• 제목/요약/키워드: Heterogeneous surface

검색결과 304건 처리시간 0.023초

Surface modification of graphene oxide by citric acid and its application as a heterogeneous nanocatalyst in organic condensation reaction

  • Maleki, Ali;Hajizadeh, Zoleikha;Abbasi, Hamid
    • Carbon letters
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    • 제27권
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    • pp.42-49
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    • 2018
  • A citric acid functionalized graphene oxide nanocomposite was successfully synthesized and the structure and morphology of the nanocatalyst were comprehensively characterized by Fourier transform infrared spectroscopy, energy-dispersive X-ray analysis, X-ray diffraction patterns, atomic force microscopy images, scanning electron microscopy images, transmission electron microscopy images, and thermogravimetric analysis. The application of this nanocatalyst was exemplified in an important condensation reaction to give imidazole derivatives in high yields and short reaction times at room temperature. The catalyst shows high catalytic activity and could be reused after simple work up and easy purification for at least six cycles without significant loss of activity, which indicates efficient immobilizing of citrate groups on the surface of graphene oxide sheets.

다공성 세라믹스와 다공질층을 포함하는 적층세라믹스의 제조에 관한 연구;II. 불균일 적층소결체 (Fabrication of Porous Ceramics and Multilayered Ceramics Containing Porous Layers; II. Heterogeneous Laminates)

  • 이해원;윤복규;송휴섭
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1323-1329
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    • 1994
  • Tape casting and lamination were used to produce heterogeneous laminates with alternating layers of different porosity and homogeneous laminates with component layers of the same porosity. The pore structure was investigated for heterogeneous laminates, and bend strength was measured for comparison with that of homogeneous laminates. For a reference, strength measurement was made for the porous body fabricated by sintering samples dry-pressed at low pressure with spray-dried granules. Strength increase, in the range 50~120 MPa, was achieved in the presence of the surface dense layer, while extensive delamination, presumably responsible for enhanced fracture toughness, took place through the internal porous layer.

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VNURBS기반의 다차원 불균질 볼륨 객체의 표현: 모델링 및 응용 (Volumetric NURBS Representation of Multidimensional and Heterogeneous Objects: Modeling and Applications)

  • 박상근
    • 한국CDE학회논문집
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    • 제10권5호
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    • pp.314-327
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    • 2005
  • This paper describes the volumetric data modeling and analysis methods that employ volumetric NURBS or VNURBS that represents heterogeneous objects or fields in multidimensional space. For volumetric data modeling, we formulate the construction algorithms involving the scattered data approximation and the curvilinear grid data interpolation. And then the computational algorithms are presented for the geometric and mathematical analysis of the volume data set with the VNURBS model. Finally, we apply the modeling and analysis methods to various field applications including grid generation, flow visualization, implicit surface modeling, and image morphing. Those application examples verify the usefulness and extensibility of our VNUBRS representation in the context of volume modeling and analysis.

액체 시뮬레이션의 얇은 특징을 빠르게 표현하기 위한 CPU와 GPU 이기종 컴퓨팅 기술 (A CPU and GPU Heterogeneous Computing Techniques for Fast Representation of Thin Features in Liquid Simulations)

  • 김종현
    • 한국컴퓨터그래픽스학회논문지
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    • 제24권2호
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    • pp.11-20
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    • 2018
  • 우리는 유체의 얇은 막을 명시적으로 표현하고 보존할 수 있는 CPU-GPU 이기종 컴퓨팅 기반의 유체 시뮬레이션 기법을 소개한다. 본 논문에서 가장 큰 기여는 얇은 유체표면에서 쪼개지거나 밀도가 높은 지점에서 붕괴되어 유체표면에 나타나는 Hole을 방지하는 입자 기반 프레임워크를 GPU를 활용한다는 것이다. 유체표면을 추적하는 기존의 방법과는 달리, 제안된 프레임워크는 CPU-GPU 프레임워크상에서 수치적 확산이나 꼬임문제 없이 안정적으로 토폴로지 변화를 처리할 수 있다. 얇은 표면의 특징은 이방성 커널(Anisotropic kernel)과 주성분 분석(Principal component analysis; PCA)을 GPU상에서 수행하여 유체의 방향성을 빠르게 찾고, 새로운 유체입자의 위치를 결정하기 위해 계산하는, 후보위치 추출 과정의 효율성을 CPU-GPU 이기종 컴퓨팅 기술 기반으로 빠르게 계산한다. 제안된 알고리즘은 직관적으로 구현되며, 병렬화가 쉽고 시각적으로 디테일한 액체의 얇은 표면을 빠르게 애니메이션 할 수 있다.

비균질 도시 지표에서 측정된 에디 공분산 난류 플럭스의 불확실성 분석: 좌표계 편향 영향 (Uncertainty Analysis of the Eddy-Covariance Turbulent Fluxes Measured over a Heterogeneous Urban Area: A Coordinate Tilt Impact)

  • 이두일;이재형;이상현
    • 대기
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    • 제26권3호
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    • pp.473-482
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    • 2016
  • An accurate determination of turbulent fluxes over an urban area is a challenging task due to its morphological diversity and associated flow complexity. In this study, an eddy covariance (EC) method is applied over a highly heterogeneous urban area in a small city (Gongju), South Korea to investigate the quantitative influence of 'coordinate tilt' in determining the turbulent fluxes of sensible heat, latent heat, momentum, and carbon dioxide mass. Two widely-used coordinate transform methods are adopted and applied to eight directional sections centered on the site to analyze a 1-year period EC measurement obtained from the urban site: double rotation (DR) and planar fit (PF) transform. The results show that mean streamline planes determined by the PF method are distinguished from the sections, representing morphological heterogeneity of the site. The sectional pitch angles determined by the DR method also compare well with those in the PF method. Both the PF and DR methods show large variabilities in the determined streamline planes at each directional section, implying that flow patterns may form in a complicate way due to the surface heterogeneity. Resulting relative differences of the turbulent fluxes, defined by $(F_{DR}-F_{PF})/F_{DR}$, are found on average +13% in sensible heat flux, +21% in latent heat flux, +37% in momentum flux, and +26% in carbon dioxide mass flux, which are larger values than those reported previously for fairly homogeneous natural sites. The fractional differences depend significantly on wind direction, showing larger differences in northerly winds at the measurement site. It is also found that the relative fractional differences are negatively correlated with the mean wind speed at both stable/unstable atmospheric conditions. These results imply that EC turbulent fluxes determined over heterogeneous urban areas should be carefully interpreted with considering the uncertainty due to 'coordinate tilt' effect in their applications.

기능성 경사복합재의 적층조형을 위한 분해기반 공정계획 (Decomposition-based Process Planning far Layered Manufacturing of Functionally Gradient Materials)

  • 신기훈;김성환
    • 한국CDE학회논문집
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    • 제11권3호
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    • pp.223-233
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    • 2006
  • Layered manufacturing(LM) is emerging as a new technology that enables the fabrication of three dimensional heterogeneous objects such as Multi-materials and Functionally Gradient Materials (FGMs). Among various types of heterogeneous objects, more attention has recently paid on the fabrication of FGMs because of their potentials in engineering applications. The necessary steps for LM fabrication of FGMs include representation and process planning of material information inside an FGM. This paper introduces a new process planning algorithm that takes into account the processing of material information. The detailed tasks are discretization (i.e., decomposition-based approximation of volume fraction), orientation (build direction selection), and adaptive slicing of heterogeneous objects. In particular, this paper focuses on the discretization process that converts all of the material information inside an FGM into material features like geometric features. It is thus possible to choose an optimal build direction among various pre-selected ones by approximately estimating build time. This is because total build time depends on the complexity of features. This discretization process also allows adaptive slicing of heterogeneous objects to minimize surface finish and material composition error. In addition, tool path planning can be simplified into fill pattern generation. Specific examples are shown to illustrate the overall procedure.

Origin of Callus and Vascular Cambium in Debarked Stem of Robinia pseudoacacia

  • Soh, Woong-Young
    • Journal of Plant Biology
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    • 제37권3호
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    • pp.317-323
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    • 1994
  • The calluses formed on the surface of a quarter-girdled Robinia pseudoacacia stems have been shown to originate from immature xylem cells and preexisting cambial cells. The cellus is not only formed by periclinal and anticlinal divisions of radial cells, but also axial cells. In tangential view, the callus at initial stage showed heterogeneous structure composed of long and short cells and then homogeneous one with short cells. Some cells of homogeneous structure in middle region of callus at early stage is later elongated and others mainly divided in trasverse plane. In the result the homogeneous structure becomes into a heterogeneous one. Subsequently, the long cells in heterogeneous structures elongated further and became fusifrom initials, and the short cells divided transversely became ray initials. The appearence of homogeneous and heterogeneous structure in the callus on debarked stem without organ elongation is almost similar to that of the structure in the procambium of young stem which is elongating extensively. Eventually, the ontogeny of vascular cambium in wound callus resembles that of a young stem grown normally, although the debarked stem does not grow in length but in girth and the young stem elongates activity. These findings mean that the active intrusive growth of short procambial cells occurs during the differentiation of fusiform cambial cells.

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랜덤포레스트를 활용한 교량 바닥판의 이종손상 원인 추정 기술 개발 (Development of Heterogeneous Damage Cause Estimation Technology for Bridge Decks using Random Forest)

  • 정현진;박기태;김재환;권태호;이종한
    • 대한토목학회논문집
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    • 제44권1호
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    • pp.19-32
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    • 2024
  • 정밀안전진단보고서를 분석한 결과 국내 고속도로 교량은 결함, 열화, 물리력에 의한 손상이 주요하게 발생한다. 특히 열화는 시간이 경과함에 따라 다양한 환경 영향인자와 외부적 요인에 의해 발생하는 필연적인 손상이다. 교량 바닥판의 경우 열화가 가장 빠른 부재로, 균열부를 중심으로 철근부식, 박리/박락 등의 여러 가지 유형의 이종손상이 함께 발생하는 것으로 분석된다. 따라서 교량의 이종손상과 열화환경 간의 상관관계를 밝히고 이를 통해 교량의 이종손상 발생 원인을 규명해야 한다. 본 연구에서는 랜덤포레스트를 활용하여 교량의 이종손상 예측 모델을 개발하였으며, 개발된 모델을 통해 이종손상 발생에 영향을 미치는 상위 5가지 영향인자를 도출하였다. 이를 통해 장래 교량의 유지관리 및 예산을 추정하는 분야에 활용하는 기초자료가 될 수 있을 것으로 판단된다.

이종방전 중첩에 의한 방전 플라스마반응기의 효율개선의 시도 - 연면.직류코로나 방전 중첩형 반응기의 특성 - (A Trial for Improvement of Energy Efficiency of Plasma Reactor by Superposing Two Heterogeneous Discharges - Characteristics of Surface and Corona Discharge Combined Plasma Reactor -)

  • 우인성;;황명환
    • 한국안전학회지
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    • 제15권3호
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    • pp.66-70
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    • 2000
  • In order to cope with environmental problems caused by harmful gases emitted from various industrial sources, a new technology which employs discharge plasma formed in ordinary atmospheric pressure has been intensively investigated in many industrialized nations. Although a plenty of useful outcomes and suggestions have been made public by scientists in this field, few commercial products which effectively decompose pollutant gases have appeared as yet. This is partly because that the energy efficiency of a most effective plasma reactor has not reached a satisfactory level in comparison with those of devices using conventional technologies. In an attempt to solve the problem mentioned above, we noticed to combine heterogeneous electrical discharges. This concepts is based on that each plasma reactor has its specific spatial region in which chemical reaction are active and by electrically affected with another reactor of different type, the activated region would increase - which may lead to cutting down the energy consumption. To prove this concept experimentally, two different discharge equipments, a plane ceramic-based surface discharge electrode and a corona electrode with tungsten needle may, are selected and combined to fabricate a hybrid plasma reactor. The results are summarized as follows; (1) Ozone concentration generated in the plasma region drastically increases when the positive corona discharge is added to the surface discharge. The rate of increase of ozone depends on the frequency of the surface discharge. The negative corona, however, does not contribute to the improvement of the ozone generation. (2) NO(nitrogen monoxide) decomposition rate also improves by simultaneously applying the surface and the positive corona discharges. The effect of the corona superposition is more evident when the level of the surface discharge is moderate. (3) By adjusting the corona level, the net energy efficiency during NO decomposition improves in comparison with the simple surface discharge reactor.

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단일 알루미늄 연료 입자의 점화 및 연소 모델링 (Modeling of the Ignition and Combustion of Single Aluminum Particle)

  • 양희성;임지환;김경무;이지형;윤웅섭
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년도 제30회 춘계학술대회논문집
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    • pp.187-192
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    • 2008
  • A simplified model for an isolated aluminum particle burning in air is presented. Burning process consists of two stages, ignition and quasi-steady combustion (QSC). In ignition stage, aluminum which is inside of oxide film melts owing to the self heating called heterogeneous surface reaction (HSR) as well as the convective and radiative heat transfer from ambient air until the particle temperature reaches melting point of oxide film. In combustion stage, gas phase reaction occurs, and quasi-steady diffusion flame is assumed. For simplicity, 1-dimesional spherical symmetric condition and flame sheet assumption are also used. Extended conserved scalar formulations and modified Shvab-Zeldovich functions are used that account for the deposition of metal oxide on the surface of the molten aluminum. Using developed model, time variation of particle temperature, masses of molten aluminum and deposited oxide are predicted. Burning rate, flame radius and temperature are also calculated, and compared with some experimental data.

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