• 제목/요약/키워드: High discharge rate

검색결과 776건 처리시간 0.027초

Charge/discharge Capacity of Natural Graphite Anode According to the Charge/discharge Rate in Lithium Secondary Batteries (리튬 이차전지의 음극재료인 천연흑연의 충방전 속도에 따른 충방전 용량)

  • Ryu Ji Heon;Oh Eun Young;Oh Seung M.
    • Journal of the Korean Electrochemical Society
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    • 제7권1호
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    • pp.32-37
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    • 2004
  • The charge/discharge capacity of natural graphite anode in lithium secondary batteries was examined as a function of charge/discharge rate. When the natural graphite anode was galvanostatically cycled in the range of 0.0-2.0V $(vs.\;Li/Li^+)$, the charging capacity decreased with an increase in the charging rate, which is caused by an earlier approach to the charging cut-off (0.0 V) before the complete charging that is in turn caused by an ever-increasing overpotential at higher rates. Even if the overpotential of discharging reaction also increased at higher discharge rates, the discharging reaction took place in the range of 0.0-0.3 V that is far below the discharge cut-off (2.0 V). As a result, the discharge capacity was not affected by the discharge rate because all the lithium ions once intercalated are fully discharged even at high current condition. As the overpotential of lithium deposition reaction also increased at high current condition, the charge capacity of natural graphite could be enlarged by lowering the charging cut-off voltage below 0.0 V, There is, however, a limitation for the lowering of cut-off voltage because the resistance for lithium deposition is smaller than that of lithium intercalation into graphite. When the charge cut-off voltage was lowered down to -0.04 V under IC condition, lithium ions were inserted into graphite without lithium deposition such that the discharge capacity could be raised up to $11\%$.

Experimental Study on Air Decomposition By-Product Under Creepage Discharge Fault and Their Impact on Insulating Materials

  • Javed, Hassan;LI, Kang;Zhang, Guoqiang;Plesca, Adrian Traian
    • Journal of Electrical Engineering and Technology
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    • 제13권6호
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    • pp.2392-2401
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    • 2018
  • Creepage discharge faults in air on solid insulating material play a vital role in degradation and ageing of material which ultimately leads to breakdown of power equipment. And electric discharge decompose air in to its by-products such as Ozone and $NO_x$ gases. By analyzing air decomposition gases is a potential method for fault diagnostic in air. In this paper, experimental research has been conducted to study the effect of creepage discharge on rate of generation of air decomposition by-products using different insulating materials such as RTV, epoxy and fiberglass laminated sheet. Moreover XRF analysis has been done to analyze creepage discharge effect on these insulating materials. All experiments have been done in an open air test cell under constant temperature and pressure conditions. While analysis has been made for low and high humidity conditions. The results show that the overall concentration of air decomposition by-products under creepage discharge in low humidity is 4% higher than concentration measured in high humidity. Based on this study a mathematical relationship is also proposed for the rate of generation of air decomposition by-products under creepage discharge fault. This study leads to indirect way for diagnostic of creepage discharge propagation in air.

Toluene Removal Using Surface Discharge Induced Plasma Chemical Process (연면방전 플라즈마를 이용한 톨루엔 처리에 관한 연구)

  • 부문자;봉춘근;김신도
    • Journal of Korean Society for Atmospheric Environment
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    • 제13권4호
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    • pp.297-305
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    • 1997
  • The experimental study by use of SPCP was fulfilled to remove toluene emitted from various industrial processes. First of all, discharge characteristic was experimented as the change of applied voltage and frequency. Then toluene removal characteristic was tested with the analysis of by-products. As a result, optimum electrical discharge condition was from 20.0 kHz to 25.0 kHz of frequency and from 3.5 kV to 4.0 kV of voltage range. The variation of applied voltage had a more important effect on the removal characteristic of toluene than the frequency variation. The toluene removal efficiency was proportioned to ozone concentration and retention time on discharge plate. It was dropped as increase of toluene concentration, but total treated volume of tolene per power consumption was high. The decomposed toluene was transformed to $CO, CO_2$ and particulates, and the rate of transformation to particulates was higher than CO and $CO_2$ at high toluene concentration. Particulates were increased from 0.017 $\mum$ to 0.3 $\mum$ range of size distribution.

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Formation of Dielectric Carbon Nitride Thin Films using a Pulsed Laser Ablation Combined with High Voltage Discharge Plasma (펄스 레이저 애블레이션이 결합된 고전압 방전 플라즈마 장치를 이용한 유전성 질화탄소 박막의 합성)

  • 김종일
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • 제16권7호
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    • pp.641-646
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    • 2003
  • The dielectric carbon nitride thin films were deposited onto Si(100) substrate using a pulsed laser ablation of pure graphite target combined with a high voltage discharge plasma in the presence of a N$_2$ reactive gas. We calculated dielectric constant, $\varepsilon$$\_$s/, with a capacitance Schering bridge method. We investigated the influence of the laser ablation of graphite target and DC high voltage source for the plasma. The properties of the deposited carbon nitride thin films were influenced by the high voltage source during the film growth. Deposition rate of carbon nitride films were increased drastically with the increase of high voltage source. Infrared absorption clearly shows the existence of C=N bonds and C=N bonds. The carbon nitride thin films were observed crystalline phase confirmed by x-ray diffraction data.

A study on the RE/DC discharge cleaning for high vacuum SUS chamber (RF/DC 방전을 이용한 고 진공용SUS 용기세정에 관한 연구)

  • 김정형;임종연;서인용;정광화
    • Journal of the Korean Vacuum Society
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    • 제10권3호
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    • pp.298-302
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    • 2001
  • Cleaning effect of RF/DC discharge to clean the surface of vacuum chamber was studied for various discharge conditions. Glow discharge cleaning without baking reduced the outgassing rate to 1/2, which was similar to that after the only baking treatment alone. Glow discharge cleaning treatment with baking improved the cleaning efficiency and then the outgassing rate was remarkably reduced to 1/20. It was found that the ion energy and the ion density were important factors in cleaning the surface. RF discharge cleaning was more effective than BC discharge cleaning.

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Effect of the Suction Air Temperature on the Performance of a Positive Displacement Air Compressor (흡입공기 온도에 의한 용적형 공기 압축기 성능 변화)

  • Jang, Ji-Seong;Han, Seoung-Hun;Ji, Sang-Won
    • Journal of Power System Engineering
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    • 제21권2호
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    • pp.89-94
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    • 2017
  • Pneumatic systems are widely applied in various industry because it have a many advantage(low cost, high safety, etc.). Air compressors supply the working fluid to the pneumatic systems and consume a lot of electrical energy at the manufacturing site. The one of the suggested idea is to reduce the energy consumption by reducing the suction temperature of the air compressor and increasing the discharge flow rate. In this paper, the discharge flow rate and air power of the positive displacement type air compressor is simulated by changing the temperature of suction air and the relationship between the suction air temperature and the performance variation of the air compressor is analyzed. As a result, we know that as the suction temperature of air is lowered, the discharge mass flow-rate is increased, but the specific enthalpy is reduced rather than increased, which means that the power of the discharged air is not greatly increased even if lower the suction air temperature.

Comparison of Discharge UV Intensity Due to AR Coating of Optic Lens on Polymer Insulator (광학렌즈 AR 코팅에 따른 폴리머애자에서의 방전 자외선 강도 비교)

  • Kim, Young-Seok;Shong, Kil-Mok;Bang, Sun-Bae;Kim, Chong-Min;Choi, Myeong-Il
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • 제26권4호
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    • pp.35-40
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    • 2012
  • In this study, the ultraviolet (UV) intensity of polymer insulator was measured using the Anti-Reflective (AR) coating lens on the occurrence of corona discharge. The UV intensity was compared before and after the AR coating. Under the 200-260[nm] of UV lens, the reflection rate before AR coating was 7.5~5.5[%] with 85-89[%] of transmission rate. After AR coating, however, the reflection rate decreased to 1.3~1.22[%] with improved transmission (97.4~97.6[%]). Then, the UV intensity by distance was measured in the polymer insulator. According to the measurement, the UV intensity increased 6.5 times at 37.5[%] of Vm/Vbd with 5[m] of distance. As distance increased, the growth rate declined. As high voltage increased, in addition, AR coating was less effective due to the count error caused by the UV sensor pulse signal overlap. Therefore, it appears that it would be more effective to detect corona discharge with 5[m] or less of distance at diagnosis of power facilities by AR coating and UV sensor sensitivity.

강변여과수 취수에 따른 지하수위의 계절적인 변동 특성

  • Jeong Jae-Yeol;Ham Se-Yeong;Lee Jeong-Hwan;Kim Hyeong-Su;Ryu Sang-Hon;Kim Tae-Won;Kim Mun-Su
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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    • pp.68-71
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    • 2006
  • Seasonal fluctuation of groundwater level by pumping amount and stream discharge at the riverbank filtrate site adjacent to the Nakdong River in Daesan-Myeon was characterized. Groundwater level fluctuation shows increase in wet season (June, July, August and September) and decrease in dry season (the other months). Seasonal variation of pumping amount shows similar trend to the groundwater fluctuation due to higher consumption of potable water in summer. The relation of specific capacity, Nakdong River and pumping quantity was analyzed. The logarithmic relationship between specific capacity and the stream discharge gives high correlation coefficient, 0.96. This fact indicates that the increase of stream discharge rate reduces the rate of drawdown in the pumping area in wet season.

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Size Effects of the Catalyst on Characteristics of Zn/Air Batteries ($MnO_2$입자 크기에 따른 아연공기전지의 특성연구)

  • Kim, Jee-Hoon;Eom, Seung-Wook;Moon, Seong-In;Yun, Mun-Soo;Kim, Ju-Yong;Yug, Gyeong-Chang;Park, Jeong-Hoo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.1129-1131
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    • 2002
  • Zinc Air battery obtain their energy density advantage over the other batteries by utilizing ambient oxygen as the cathode materials, and reusing cathode as recycled form. And specific capacity of zinc powder is as high as 820mAh/g. When Zinc Air battery discharged by low rate current discharge voltage profile has very flat pattern until end of voltage. But, when Zinc Air battery discharged by high rate current discharge voltage and capacity become lower. Therefore, we focused on effects of catalyst size in cathode. So we examined performance of zinc air batteries, average discharge voltage, capacity, energy, resistance. And we also obtained resistance by the GSM pulse discharge. So we have got optimum size of catalyst for Zinc Air battery.

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Enhancement of OH Radical Generation of Dielectric Barrier Discharge Plasma Gas Using Air-automizing Nozzle (이류체 노즐을 이용한 유전체장벽방전 플라즈마 가스의 OH 라디칼 생성 향상)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • 제27권8호
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    • pp.621-629
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    • 2018
  • Many chemically active species such as ${\cdot}H$, ${\cdot}OH$, $O_3$, $H_2O_2$, hydrated $e^-$, as well as ultraviolet rays, are produced by Dielectric Barrier Discharge (DBD) plasma in water and are widely use to remove non-biodegradable materials and deactivate microorganisms. As the plasma gas containing chemically active species that is generated from the plasma reaction has a short lifetime and low solubility in water, increasing the dissolution rate of this gas is an important challenge. To this end, the plasma gas and water within reactor were mixed using the air-automizing nozzle, and then, water-gas mixture was injected into water. The dissolving effect of plasma gas was indirectly confirmed by measuring the RNO (N-Dimethyl-4-nitrosoaniline, indicator of the formation of OH radical) solution. The plasma system consisted of an oxygen generator, a high-voltage power supply, a plasma generator and a liquid-gas mixing reactor. Experiments were conducted to examine the effects of location of air-automizing nozzle, flow rate of plasma gas, water circulation rate, and high-voltage on RNO degradation. The experimental results showed that the RNO removal efficiency of the air-automizing nozzle is 29.8% higher than the conventional diffuser. The nozzle position from water surface was not considered to be a major factor in the design and operation of the plasma reactor. The plasma gas flow rate and water circulation rate with the highest RNO removal rate were 3.5 L/min and 1.5 L/min, respectively. The ratio of the plasma gas flow rate to the water circulation rate for obtaining an RNO removal rate of over 95% was 1.67 ~ 4.00.