• Title/Summary/Keyword: High temperature environments

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Investigation on Mechanical Property and Adhesion of Oxide Films Formed on Ni and Ni-Co Alloy in Room and High Temperature Environments

  • Oka, Yoshinori I.;Watanabe, Hisanobu
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.145-151
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    • 2008
  • Material degradation such as high temperature oxidation of metallic material is a severe problem in energy generation systems or manufacturing industries. The metallic materials are oxidized to form oxide films in high temperature environments. The oxide films act as diffusion barriers of oxygen and metal ions and thereafter decrease oxidation rates of metals. The metal oxidation is, however, accelerated by mechanical fracture and spalling of the oxide films caused by thermal stresses by repetition of temperature change, vibration and by the impact of solid particles. It is therefore very important to investigate mechanical properties and adhesion of oxide films in high temperature environments, as well as the properties in a room temperature environment. The oxidation tests were conducted for Ni and Ni-Co alloy under high temperature corrosive environments. The hardness distributions against the indentation depth from the top surface were examined at room temperature. Dynamic indentation tests were performed on Ni oxide films formed on Ni surfaces at room and high temperature to observe fractures or cracks generated around impact craters. As a result, it was found that the mechanical property as hardness of the oxide films were different between Ni and Ni-Co alloy, and between room and high temperatures, and that the adhesion of Ni oxide films was relatively stronger than that of Co oxide films.

Evaluation of thermal characteristics by cutting environments in high speed ball end-milling (볼엔드밀을 이용한 고속가공에서 가공환경 변화에 따른 열특성 평가)

  • 이채문
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2000.04a
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    • pp.34-38
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    • 2000
  • The trend of cutting process today goes toward higher precision and higher efficiency. Many thermal/frictional troubles occur in high-speed machining of die and mold steels.In this paper, the thermal characteristics are evaluated in high sped ball end-milling of hardened steel(HRc42). Experimental work is performed on the effect of cutting environments on tool life and cutting temperature. Cutting environments involve dry, wet(20bar), compressed chilly air at -9$^{\circ}C$, compressed chilly air at -35$^{\circ}C$. The measuring technique of cutting temperature using implanted thermocouple is used. The cutting temperature is about 79$0^{\circ}C$, 35$0^{\circ}C$ and 54$0^{\circ}C$ in dry, wet and compressed chilly air at +9$^{\circ}C$, respectively. The tool life for compressed chilly air at -9$^{\circ}C$ is longer than all other cutting environments in experiment.

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Corrosion of Titanium Alloys in High Temperature Seawater

  • Pang, J.J.;Blackwood, D.J.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.195-199
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    • 2015
  • Materials of choice for offshore structures and the marine industry have been increasingly favoring materials that offer high strength-to-weight ratios. One of the most promising families of light-weight materials is titanium alloys, but these do have two potential Achilles' heels: (i) the passive film may not form or may be unstable in low oxygen environments, leading to rapid corrosion; and (ii) titanium is a strong hydride former, making it vulnerable to hydrogen embrittlement (cracking) at high temperatures in low oxygen environments. Unfortunately, such environments exist at deep sea well-heads; temperatures can exceed $120^{\circ}C$, and oxygen levels can drop below 1 ppm. The present study demonstrates the results of investigations into the corrosion behavior of a range of titanium alloys, including newly developed alloys containing rare earth additions for refined microstructure and added strength, in artificial seawater over the temperature range of $25^{\circ}C$ to $200^{\circ}C$. Tests include potentiodynamic polarization, crevice corrosion, and U-bend stress corrosion cracking.

Characteristics of Heptane Droplet Vaporization in High-Pressure and Temperature Flow Field (고온 고압 유동장에서 햅탄 액적의 기화 특성)

  • Ko, Jung-Bin;Koo, Ja-Ye
    • Journal of ILASS-Korea
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    • v.9 no.4
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    • pp.83-89
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    • 2004
  • Vaporization characteristics of a liquid heptane droplet in high-pressure and temperature flow field are numerically studied. Variable thermodynamic and transport properties and high-pressure effects are taken into account in order to consider real gas effects. Droplet Vaporization in convective environments was investigated on the basis of droplet vaporization in quiescent and convective environment. In quiescent environments, droplet lifetime is directly proportional to pressure at the subcritical temperature range but it is inversely proportional to pressure at the supercritical temperature range. In convective environment, droplet deformation becomes stronger by increasing Reynolds number due to increase of velocity while droplet deformation is relatively weak at a higher pressure for the same Reynolds number cases.

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Development of Two-color Radiation Thermometer for Harsh Environments

  • Mohammed, Mohammed Ali Alshaikh;Kim, Ki-Seong
    • Journal of ILASS-Korea
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    • v.21 no.4
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    • pp.184-194
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    • 2016
  • Many industrial processes require reliable temperature measurements in harsh environments with high temperature, dust, humidity, and pressure. However, commercially-available conventional temperature measurement devices are not suitable for use in such conditions. This study thus proposes a reliable, durable two-color radiation thermometer (RT) for harsh environments that was developed by selecting the appropriate components, designing a suitable mechanical structure, and compensating environmental factors such as absorption by particles and gases. The two-color RT has a simple, compactly-designed probe with a well-structured data acquisition system combined with efficient LabVIEW-based code. As a result, the RT can measure the temperature in real time, ranging from 300 to $900^{\circ}C$ in extremely harsh environments, such as that above the burden zone of a blast furnace. The error in the temperature measurements taken with the proposed two-color RT compared to that obtained using K-type thermocouple readouts was within 6.1 to $1.4^{\circ}C$ at a temperature range from 200 to $700^{\circ}C$. The effects of absorption by gases including $CO_2$, CO and $H_2O$ and the scattering by fine particles were calculated to find the transmittance of the two wavelength bands of operation through the path between the measured burden surface and the two-color probe. This method is applied to determine the transmittance of the short and long wavelength bands to be 0.31 and 0.51, respectively. Accordingly, the signals that were measured were corrected, and the true burden surface temperature was calculated. The proposed two-color RT and the correction method can be applied to measure temperatures in harsh environments where light-absorbing gases and scattering particles exist and optical components can be contaminated.

Effect of 20 % EDTA Aqueous Solution on Defective Tubes (Alloy600) in High Temperature Chemical Cleaning Environments (고온화학세정환경에서 20 % EDTA 용액이 결함 전열관 (Alloy600)에 미치는 영향)

  • Kwon, Hyuk-chul
    • Corrosion Science and Technology
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    • v.15 no.2
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    • pp.84-91
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    • 2016
  • The transport and deposition of corrosion products in pressurized water nuclear reactor (PWR) steam generators have led to corrosion (SCC, denting etc.) problems. Lancing, mechanical cleaning and chemical cleaning have been used to reduce these problems. The methods of lancing and mechanical cleaning have limitations in removing corrosion products due to the structure of steam generator tubes. But high temperature chemical cleaning (HTCC) with EDTA is the most effective method to remove corrosion products regardless of the structure. However, EDTA in chemical cleaning aqueous solution and chemical cleaning environments affects the integrity of materials used in steam generators. The nuclear power plants have to perform the pre-test (also called as qualification test (QT)) that confirms the effect on the integrity of materials after HTCC. This is one of the series studies that assess the effect, and this study determines the effects of 20 % EDTA aqueous solution on defective tubes in high temperature chemical cleaning environments. The depth and magnitude of defects in steam generator (SG) tubes were measured by eddy current test (ECT) signals. Surface analysis and magnitude of defects were performed by using SEM/EDS. Corrosion rate was assessed by weight loss of specimens. The ECT signals (potential and depth %) of defective tubes increased marginally. But the lengths of defects, oxides on the surface and weights of specimens did not change. The average corrosion rate of standard corrosion specimens was negligible. But the surfaces on specimens showed traces of etching. The depth of etching showed a range on the nanometer. After comprehensive evaluation of all the results, it is concluded that 20 % EDTA aqueous solution in high temperature chemical cleaning environments does not have a negative effect on defective tubes.

Corrosion behaviors of 18Cr Stainless Steels in Selective Catalytic Reduction Environments (Selective Catalytic Reduction (SCR) 환경에서 18% 크롬 스테인리스강의 부식 거동)

  • Heesan Kim
    • Corrosion Science and Technology
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    • v.22 no.3
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    • pp.175-186
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    • 2023
  • Effects of high-temperature environment and low-temperature environment on corrosion behaviours of 18Cr stainless steels (type 304L, type 441) in simulated selective catalytic reduction (SCR) environments were studied using weight loss test in each environment and rust analysis. With time to exposure to the high-temperature environment, type 441 was more resistant to corrosion than type 304L due to both higher diffusivity of Cr and lower thermal expansion coefficient in α-iron. The former provides a stable protective Cr2O3 layer. The latter leaded to low residual stress between scale and steel, reducing the spallation of the scale. With time to exposure to the low-temperature environment, on the other hand, type 304L was more resistant to corrosion than type 441. The lower resistance of type 441 was caused by Cr-depleted zone with less than 11% formed during the pre-exposure to a high-temperature environment, unlike type 304L. It was confirmed by results from the crevice corrosion test of sensitised 11Cr steel. Hence, to achieve higher corrosion resistance in simulated SCR environments, ferritic stainless steels having lower thermal expansion coefficient and higher diffusivity of Cr but containing more than 18% Cr are recommended.

High-Temperature-Tolerant Fungus and Oomycetes in Korea, Including Saksenaea longicolla sp. nov.

  • Nam, Bora;Lee, Dong-Jae;Choi, Young-Joon
    • Mycobiology
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    • v.49 no.5
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    • pp.476-490
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    • 2021
  • Global temperatures are steadily increasing, leading to significant changes in microbial diversity and ecology. In the present study, we isolated high-temperature-growing fungi and fungi-like group (Oomycota) strains from freshwater environments of Korea and identified them based on cultural, morphological, and multilocus phylogenetic analyses. As a result, we introduce Saksenaea (Fungi) isolates as a new species, Saksenaea longicolla sp. nov. and record Phytophthora chlamydospora and P. lagoariana (Oomycota) new to Korea. In the growth experiments, they exhibited high-temperature tolerance, which can grow at 35-40 ℃ but become inactive at 4 ℃ and below. This study confirms the presence of high-temperature-tolerant fungi and oomycetes in Korea and suggests that the Korean climate conditions are changing in favor of these species. This indicates that climate warming is altering microbial distributions in freshwater environments.

An Experimental Study on Burning Time and Ignition Delay of Waste Tire Chips in High Temperature Environments (폐타이어 시편의 연소 특성 및 착화지연에 관한 실험적 연구)

  • 정종수;박은성;박종원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.7
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    • pp.1833-1839
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    • 1994
  • Experiments have been carried out to investigate the burning characteristics of waste tires in high temperature environments. The burning of waste tire chips consists of four stages ; evaporation of volatile matters, ignition, burning of volatile matters, and burning of solid carbon. Burning time of waste tire chips depends on the gas temperature and the initial weight of the chip. However, the environments. In the ceramic matrix burner with a ceramic radiation shield, the burning time of the waste tire chips becomes shorter than that without the shield. This is due to the increase in heat transfer to the tire chips by radiation.