• Journal of the Korean Electrochemical Society
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• v.18 no.3
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• pp.95-101
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• 2015

In this article, we report the fabrication of Li-rich oxide nanoparticles for Li-ion batteries. Li-rich oxides are promising cathode materials because their capacity is much higher than commercial cathode materials. However, they have several disadvantages such as low rate capability due to their low ionic and electronic conductivity. This study focuses on the fabrication of nanoparticles to enhance the rate capability of Li-rich oxide. Two types of surfactants were introduced to disperse the particles and form the nano-sized particles. The Li-rich oxide nanoparticles showed improved rate capability than pristine sample.

• Journal of Institute of Control, Robotics and Systems
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• v.5 no.7
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• pp.848-854
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• 1999

In this paper, we designed and implemented a precise pulse motor controller chip that generates the pulse needed to control step motor, DC servo and AC servo motors. This chip generates maximum pulse output rate of 5Mpps and has the quasi-S driving capability and speed and moving distance override capability during driving. We designed this chip with VHDL and executed a logic simulation and synthesis using Synopsys tool. The pre-layout simulation and post-layout simulation was executed by Compass tool. This chip was produced with 100 pins, PQFP package by 0.8${\mu}{\textrm}{m}$ gate array process and implemented by completely digital logic. We developed the test hardware board of performance and the CAMC(Computer Aided Motor Controller) Agent softwate to test the performance of the pulse motor controller chip produced. CAMC Agent enables user to set parameters needed to control motor with easy GUI(Graphic User Interface) environment and to display the output response of motor graphically.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.9
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• pp.265-278
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• 2016

In this study, an ascending capability experiment was performed with largemouth bass and bluegill, which are exotic fish species inhabiting (the freshwaters) in Korea. The experiment was performed by dividing the subject fish into four groups according to their size and at four flow rates for each group. The number of fish passing through a reference line was analyzed by recording videos, and their swimming and ascending capabilities were observed by the naked eye. The number of fish passing through the reference line did not include those returning downstream within five minutes due to the high flow rate. The flow rate used for the analysis was the mean of the flow rate values measured at the left bank, the right bank, and in the middle of the stream. The results showed that the number of exotic fish migrating upstream decreased as the flow rate increased, regardless of the species and size of the fish. The comparison between the fish species showed that the ascending capability of bass was higher than that of bluegill, but the difference was not significant when considering the difference in the size of the fish. In addition, the upper limit flow velocity allowing the ascending of the exotic fish species was 1.11 m/s, when considering the fish returning to the downstream after the upstream migration and experimental error. The results of the experiment may be used as fundamental data for the blocking of fish and the management of exotic fish species by means of a high flow rate current. Further experiments, verification, and monitoring may need to be conducted continuously to determine whether the fish are able to pass through the reference line at a high flow rate, when they attain a high or cruising velocity. Additionally, the reaction of the fish species should be investigated by considering the response to external forces as well as pressure differences due to the flow rate.

• Journal of Electrochemical Science and Technology
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• v.12 no.4
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• pp.377-386
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• 2021

The Li-rich oxides are promising cathode materials due to their high energy density. However, characteristics such as low rate capability, unstable cyclic performance, and rapid capacity fading during cycling prevent their commercialization. These characteristics are mainly attributed to the phase instability of the host structure and undesirable side reactions at the cathode/electrolyte interface. To suppress the phase transition during cycling and interfacial side reactions with the reactive electrolyte, K (potassium) doping and Nb oxide coating were simultaneously introduced to a Li-rich oxide (Li_1.2Ni_0.13Co_0.13Mn_0.54O₂). The capacity and rate capability of the Li-rich oxide were significantly enhanced by K doping. Considering the X-ray diffraction (XRD) analysis, the interslab thickness of LiO₂ increased and cation mixing decreased due to K doping, which facilitated Li migration during cycling and resulted in enhanced capacity and rate capability. The K-doped Li-rich oxide also exhibited considerably improved cyclic performance, probably because the large K⁺ ions disturb the migration of the transition metals causing the phase transition and act as a pillar stabilizing the host structure during cycling. The Nb oxide coating also considerably enhanced the capacity and rate capability of the samples, indicating that the undesirable interfacial layer formed from the side reaction was a major resistance factor that reduced the capacity of the cathode. This result confirms that the introduction of K doping and Nb oxide coating is an effective approach to enhance the electrochemical performance of Li-rich oxides.

• Journal of Electrochemical Science and Technology
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• v.5 no.4
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• pp.109-114
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• 2014

The $Li_3V_2(PO_4)_3$/graphene nano-particles composite was successfully synthesized by a facile sol-gel method. The addition of a graphene in $Li_3V_2(PO_4)_3(LVP)$(LVP) showed the high crystallinity and influenced the morphology of the $Li_3V_2(PO_4)_3$ particles observed in X-ray diffraction (XRD) and scanning electron microscopy (SEM). The LVP/graphene samples were well connected, resulting in fast charge transfer. The effect of the addition graphene nano-particles on electrochemical performance of the materials was investigated. Compared with the pristine LVP, the LVP/graphene composite delivered a higher discharge capacity of $122mAh\;g^{-1}$ at 0.1 C-rate, better rate capability and cyclability in the potential range of 3.0-4.3 V. The electrochemical impedance spectra (EIS) measurement showed the improved electronic conductivity for the LVP/graphene composite, which can ensure the high specific capacity and rate capability.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.1
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• pp.64-70
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• 2006

In this study, the $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ mixed cathode electrodes were prepared and their electrochemical performances were measured in a high cut-off voltage. As the content of $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ increased in a mixed cathode, the reversible specific capacity and cycleability of the electrode enhanced, but the rate capability was deteriorated. On the contrary the rate capability of the cathode enhanced, but the reversible specific capacity and cycleability were deteriorated, increasing the content of $LiCoO_2$ in the mixed cathode. The cell of $LiCoO_2/LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ ($50:50 wt\%$) mixed cathode delivered a discharge capacity of ca. 168 mAh/g at a 0.2 C rate. The capacity of the cell decreased with the current rate and a useful capacity of ca. 152 mAh/g was obtained at a 2.0 C rate. However, the cell showed very stable cycleability: the discharge capacity of the cell after 20th charge/discharge cycling maintains ca. 163 mAh/g.

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3233-3237
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• 2010

A $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ cathode was modified by coating with Li-La-Ti-O, and the effect of the coating thickness on their electrochemical properties was studied. The thickness of the coating on the surface of $Li[Ni_{0.3}Co_{0.4}Mn_{0.3}]O_2$ was increased by increasing the wt % of the coating material. The rate capability of the Li-La-Ti-O-coated electrode was superior to that of the pristine sample. 1- and 2-wt %-coated samples showed considerable improvement in capacity retention at high C rates. However, the rate capability of a 5-wt %-coated sample decreased. All the coated samples showed a high discharge capacity and slightly improved cyclic performance under a high cut-off voltage (4.8 V) condition. Results of a storage test confirmed that the Li-La-Ti-O coating layer was effective in suppressing the dissolution of the transition metals as it offered protection from the attack of the acidic electrolyte. In particular, the 2- and 5-wt %-coated samples showed a better protection effect than the 1-wt %-coated sample.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.39 no.3
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• pp.117-124
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• 2002

A high speed data link capability is one of the critical factors in determining the performance of the spaceborne SAR system with high resolution because of the strict requirement for the real-time data transmission of the massive SAR data in a limited time of mission. In this paper, based on the data link model characterized by the spaceborne small SAR system, the high rate multi-channel data link module is designed including link storage, link processor, transmitter, and wide-angle antenna. The design results are presented with the performance analysis on the data link budget as well as the multi-mode data rate in association with the SAR imaging mode of operation from high resolution to the wide swath. The designed data link module can be effectively used for the spaceborne and airborne applications which requires to expand the high speed data link capability.

• Journal of Power Electronics
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• v.9 no.3
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• pp.410-417
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• 2009

This paper represents a design and implementation of a digital controller for a multi-phase synchronous buck converter (SBC) using a digital signal processor (DSP). The multi-phase SBC has generally been used for a voltage regulation module (VRM) of a microprocessor because of its high current handling capability at a low output voltage. The VRM requires high control performance of tight output regulation, high slew rate, and load sharing capability of multiple converters. In order to achieve these requirements, the design and implementation of a digital control system for a multi-phase SBC are presented in this paper. The digital PWM generation, current sensing, and voltage and current controller using a DSP TMS320F2812 are considered. The experimental results are provided to show the validity of the implemented digital control system.

• Transactions of Materials Processing
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• v.20 no.8
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• pp.595-600
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• 2011

This paper investigates the effect of strain rate on the anisotropic deformation behavior of advanced high strength steel sheets. Uniaxial tensile tests were carried out on TRIP590 and DP780 steel sheets at strain rates ranging from 0.001/sec to 100/sec to determine yield stresses and r-values at various loading angles from the reference rolling direction. R-values were determined by the digital image correlation technique. Hill48 and Yld2000-2d yield functions were tested for their capability to describe the plastic deformation anisotropy of the materials. Initial yield loci were constructed using the Yld2000-2d yield function, which adequately described the anisotropic behavior of the materials. The shape of the initial yield loci was found to change with different strain rate, and the anisotropic behavior decreased with increasing strain rate.