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Durability Evaluation of Cement Concrete Using Ferrosilicon Industrial Byproduct (페로실리콘 산업부산물 활용 시멘트 콘크리트의 내구성능 평가)

  • Chang-Young Kim;Ki Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.89-96
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    • 2023
  • In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO2 content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

Development of Reduced Graphene Oxide/Sr0.98Y0.08TiO3-δ Anode for Methane Fuels in Solid Oxide Fuel Cells (메탄연료사용을 위한 고체산화물 연료전지용 Reduced Graphene Oxide/Sr0.98Y0.08TiO3-δ 연료극 개발)

  • Hyung Soon Kim;Jun Ho Kim;Su In Mo;Gwang Seon Park;Jeong Woo Yun
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.296-301
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    • 2023
  • Solid oxide fuel cell has received more attention recently due to the fuel flexibility via internal reforming. Commonly used Ni/YSZ anode, however, can be easily deactivated by carbon coking in hydrocarbon fuels. The carbon deposition problem can minimize by developing alternative perovskite anode. This study is focused on improving conductivity and catalytic activity of the perovskite anode by introducing rGO (reduced graphene oxide). Sr0.92Y0.08TiO3(SYT) anode with perovskite structure was synthesized with 1wt% of rGO. The presence of rGO during anode fabricating process and cell operation is confirmed through XPS and Raman analysis. The maximum power density of rGO/SYT anode improved to 3 times in H2 and 6 times in CH4 comparing to that of SYT anode due to the high electrical conductivity and good catalytic activity for CH4.

Trace-based Interpolation Using Machine Learning for Irregularly Missing Seismic Data (불규칙한 빠짐을 포함한 탄성파 탐사 자료의 머신러닝을 이용한 트레이스 기반 내삽)

  • Zeu Yeeh;Jiho Park;Soon Jee Seol;Daeung Yoon;Joongmoo Byun
    • Geophysics and Geophysical Exploration
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    • v.26 no.2
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    • pp.62-76
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    • 2023
  • Recently, machine learning (ML) techniques have been actively applied for seismic trace interpolation. However, because most research is based on training-inference strategies that treat missing trace gather data as a 2D image with a blank area, a sufficient number of fully sampled data are required for training. This study proposes trace interpolation using ML, which uses only irregularly sampled field data, both in training and inference, by modifying the training-inference strategies of trace-based interpolation techniques. In this study, we describe a method for constructing networks that vary depending on the maximum number of consecutive gaps in seismic field data and the training method. To verify the applicability of the proposed method to field data, we applied our method to time-migrated seismic data acquired from the Vincent oilfield in the Exmouth Sub-basin area of Western Australia and compared the results with those of the conventional trace interpolation method. Both methods showed high interpolation performance, as confirmed by quantitative indicators, and the interpolation performance was uniformly good at all frequencies.

Development of Pore Filled Anion Exchange Membrane Using UV Polymerization Method for Anion Exchange Membrane Fuel Cell Application (음이온교환막 연료전지 응용을 위한 UV 중합법을 이용한 세공 충진 음이온교환막 개발)

  • Ga Jin Kwak;Do Hyeong Kim;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.2
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    • pp.77-86
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    • 2023
  • In this study, pore-filled ion exchange membranes with low membrane resistance and high hydroxide ion conductivity was developed. To improve alkali durability, a porous substrate made of polytetrafluoroethylene was used, and a copolymer was prepared using monomers 2-(dimethyl amino) ethyl methacrylate (DMAEMA) and vinyl benzyl chloride (VBC) for pores. divinyl benzene (DVB) was used as the cross-linker, and ion exchange membranes were prepared for each cross-linking agent content to study the effect of the cross-linker content on DMAEMA-DVB and VBC-DMAEMA-DVB copolymers. As a result, chemical stability is improved by using a PTFE material substrate, and productivity can be increased by enabling fast photo polymerization at a low temperature by using a low-pressure UV lamp. To confirm the physical and chemical stability of the ion exchange membrane required for an anion exchange membrane fuel cell, tensile strength, and alkali resistance tests were conducted. As a result, as the cross-linking degree increased, the tensile strength increased by approximately 40 MPa, and finally, through the silver conductivity and alkali resistance tests, it was confirmed that the alkaline stability increased as the cross-linking agent increased.

Scalable Fabrications of Mixed-Matrix Membranes via Polymer Modification-Enabled In Situ Metal-Organic Framework Formation for Gas Separation: A Review (고분자 변형으로 가능해진 MOF의 원위치 형성을 이용한 혼합기질 기체분리막의 대면적화 가능한 제막)

  • Sunghwan Park;Young-Sei Lee
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.213-220
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    • 2023
  • Mixed-matrix membranes (MMMs), which are composed of a polymer matrix filled with high-performance fillers as a dispersed phase, have been intensively studied for gas separations for the past 30 years. It has been demonstrated that MMMs exhibit superior gas separation performance compared to polymer membranes and are more scalable than polycrystalline membranes. Despite their potential, the commercialization of MMMs has yet to be reported due to several challenging issues. One of the major challenges of MMMs is the non-ideal interface between the continuous polymer phase and dispersed phase, which can result in defect formation (i.e., interfacial voids, etc.). With respect, many MMM studies have focused on addressing the issues through scientific approaches. The engineering approaches for facile and effective large-scale fabrication of MMMs, however, have been relatively underestimated. In this review paper, a novel strategy for fabricating MMMs in a facile and scalable manner using in situ metal-organic framework (MOF) formation is introduced. This new MMM fabrication methodology can effectively address the issues facing current MMMs, likely facilitating the commercialization of MMMs.

Dynamic Analysis of Structures with Continuous Transverse Reinforcement Applied (연속 횡방향철근을 적용한 구조물의 동적 해석)

  • Cho, Kyung Hun;Han, Soo Ho;Lee, Jung Bin;Kim, Sung Bo;Kim, Jang Jay Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.3
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    • pp.277-285
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    • 2023
  • Recently, as the magnitude and frequency of earthquakes increases, research is needed to increase the ductility of the columns in order to prevent the collapse of structures. In this study, to evaluate the performance of columns reinforced with continuous transverse reinforcing bars, the FE model for the dynamic analysis of structures reinforced with continuous transverse reinforcing bars for circular and rectangular columns is to be verified using the results of uniaxial compression experiments in the previous study. As a result, the experimental value of the column reinforced with continuous transverse reinforcement and the result value related to the dynamic analysis showed similar behavior, and the reliability was high. As a result of the analysis, the usability of the rectangular column reinforced with continuous lateral reinforcing bars was confirmed because the dissipated energy performance of the columns reinforced with spiral reinforcing bars was higher than that of the columns reinforced with band reinforcing bars.

International Comparison of Decoupling of Greenhouse Gas Emissions in the Steel Industry (철강산업의 온실가스 배출 탈동조화 국제비교)

  • Kim, Dong Koo
    • Environmental and Resource Economics Review
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    • v.31 no.1
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    • pp.113-139
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    • 2022
  • The iron and steel industry is a manufacturing industry with the largest greenhouse gases emissions and has a great ripple effect on the national economy as a core material industry. This study internationally compared the decoupling patterns of greenhouse gases emissions in the iron and steel industry from 1990 to 2019, focusing on Korea, Japan, and Germany. In particular, unlike previous studies that considered only fuel combustion emissions, this study considered all fuel combustion emissions, industrial process emissions, and indirect emissions from the use of electricity and heat. As a result of the analysis, Korea is interpreted as expansive coupling, Japan as decoupling, and Germany as unclear. Therefore, the decoupling path that the Korean iron and steel industry should take should not be in Germany, but in the form of seeking a decoupling method similar to Japan or more effective than Japan. In addition, this study considered the characteristics of the iron and steel industry as much as possible and presented the causes of the decoupling analysis results and implications for the Korean iron and steel industry through comparison with Japan and Germany. In particular, four factors were suggested as factors which has promoted decoupling in Japan: high value-added of Japanese iron and steel products, development of energy efficiency technology in the Japanese iron and steel industry, strategic M&A of the Japanese iron and steel industry, and maintaining competitiveness according to the closed distribution structure of Japanese iron and steel products. The Korean iron and steel industry should also use the case of Japan as a benchmark to further increase added value through quality uprade and product diversification of iron and steel products, while at the same time making efforts to fundamentally reduce greenhouse gas emissions through the development of new technologies.

A Study on the Development Methodology of Intelligent Medical Devices Utilizing KANO-QFD Model (지능형 메디컬 기기 개발을 위한 KANO-QFD 모델 제안: AI 기반 탈모관리 기기 중심으로)

  • Kim, Yechan;Choi, Kwangeun;Chung, Doohee
    • Journal of Intelligence and Information Systems
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    • v.28 no.1
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    • pp.217-242
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    • 2022
  • With the launch of Artificial Intelligence(AI)-based intelligent products on the market, innovative changes are taking place not only in business but also in consumers' daily lives. Intelligent products have the potential to realize technology differentiation and increase market competitiveness through advanced functions of artificial intelligence. However, there is no new product development methodology that can sufficiently reflect the characteristics of artificial intelligence for the purpose of developing intelligent products with high market acceptance. This study proposes a KANO-QFD integrated model as a methodology for intelligent product development. As a specific example of the empirical analysis, the types of consumer requirements for hair loss prediction and treatment device were classified, and the relative importance and priority of engineering characteristics were derived to suggest the direction of intelligent medical product development. As a result of a survey of 130 consumers, accurate prediction of future hair loss progress, future hair loss and improved future after treatment realized and viewed on a smartphone, sophisticated design, and treatment using laser and LED combined light energy were realized as attractive quality factors among the KANO categories. As a result of the analysis based on House of Quality of QFD, learning data for hair loss diagnosis and prediction, micro camera resolution for scalp scan, hair loss type classification model, customized personal account management, and hair loss progress diagnosis model were derived. This study is significant in that it presented directions for the development of artificial intelligence-based intelligent medical product that were not previously preceded.

A Study on Tensile Property due to Stacking Structure by Fiber Design of CT Specimen Composed of CFRP (CFRP로 구성된 CT시험편의 섬유설계에 의한 적층구조에 따른 인장 특성 연구)

  • Hwang, Gue-Wan;Cho, Jae-Ung
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.7 no.11
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    • pp.447-455
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    • 2017
  • At the modern industry, the composite material has been widely used. Particularly, the material of carbon fiber reinforced plastic hardened with resin on the basis of fiber is excellent. As the specific strength and rigidity are also superior, it receives attention as the light material. Among these materials, the carbon fiber reinforced plastic using carbon fiber has the superior mechanical property different from another fiber. So, it is utilized in vehicle and airplane at which high strength and light weight are needed at the same time. In this paper, the tensile property due to the fiber design is investigated through the analysis study with CT specimen composed of carbon plastic reinforced plastic. At the stress analysis of CFRP composite material with hole, the fracture trend at the tensile environment is examined. Also, it is shown that the lowest stress value happens and the deformation energy of the pre-crack becomes lowest at the analysis model composed of the stacking angle of 60° through the result due to the stacking angle. On the basis of this study result, it is thought to apply the foundation data to anticipate the fracture configuration at the structure applied with the practical experiment.

A Study on Performance Evaluation of Light Shelf according to the Reflectivity of Interior Space (실내 공간의 반사율에 따른 광선반 성능평가 연구)

  • Jeon, Gangmin;Lee, Heangwoo;Kim, Yongseong
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.5 no.5
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    • pp.461-470
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    • 2015
  • There has been a significant increase in the amount of research on reducing the lighting power consumption of buildings and also an increasing demand for technological development. Light shelf has been recognized as one of the most efficient solutions to this issue and related researches have been conducted, which have mostly focused on factors related to simple light shelves and are not suitable as an appropriate basis for the design of light shelves. Thus this study aims to establish the proper design basis for light shelves by evaluating the performance of shelves per reflection rate in indoor areas. Power consumption rate and indoor illumination intensity distribution of a testbed built based on actual living conditions were calculated for the performance evaluation, of which the results are as following: 1) Reduction of reflection rate of ceiling and walls caused average illumination intensity in summer, winter and median seasons, and evenness per reflection rate of indoor areas was found to be different in summer, winter and median seasons, making it a necessary consideration for designing light shelves. 2) Calculation of power consumption from lighting control showed that a high reflection rate of indoor areas may be suitable for power consumption reduction, and that reflection rates higher than 80% for ceilings and higher than 75% for walls in terms of the efficiency of researches on the indoor reflection rate and its application would be appropriate. This study is meaningful as the research focuses on light shelves based on considering indoor environmental factors. More studies will be required that consider a variety of factors.