• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권1호
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• pp.37-43
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• 2000

In this experimental study we proposed the double dielectric barrier discharge (DDBD) reactor to produce as high an electric field as possible. The experiment are conducted for applied voltage from 15 to 20[kV], $1~4[\ell/min]$ of gas flow rate and 120[Hz] and 240[Hz] of pulse rate. Superposition discharge(SPD) generated in DDBD which combined the surface discharge with the silence discharge was the most effective to reduce the $NO_x$. In the decomposition efficiency per watt, the low pulse rate gave better efficiency than the high pulse rate. However in DeNOx rate, the high pulse rate gave better performance than the low pulse rate. $NO_x$ removal rate and efficiency increased with increasing the applied voltage in all reactors.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.169-172
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• 1999

In this experimental study we Proposed the double dielectric barrier discharge (DDBD) reactor to produce as high an electric field as possible. The experiment are conducted for applied voltage from 15 to 20[tV], flow gas rage at 2[1/min] and pulse rate at 120[pulses/s] and 240[pulses/s]. SPD connection of DDBD which combine the surface discharge with the silence discharge was most effective to reduce the NOx. In the decomposition efficiency per watt, the low pulse rate gave hotter efficiency than that of the high pulse rate. However in DeNOx rate, the high pulse rate gave better performance than that of the low pulse rate. NOx removal rate increased with increasing the applied voltage in all reactors.

• 한국전기전자재료학회논문지
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• 제11권11호
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• pp.1043-1048
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• 1998

The decomposition performance of the Surface induced Plasma Chemical Processing(SPCP) for benzene, toluene, xylene and $NO_2$ were experimentally examined. Discharge exciting frequency range was 5kHz and 10kHz, and low frequency discharge requires high voltage to inject high electric power in gas and to decompose contaminants. The decomposition rate of dioxide nitrogen for 5kHz power in gas and to decompose contaminants. The decomposition rate of dioxide nitrogen for 5kHz power supply is only 85%, but it’s rate for 10kHz power supply is very high, more than 96% when peak voltage is 12kv. Aromatic hydrocarbon vapor of up to 1000ppm is almost throughly decomposed at the flow rate of 1000$\ell$/min or lower rate under the discharge with electric power of several hundred watts. High decomposition rate is shown in every case, that is, for SPCP reactor is necessary to obtain the decomposition rate of more than 80~98%. The decomposition rate of benzene, toluene and xylene were 90~98% and dioxide nitrogen was 45~96%.

• 대한기계학회논문집A
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• 제39권8호
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• pp.807-812
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• 2015

리튬 전지는 에너지 밀도가 높고, 소형화 및 경량화가 가능한 이차전지로서 저장된 화학 에너지를 전기화학적 반응을 통해 전기 에너지로 변환하는 장치로 노트북, 휴대폰, 파워-툴 및 자동차 등에 널리 사용되고 있는 에너지원이다. 특히, 파워-툴이나 자동차와 같은 응용분야에서는 고율 충방전을 필요로 하는데, 본 논문에서는 리튬 전지의 고율 방전 특성에 대해서 상용 유한요소 해석 프로그램을 이용하여 전기화학 시뮬레이션을 진행하여 실험 결과와 유사한 전기화학 모델을 완성하게 되었다. 또한, 이러한 전기화학적 해석 모델을 이용하여 고율 방전용 리튬 전지의 한계 방전 전류가 63A 정도라는 것을 해석적으로 예측 할 수 있었고, 이를 바탕으로 고율 방전 시 리튬 전지의 거동에 대해서 이해할 수 있게 되었다.

• 분석과학
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• 제15권2호
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• pp.108-114
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• 2002

고체 시료를 직접 분석하기 위하여 글로우 방전 원자 방출법을 이용한 새로운 장치를 개발하였다. 이 시스템은 기존의 gas-jet boosted nozzle을 개선한 새로운 방전 셀과 Radio-frequency 전원장치를 사용하였다. 기존의 gas-jet boosted nozzle의 경우 재침전이 적고, 시료 손실량이 많아서 낮은 방전 전력에서 저 합금강의 미량 분석에 적합하였다. 하지만 높은 방전 전력을 사용할 경우 시료 손실량이 많아지고, 재석출(redeposition)이 증가함으로 해서 플라스마가 불안정해지는 단점을 지니고 있었다. 기존의 글로우 방전 셀의 경우 방전 전력을 높일 수록 플라스마의 들뜸 온도가 증가하는 경향을 가진다. 이 때문에 높은 방전 전력에서는 플라스마의 온도가 높아져서 극미량 분석이 가능할 수 있지만, 기존의 노즐 부분에 문제점으로 인해 높은 방전 전력으로 분석하기에는 부적합하였다. 이러한 문제점을 modified gas-jet boosted nozzle은 시료 손실량이 같은 방전 전력에서 기존의 가스 제트 흐름노즐에 비하여 감소하지만 높은 방전 전력에서는 플라스마 안정도가 증가하여 극미량 분석이 가능하도록 개선하였다. 본 시스템은 여러 가지 방전에 미치는 실험 변수인 압력과 가스 흐름량 그리고 방전 전력의 변화에 따른 시료 손실 속도와 방출 세기 등의 변화를 측정하여 최적화 하였으며, 표준 시료 Fe합금을 이용하여서 미량 분석을 하였다.

• 한국수소및신에너지학회논문집
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• 제24권2호
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• pp.179-185
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• 2013

The behavior of surface film formation was greatly dependent on the speed of potential cycling. In $LiClO_4$ / EC + DEC, cyclic voltammetry results showed that the peaks originated from surface film formation on graphite electrode at the high charge-discharge rate was shifted to the lower potentials as the charge-discharge rate decrease. This indicates that surface films with different morphology and thickness were formed by different charge-discharge rate. Transmission electron microscopy (TEM) results indicated that the properties such as thickness and morphology of the surface film were greatly affected by the charge-discharge rate. Electrochemical impedance spectroscopy (EIS) showed that the resistance of surface film was affected by the speed of potential cycling. In addition, the charge transfer resistance was also dependent on the charge-discharge rate indicating that the charge transfer reaction was affected by the nature of surface film. TEM and EIS results suggested that the chemical property as well as the physical property of the surface film was affected by the charge-discharge rate.

• 한국안전학회지
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• 제14권1호
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• pp.73-77
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• 1999

In this study, $SO_2$ and $NO_2$ reduction have been investigated by using coil type plasma reactor. The experiments have been carried out changing discharge power, gas flow rate frequency and electrode style to obtain the decomposition rate. Decomposition rates of $SO_2$ and $NO_2$ were obtained 20~98% at gas flow rate 100ml/min~1,000ml/min and discharge power 5~25w respectively. The energy efficiency is very good at the high frequency power. The decomposition rate of $SO_2$ for 5kHz power supply is only 90%, but for 10kHz power supply is very high, more than 98% for 15w. The decomposition rate is increasing according to the residence time or the power consumption of the discharge. About 15W discharge power for 17$cm^2$ reactor is necessary to obtain the decomposition rate of $SO_2$ and $NO_2$ of more than 85% or 98%. From these experiments, the consumption power of the decomposition rate of 98% in 300ppm $NO_2$ gas in nitrogen gas proved to be 18W and 300ppm $SO_2$ gas to be 15w.

• 기술사
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• 제15권3호
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• pp.12-18
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• 1982

단추형 제 2신화은전지의 고주파형 방전용량의 변화를 음극의 구조, 합제배합, 음극 소제의 모양, 격리막, 전해액농도와 연결지어 조사하였다.

• 대한전기학회논문지
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• 제34권9호
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• pp.355-360
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• 1985

In this paper, the discharge phenomena of high frequency glow discharge in organic vapor are basically investigted to establish the growth mechanism and preparation technique for organic thin film. According to the increasing of discharge frequency, the discharge firing voltage(Vs) of organic vapor decreases. The dependence of discharge voltage(Vd) on gas pressure is generally in accord with Paschen's Law and Vd decreases as gas flow rate become larger, but increases as dischange current density become higher. And the values of Vd in organic vapor are generally higher than those of inorganic gas.

• 한국안전학회지
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• 제15권2호
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• pp.92-96
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• 2000

In this experiment, we studied about concentration characteristics of $NO_x$ and generation of ozone in the reactor of corona discharge type by using mixed gas of $NO/N_2$ and $N_2/O_2$. In the case of the initial NO concentration increased, decrease rate of NO concentration was weakened and discharge input power of minimum NO concentration became high. When NO concentration was high, NO decomposition limit was appeared. And NO reduction rate was decreased, when initial NO concentration and discharge input power increased. When discharge input power was 5W, we could know the most proper energy value for treatment of NO. When the concentration of initial NO increased, generation of ozone decreased and in the case of same concentration of NO, according to discharge input power increase, generation of ozone increased.