings of at least 2% by adding the fuel additive in low load conditions (50%). Likewise, the maximum combustion pressure was found to have increased. On the other hand, we observed that there was a reduction in the exhaust temperature.

Delamination Evaluation of Thermal Barrier Coating on Turbine Blade owing to Isothermal Degradation Using Ultrasonic C-scan Image (초음파 C-scan을 이용한 터빈 블레이드 열차폐코팅의 등온열화에 의한 박리 평가 기법)

  • Lee, Ho-Girl;Kim, Hak-Joon;Song, Sung-Jin;Seok, Chang-Sung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.5
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    • pp.353-362
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    • 2016
  • Thermal barrier coating (TBC) is an essential element consisting of a super-alloy base and ceramic coating designed to achieve long operational time under a high temperature and pressure environment. However, the top coat of TBC can be delaminated at certain temperatures with long operation time. As the delamination of TBC is directly related to the blade damage, the coupling status of the TBC should be assured for reliable operation. Conventional studies of nondestructive evaluation have been made for detecting generation of thermally grown oxide (TGO) or qualitatively evaluating delamination in TBC. In this study, the ultrasonic C-scan method was developed to obtain the damage map inside TBC by estimating the delamination in a quantitative way. All specimens were isothermally degraded at $1,100^{\circ}C$ with different time, having different partial delamination area. To detect partial delamination in TBC, the C-scan was performed by a single transducer using pulse-echo method with normal incidence. Partial delamination coefficients of 1 mm to 6 mm were derived by the proportion of the surface reflection signal and flaw signal which were theoretical signals using Rogers-Van Buren and Kim's equations. Using the partial delamination coefficients, the partial delamination maps were obtained. Regardless of the partial delamination coefficient, partial delamination area was increased when degradation time was increased in TBC. In addition, a decrease in partial delamination area in each TBC specimen was observed when the partial delamination coefficient was increased. From the portion of the partial delamination maps, the criterion for delamination was derived.

A Study on the characteristic analysis and optimization according to Ballast design of Induction Lamp (고출력 무전극램프의 점등회로 설계를 통한 특성분석 및 최적화에 관한 연구)

  • Chung, Young-Il;Jung, Dae-Chul;Park, Dae-Hee;Kim, Yong-Kab
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.10 no.1
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    • pp.31-37
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    • 2017
  • In this paper, we implemented for the development of a high output induction lamp system, which lamp design is optimized by gas type, mixing ratio, pressure and discharge tube size, amalgam type and mixing ratio, and characteristics of ferrite core in the lamp. It's the circuit design by improving the power factor and efficiency according to the driving method, which has analyzing the characteristics according to the waveform and frequency. Finally, luminaries design part for applying the optimal lighting system considering the surrounding environment, the characteristics of the lighting circuit for electrodeless lamp has analyzed and the improvement has been proceeded. In conclusion, the driving frequency has optimized at 135kHz with degrading $7{\sim}10^{\circ}C$ based on the results of the optical characteristics of the induction lamp on peak noise FET(Q3,Q4) damage.

A Study on the Metamorphism of Gneisses in the Northern Gohung Area, Chonnam (전라남도 고흥 북부지역에 분포하는 편마암류의 변성작용에 관한 연구)

  • Shin, Sang-Eun;Cho, Kye-Bok;Park, Bae-Young
    • Journal of the Korean earth science society
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    • v.25 no.6
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    • pp.443-473
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    • 2004
  • In northern Gohung granitic gneiss, porphyroblastic gneiss and migmatitic gneiss are widely distributed. Gneisses were plotted in granodiorite domain on an lUGS silica-alkali diagram. The amounts of trace elements (Li, Zn, Sc, Sr, Ni, V Y etc.) vs. $SiO_2$, somewhat decreased. Plagioclase showed a wide compositional range ($An_{32-48}$). $X_{alm}$ and $X_{sps}$ were higher in garnet rim and $X_{pyp}$ in garnet core. The rocks in the study area were formed from S and I-type magmas which generated from syn-collision and the late to post-orogenic tectonic environment. Metamorphic P-T conditions u·ere low to medium pressure, high temperature (803-913$^{\circ}C$, 6.1-7.3 kb) and overprinted by retrograde metamorphism (570-726$^{\circ}C$, 2.2-5.1 kb) and chloritization.

A Study on the Combustion Flow Characteristics of a Exhaust Gas Recirculation Burner with the Change of Outlet Opening Position (배기가스 재순환 버너에서 연소가스 출구 위치에 따른 연소 유동 특성에 관한 연구)

  • Ha, Ji-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.8-13
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    • 2018
  • Nitrogen oxides (NOx) have recently been very influential in the generation of ultrafine dust, which is of great social interest in terms of improving the atmospheric environment. Nitrogen oxides are generated mainly by the reaction of nitrogen and oxygen in air in a combustion gas atmosphere of high temperature in a combustion apparatus such as thermal power generation. Recently, research has been conducted on the combustion that recirculates the exhaust gas to the cylindrical burner by using a piping using a Coanda nozzle. In this study, three types of burners were carried out through computational fluid analysis. Case 1 burner with the outlet of the combustion gas to the right, Case 2 burner with both sides as gas exit, Case 3 burner with left side gas exit. The pressure, flow, temperature, combustion reaction rate and distribution characteristics of nitrogen oxides were compared and analyzed. The combustion reaction occurred in Case 1 and Case 2 burner in the right direction with combustion gas recirculation inlet and Case 3 burner in the vicinity of mixed gas inlet. The temperature at the outlet was about $100^{\circ}C$ lower than that of the other burners as the Case 2 burner was exhausted to both sides. The NOx concentration of Case 1 burner at the exit was about 20 times larger than that of the other burners. From the present study, it could be seen that it is effective for the NOx reduction to exhaust the exhaust gas to both side gas exits or to exhaust the exhaust gas to the opposite direction of inlet of recirculation gas.