• Mass Spectrometry Letters
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• v.3 no.2
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• pp.29-38
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• 2012

A new approach of volatile compounds analysis is proposed using a linear ion trap Orbitrap mass spectrometer coupled with gas chromatography through an atmospheric pressure photoionization interface. In the proposed GC-HRMS/MS approach, direct chemical composition analysis is made for the precursor ions in high resolution MS spectra and the structural identifications were made through the database search of high quality MS/MS spectra. Successful analysis of a complex perfume sample was demonstrated and compared with GC-EI-Q and GC-EI-TOF. The current approach is complementary to conventional GC-EI-MS analysis and can identify low abundance co-eluting compounds. Toluene co-sprayed as a dopant through API probe significantly enhanced ionization of certain compounds and reduced oxidation during the ionization.

• Journal of the Korean Society of Safety
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• v.33 no.3
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• pp.33-38
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• 2018

Defects in piping caused by corrosion or external impact of underground piping can lead to high risk of rupture of the piping due to high pressure. Flammable gas can be immediately ignited when discharged from piping, causing a jetfire. The damage of the radiant heat not only threatens the health of the workers who work in the industry but also the health of the people living in the neighboring residential areas. It is important to prevent and prepare before an accident occurs. In this study, three types of flammable gas underground piping accident scenarios were investigated, and the ranges of influence were determined using Phast ver7.2. and finally regression models were formulated to predict the ranges using excel and Matlab.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.353-358
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• 2010

High pressure gas is a widely used storage mode for hydrogen fuel. A typical hydrogen tank that is charged with hydrogen gas can function as a hydrogen supply source in a large number of applications. The filling process of a high-pressure hydrogen tank should be reasonably short. However, when the fill time is short, the maximum temperature in the tank increases. Therefore the process should be designed in such a way to avoid high temperatures in the tank because of safety reasons. The paper simulates the fast filling process of hydrogen tanks using Computational Fluid Dynamics method. The local temperature distribution in the tank is obtained. Results obtained are compared with available experimental data. Further work is going on to improve the accuracy of the calculations.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.9
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• pp.973-980
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• 2015

With their wide geographical distribution, unconventional resources are continuously compared against conventional resources, but their development is expanding because TRRs (Technical Recoverable Resources) are similar to conventional resources. In particular, there is active development of unconventional gas resources such as shale gas, tight gas, CBM (coalbed methane) and gas hydrate. However, it is difficult to calculate the material properties of unconventional resources, especially the gas content, with current geophysical logging technology. Additionally, some overseas companies have monopolies on related equipment and materials. Therefore, this study developed a reservoir PCS (Pressure Core Sampler). It can collect core samples without gaseous loss by maintaining high pressure from the moment the core is sampled and record pressure and temperature in real time. Successful performance testing was also carried out for official verification of the manufactured PCS. The reservoir PCS will contribute to the acquisition of geophysical well logging data as well as accurate and reliable cores.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.250.2-250.2
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• 2014

Currently, teeth whitening method which is applicable to dental surgery is that physician expertises give medical treatment to teeth directly dealed with a high concentration of hydrogen peroxide and carbamide peroxide. If hydrogen peroxide concentration is too high for treatment of maximized teeth whitening effect [1], it is harmful to the human body [2]. To the maximum effective and no harmful teeth whitening effect in a short period of time at home, we have observed the whitening effect using carbamide peroxide (15%) and a low-temperature atmospheric pressure plasma jet which is regulated by the Food and Drug Administration. The gas supplied conditions of the non-thermal atmospheric pressure plasma jet was with the humidified (0.6%) gas in nitrogen or air at gas flow rate of 1000 sccm. Also, the measurement of chemical species from the jet was carried out using the optical emission spectroscopy (OES), the evidence of increased reactive oxygen species compared to non-humidified plasma jet. We have found that the whitening effect of the plasma is very excellent through this experiment, when bovine teeth are treated in carbamide peroxide (15%) and water vapor (0.2 to 1%). The brightness of whitening teeth was increased up to 2 times longer in the CIE chromaticity coordinates. The colorimetric spectrometer (CM-3500d) can measure color degree of whitening effect.

• Electrical & Electronic Materials
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• v.8 no.2
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• pp.217-223
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• 1995

In this paper, we investigated physical properties and electrical characteristics of the fluorocarbon that used as coolants for large power gas-insulated transformer. Volume resistivity of the fluorocarbon was .rho.=1.87*10$^{15}$ [.ohm.cm] at 1 atm, 27.deg. C. Dielectric constant was 1.86 and decreases as temperature increase. The breakdown voltage at 1 atm was higher than that of transformer oil. The breakdown voltage of fluorocarbon vapor was about 18kV when pressure in a test chamber increases over lkg/cm$^{2}$. When fluorocarbon was mixed with SF$_{6}$ gas, breakdown voltage of the mixed was higher than that of fluorocarbon. Then fluorocarbon leads to increase over 4kg/cm$^{2}$ in pressure as temperature increase. Therefore, when a gas-insulated transformer is manufactured, the design must be taken into consideration a high-pressure.

• Journal of the Korean Society of Safety
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• v.23 no.5
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• pp.15-21
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• 2008

The bus using compressed natural gas(CNG) trend to be extended in use internationally as optimal counter-plan for reducing discharge gas of light oil due to high concern about environment. But, Composit pressure vessels(CPV) to be equipped with CNG bus is always involved in the point that safety accidents happen due to having compressed natural gas. In this report, we analysis the cause of CPV bursting accident by reviewing design and manufacture factor and suggest preventive measure through this case.

• Journal of the korean Society of Automotive Engineers
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• v.7 no.2
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• pp.45-54
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• 1985

Recently, the problem of exhaust gas pollution is increasingly being aggravated by the active use of the Diesel engine. For the fuel-injection system which affects the composition of exhaust gas from the Bosch type single-hole nozzle in the Diesel engine, a mathematical model was set up to study pressure variations in the high pressure pipe, the injection rate, and the needle lift. The fundamental equations of the mathematical model have been solved by the Newton Raphson Method applying the Finite Diffrence Method. The effective stroke of the injection pump plunger due to a change in engine rpm was calculated by the measurement of Control Rack, Pinion, and Plunger sizes and by the use of Characteristic Curve of Governor. The computed results for the pressure variations in the high pressure pipe and needle lift at 800 rpm and 1000 rpm are in good agreement with experimental ones in general. By a developed program, the effects of other various parameters will by calculated for the performance of the fuel-injection system.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.15 no.1
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• pp.76-81
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• 2006

Modem after-treatment technology has been developed variously in order to decrease exhausted emission in diesel engine. However, it seems very difficult to comply with updated stringent emission standards. Specially, it has been many years that exhaust gas from gasoline automobile rather than from diesel is the major object concerned by Korea and other countries, and it is strongly required on the reduction techniques on harmful NOx and PM among those compositions. Thus, this research focused on the electronic control EGR and the target for this research is heavy-duty turbo-diesel engine with EGR technology(High pressure route and low pressure route system).

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.247-248
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• 2012

Unidentified self-ignitions were reported when the high-pressure hydrogen gas suddenly leaked out. This paper presents a flow visualization study to investigate the self-ignition mechanism in a test tube how the ignition process is initiated and the flame propagates with measurement of a number of pressure and light sensors installed in the tube supported the analysis of the self-ignition. The test result showed the location of the self-ignition taken place and critical static pressure at the boundary layer for self-ignition.