• 제목/요약/키워드: Heterogeneous surface

검색결과 303건 처리시간 0.028초

Survival rates against fracture of endodontically treated posterior teeth restored with full-coverage crowns or resin composite restorations: a systematic review

  • Suksaphar, Warattama;Banomyong, Danuchit;Jirathanyanatt, Titalee;Ngoenwiwatkul, Yaowaluk
    • Restorative Dentistry and Endodontics
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    • 제42권3호
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    • pp.157-167
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    • 2017
  • This systematic review aims to summarize the current clinical studies that investigated survival rates against fracture of endodontically treated posterior teeth restored with crowns or resin composite restorations. Literature search were performed using keywords. Publications from 1980 to 2016 were searched in PubMed, ScienceDirect, ISI Web of SCIENCE, MEDLINE, and SCOPUS. Included studies were selected based on inclusion and exclusion criteria. Three clinical studies were included: 1 randomized controlled trial and 1 prospective and 1 retrospective cohort studies. Pooled survival rates ranged from 94%-100% and 91.9%-100% for crowns and resin composite, respectively. The majority of teeth had no more than 3 surface loss of tooth structure. The studies included were heterogeneous, and were not appropriate for further meta-analysis. Current evidence suggested that the survival rates against the fracture of endodontically treated posterior teeth restored with crowns or resin composites were not significantly different in the teeth with minimum to moderate loss of tooth structure.

One-node and two-node hybrid coarse-mesh finite difference algorithm for efficient pin-by-pin core calculation

  • Song, Seongho;Yu, Hwanyeal;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제50권3호
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    • pp.327-339
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    • 2018
  • This article presents a new global-local hybrid coarse-mesh finite difference (HCMFD) method for efficient parallel calculation of pin-by-pin heterogeneous core analysis. In the HCMFD method, the one-node coarse-mesh finite difference (CMFD) scheme is combined with a nodal expansion method (NEM)-based two-node CMFD method in a nonlinear way. In the global-local HCMFD algorithm, the global problem is a coarse-mesh eigenvalue problem, whereas the local problems are fixed source problems with boundary conditions of incoming partial current, and they can be solved in parallel. The global problem is formulated by one-node CMFD, in which two correction factors on an interface are introduced to preserve both the surface-average flux and the net current. Meanwhile, for accurate and efficient pin-wise core analysis, the local problem is solved by the conventional NEM-based two-node CMFD method. We investigated the numerical characteristics of the HCMFD method for a few benchmark problems and compared them with the conventional two-node NEM-based CMFD algorithm. In this study, the HCMFD algorithm was also parallelized with the OpenMP parallel interface, and its numerical performances were evaluated for several benchmarks.

The Chemically Induced Hot Electron Flows on Metal-Semiconductor Schottky nanodiodes During Hydrogen Oxidation

  • Lee, Hyosun;Lee, Youngkeun;Lee, Changhwan;Kim, Sunmi;Park, Jeong Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.152-152
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    • 2013
  • Mechanism of energy conversion from chemical to electrical during exothermic catalytic reactions at the metal surfaces has been a fascinating and crucial subject in heterogeneous catalysis. A metal-semiconductor Schottky nanodiode is novel device for direct detection of chemically induced hot electrons which have sufficient energy to surmount the Schottky barrier. We measured a continuous chemicurrent during the hydrogen oxidation under of 760 Torr of O2 and 6 Torr of H2 by using Pt/Si and Pt/TiO2 nanodiodes at reaction temperatures and compared the chemicurrent with the reaction turnover rate. The thermoelectric current was measured by carrying out an experiment under O2 condition for elimination of the background current. Gas chromatograph and source meter were used for measurement of the chemical turnover rate and the chemicurrent, respectively. The correlation between the chemicurrent and the chemical turnover rate under hydrogen oxidation implies how hot electrons generated on the metal surface affect hydrogen oxidation.

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Photosynthetic Activity of Epiphytic Algae in Embayment Reed Zone in a Lagoon Connected with Lake Biwa

  • Mitamura, Osamu;Tachibana, Junji;Ishida, Noriko;Seike, Yasushi;Choi, Jun-Kil
    • 생태와환경
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    • 제42권1호
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    • pp.48-57
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    • 2009
  • Primary production of epiphytic and planktonic algae in a shallow reed zone of a lagoon Nishinoko was investigated. Concentrations of nutrients varied widely horizontally and locally in the lagoon. It seems that the reed zone has a heterogeneous environment. The photosynthetic rates of epiphytic and planktonic algae were 7 to 14 mg C surface stem $m^{-2}hr^{-1}$ and 12 to $46mg\;Cm^{-3}hr^{-1}$, respectively. The areal primary production of epiphytic algae was estimated as 4 to $13mg\;Cm^{-2}hr^{-1}$ from the stem density of Phragmites and the water depth at each station. The production of phytoplankton, on the other hand, was 5 to $56mg\;Cm^{-2}hr^{-1}$. The contribution of epiphytic algae to total primary production averaged 53%, although the assimilation number was much lower than that of phytoplankton. The present results indicate that the epiphytic algae are one of the significant primary producers in the reed zone.

KATSTIC SINKHOLE SEDIMENTS OF DOLOSTONE IN THE UPPER MIDWEST'S DRIFTLESS AREA, USA

  • Oh, Jong-woo
    • 동굴
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    • 제34권35호
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    • pp.78-104
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    • 1993
  • Analysis of one sinkhole, the Dodgeville sinkhole, developed in Ordovician dolostones in the Driftless Area of Wisconsin in the Upper Midwest'd Driftless Area reveals homogenous clayey sediment fills reflecting a range of dissolutional processes during the Quaternary or Pre-Quaternary. Granulometric analysis, graphical moments statistics, carbonate minerals, ana sand grain lithology were used to differentiate sinkhole sediment sources and modes of accumulation. Sediments in the dolostone sinkholes developed by dissolution. Sediments contain two major types of sediments : residual redish clay( autogenic sediments) and aeolian silt (allogenic sediments). The massive clay is generated from the weathered dolostone bedrocks as a in situ materials. The loessial silt is mostly derived from transportation of the surrounding surface materials, with some evidences of penetrated deposition. Unlike the collapsed sandstone sinkholes (Oh et al., 1993), dolostone sinkholes reveal homogenous, autogenic clay materials, and a geochemical composition indicative of in situ autogenic karstification. Dolostone sinkhole si1ts (26.9%) and sands (34.9%) are derived from weathered Plattevi1le-Galena dolostones, and contain high carbonate(37.5%), chert (57.2%) and lead ore (3%). Graphical moments statistics for sorting, skewness, and kurtosis indicate that sand grains from dolostones were derived entirely from local bedrock by in situ dissolution. Upper sinkhole sediments are pedagogically very young as carbonate is unleashed. Materials of the sinkhole sediment are definitely inherited from internal dolostones by dissolution and weathering, because not only a granulomatric comparison of dolostone and sandstone sediments demonstrates that they have heterogeneous paticle size distributions, but also 1ithologic analyses displays they differ completely.

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전기방사를 이용하여 제조된 산화아연 나노섬유의 직경제어 및 광촉매 특성 (Diameter-Controllable Synthesis and Enhanced Photocatalytic Activity of Electrospun ZnO Nanofibers)

  • 지명준;유재현;이영인
    • 한국재료학회지
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    • 제29권2호
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    • pp.79-86
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    • 2019
  • A heterogeneous photocatalytic system is attracting much interest for water and air purification because of its reusability and economical advantage. Electrospun nanofibers are also receiving immense attention for efficient photocatalysts due to their ultra-high specific surface areas and aspect ratios. In this study, ZnO nanofibers with average diameters of 71, 151 and 168 nm are successfully synthesized by facile electrospinning and a subsequent calcination process at $500^{\circ}C$ for 3 h. Their crystal structures, morphology features and optical properties are systematically characterized by X-ray diffraction, scanning electron microscopy, UV-Vis and photoluminescence spectroscopies. The photocatalytic activities of the ZnO nanofibers are evaluated by the photodegradation of a rhodamine B aqueous solution. The results reveal that the diameter of the nanofiber, controlled by changing the polymer content in the precursor solution, plays an important role in the photocatalytic activities of the synthesized ZnO nanofibers.

탄소나노튜브 표면의 무전해 니켈입자 코팅 (Nickel Particle Coatings by Electroless Plating onto Carbon Nanotubes)

  • 조규섭;임정규;장훈;최경환
    • 대한금속재료학회지
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    • 제48권5호
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    • pp.462-468
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    • 2010
  • Carbon Nanotubes (CNTs) have recently emerged as a material with outstanding properties. It has shown promising potential for applications in many engineering fields as electronic devices, thermal conductors, and light-weight composites. Researchers have investigated their use as reinforcements in themetal matrix composites of CNTs. In the present work, we decorated CNTs with Ni particles by electroless plating. The CNTs were wet-ball milled for various milling times with a nickel sulfate solution. The precipitated Ni particles were observed mainly by FESEM. In this study, the dispersion of the CNTs and Ni particles was improved with the addition of the surfactant. Also, as the CNTs were shortened and widened by an increased ball milling time, the size of the precipitated Ni particles increased. It was estimated that the CNTs were deformed and caused some defects on their surface during the ball milling process. Those defects were assumed to be heterogeneous nucleation sites for the Ni particles.

Photodynamic Diagnosis and Therapy for Peritoneal Carcinomatosis from Gastrointestinal Cancers: Status, Opportunities, and Challenges

  • Kim, Hyoung-Il;Wilson, Brian C.
    • Journal of Gastric Cancer
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    • 제20권4호
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    • pp.355-375
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    • 2020
  • Selective accumulation of a photosensitizer and the subsequent response in only the light-irradiated target are advantages of photodynamic diagnosis and therapy. The limited depth of the therapeutic effect is a positive characteristic when treating surface malignancies, such as peritoneal carcinomatosis. For photodynamic diagnosis (PDD), adjunctive use of aminolevulinic acid- protoporphyrin IX-guided fluorescence imaging detects cancer nodules, which would have been missed during assessment using white light visualization only. Furthermore, since few side effects have been reported, this has the potential to become a vital component of diagnostic laparoscopy. A variety of photosensitizers have been examined for photodynamic therapy (PDT), and treatment protocols are heterogeneous in terms of photosensitizer type and dose, photosensitizer-light time interval, and light source wavelength, dose, and dose rate. Although several studies have suggested that PDT has favorable effects in peritoneal carcinomatosis, clinical trials in more homogenous patient groups are required to identify the true benefits. In addition, major complications, such as bowel perforation and capillary leak syndrome, need to be reduced. In the long term, PDD and PDT are likely to be successful therapeutic options for patients with peritoneal carcinomatosis, with several options to optimize the photosensitizer and light delivery parameters to improve safety and efficacy.

Direct and Indirect Reduction of Cr(VI) by Fermentative Fe(III)-Reducing Cellulomonas sp. Strain Cellu-2a

  • Khanal, Anamika;Hur, Hor-Gil;Fredrickson, James K.;Lee, Ji-Hoon
    • Journal of Microbiology and Biotechnology
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    • 제31권11호
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    • pp.1519-1525
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    • 2021
  • Hexavalent chromium (Cr(VI)) is recognized to be carcinogenic and toxic and registered as a contaminant in many drinking water regulations. It occurs naturally and is also produced by industrial processes. The reduction of Cr(VI) to Cr(III) has been a central topic for chromium remediation since Cr(III) is less toxic and less mobile. In this study, fermentative Fe(III)-reducing bacterial strains (Cellu-2a, Cellu-5a, and Cellu-5b) were isolated from a groundwater sample and were phylogenetically related to species of Cellulomonas by 16S rRNA gene analysis. One selected strain, Cellu-2a showed its capacity of reduction of both soluble iron (ferric citrate) and solid iron (hydrous ferric oxide, HFO), as well as aqueous Cr(VI). The strain Cellu-2a was able to reduce 15 μM Cr(VI) directly with glucose or sucrose as a sole carbon source under the anaerobic condition and indirectly with one of the substrates and HFO in the same incubations. The heterogeneous reduction of Cr(VI) by the surface-associated reduced iron from HFO by Cellu-2a likely assisted the Cr(VI) reduction. Fermentative features such as large-scale cell growth may impose advantages on the application of bacterial Cr(VI) reduction over anaerobic respiratory reduction.

Cationized Lignin Loaded Alginate Beads for Efficient Cr(VI) Removal

  • Jungkyu KIM;YunJin KIM;Seungoh JUNG;Heecheol YUN;Hwanmyeong YEO;In-Gyu CHOI;Hyo Won KWAK
    • Journal of the Korean Wood Science and Technology
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    • 제51권5호
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    • pp.321-333
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    • 2023
  • In this study, lignin, a lignocellulosic biomass, was chemically modified to produce polyethyleneimine-grafted lignin (PKL) with maximum hexavalent chromium [Cr(VI)] adsorption capacity. Changes in the physicochemical properties due to the cationization of lignin were confirmed through elemental analysis, Fourier transform infrared spectroscopy, and moisture stability evaluation. Alginate (Alg) beads containing PKL (Alg/PKL) were prepared by incorporating cationic lignin into the Alg matrix to apply the prepared PKL in a batch-type water treatment process. The optimal Alg/lignin mixing ratio was selected to increase the Cr(VI) adsorption capacity and minimize lignin elution from the aqueous system. The selected Alg/PKL beads exhibited an excellent Cr(VI) removal capacity of 478.98 mg/g. Isothermal adsorption and thermodynamic analysis revealed that the Cr(VI) removal behavior of the Alg/PKL beads was similar to that of heterogeneous chemical adsorption. In addition, the bulk adsorbent material in the form of beads exhibited adsorption behavior in three stages: surface adsorption, diffusion, and equilibrium.