• 제목/요약/키워드: Heterogeneous Transition

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전이 금속 산화물 기반 Interface-type 저항 변화 특성 향상 연구 동향 (Research Trends on Interface-type Resistive Switching Characteristics in Transition Metal Oxide)

  • 김동은;김건우;김형남;박형호
    • 마이크로전자및패키징학회지
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    • 제30권4호
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    • pp.32-43
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    • 2023
  • 저항 변화 메모리 소자(RRAM)는 저항 변화 특성을 기반으로 빠른 동작 속도, 간단한 소자 구조 및 고집적 구조의 구현을 통해 많은 양의 데이터를 효율적으로 처리할 수 있는 차세대 메모리 소자로 주목받고 있다. RRAM의 작동원리 중 하나로 알려진 interface type의 저항 변화 특성은 forming process를 수반하지 않고 소자 크기를 조절하여 낮은 전류에서 구동이 가능하다는 장점을 갖는다. 그 중에서도 전이 금속 산화물 기반 RRAM 소자의 경우, 정확한 물질의 조성 조절 방법과 소자의 신뢰성 및 안정성과 같은 메모리 특성을 향상시키기 위해 다양한 연구가 진행 중에 있다. 본 논문에서는 이종 원소의 도핑, 다층 박막의 형성, 화학적 조성 조절 및 표면 처리 등의 방법을 이용하여 interface type 저항 변화 특성의 저하를 방지하고 소자 특성을 향상시키기 위한 다양한 방법을 소개하고자 한다. 이를 통해 향상된 저항 변화 특성을 기반으로 한 고효율 차세대 비휘발성 메모리 소자의 구현 가능성을 제시한다.

An Approximate Analysis of the Queueing Systems with Two Deterministic Heterogeneous Servers

  • 김정섭
    • 한국경영과학회지
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    • 제24권2호
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    • pp.31-39
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    • 1999
  • A new approximation method for finding the steady-state probabilities of the number of customers present in queueing systems with Poisson arrivals and two servers with different deterministic service times with infinite waiting room capacity is developed. The major assumption made for the approximation is that the residual service times of the servers have mutually independent uniform distributions with densities equal to the reciprocals of the respective service times. The method reflects the heterogeneity of the servers only through the ratio of their service times, irrespective of the actual magnitudes and difference. The transition probability matrix is established and the steady-state probabilities are found for a variety of traffic intensities and ratios of the two service times; also the mean number of customers present in the system and in the queue, and server utilizations are found and tabulated. The method was validated by simulation and turned out to be very sharp.

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Strategies for Mutation Discovery in Retinitis Pigmentosa: Transition to the Next Generation

  • Yoon, Chang Ki;Yu, Hyeong Gon
    • Journal of Genetic Medicine
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    • 제10권1호
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    • pp.13-19
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    • 2013
  • Retinitis pigmentosa (RP) is the most common hereditary retinal disorder and is characterized by progressive retinal degeneration and decline in vision. RP comprises a heterogeneous group of disorders caused by various genetic variants. Since the first discovery of the causal mutation in the RHO gene using positional cloning, numerous mutations have been detected in more than 60 loci and 50 genes. However, causal genes have not been discovered in about 50% of cases. We attempt here to review the strategies to identify causal alleles of retinitis pigmentosa. These include conventional methods as well as state-of-the-art technologies based on next-generation sequencing.

The Seeding Effects on the Phase Transformation of Sol-Gel Derived PZT Powder

  • Lee, Hyun-Tae;Lee, Wan-In;Kim, Yoo-Hang;Whang, Chin-Myung
    • Bulletin of the Korean Chemical Society
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    • 제23권8호
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    • pp.1078-1084
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    • 2002
  • The formation temperature for the perovskite lead zirconate titanate [Pb(Zr,Ti)O3, PZT] derived from sol-gel route was lowered by more than $100^{\circ}C$ with the addition of crystallographically suitable seed particles, such as barium titanat e (BT) or PZT. We investigated the effect of seeding on the crystallization of perovskite phase and in the microstructure of the sol-gel derived PZT powder by varying the concentration, size and chemical species of seed particles. The phase transition as a function of temperature was monitored by DTA, XRD, and Raman spectroscopy, and the interface between the seed particle and grown PZT layer was analyzed by SEM and high resolution TEM techniques. It was found that both the heterogeneous and homogeneous nucleation contributes competitively in the formation of perovskite PZT grains.

TRANSIENT CHF PHENOMENA DUE TO EXPONENTIALLY INCREASING HEAT INPUTS

  • Park, Jong-Doc;Fukuda, Katsuya;Liu, Qiusheng
    • Nuclear Engineering and Technology
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    • 제41권9호
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    • pp.1205-1214
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    • 2009
  • The critical heat flux (CHF) levels that occurred due to exponential heat inputs for varying periods to a 1.0-mm diameter horizontal cylinder immersed in various liquids were measured to develop an extended database on the effect of high subcoolings for quasi-steady-state and transient maximum heat fluxes. Two main mechanisms of CHF were found. One mechanism is due to the time lag of the hydrodynamic instability (HI) which starts at steady-state CHF upon fully developed nucleate boiling, and the other mechanism is due to the explosive process of heterogeneous spontaneous nucleation (HSN) which occurs at a certain HSN superheat in originally flooded cavities on the cylinder surface. Steady-state CHFs were divided into three regions for lower, intermediate and higher subcooling at pressures resulting from HI, transition and HSN, respectively. HSN consistently occurred in the transient boiling CHF conditions that correspond to a short period. It was also found that the transient boiling CHFs gradually increased, then rapidly decreased and finally increased again as the period became shorter.

Equity across Generations and Uncertainty within a Generation: A Welfare Analysis of the National Pension System

  • KWON, KYOOHO
    • KDI Journal of Economic Policy
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    • 제41권2호
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    • pp.1-39
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    • 2019
  • This paper utilizes a life-cycle overlapping-generations model to quantify the welfare effects of plans to postpone the depletion of the National Pension Fund. In order for the model to incorporate the rapidly changing demographic structure of Korea fully, we build and calibrate a model in transition directly. The model is considered suitable for analyzing the effects of demographic changes on the Korean economy and the effects of plans to change the National Pension System. According to a simulation of the model, to postpone the depletion of the National Pension Fund for 30 years, the premium rate must be increased to 18.3% from the current rate of 9%. By postponing the depletion of the fund reserve, young and future generations gain significantly at the expense of the older generations. The simulation results should be, however, interpreted as meaning that the current system is unjustifiably partial to the older generations. Moreover, given the current premium rate, it is desirable to strengthen the income-redistribution function of the National Pension System.

Pressure titration of the monomeric variant of transthyretin

  • Bokyung Kim;Jin Hae Kim
    • 한국자기공명학회논문지
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    • 제27권1호
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    • pp.1-4
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    • 2023
  • Transthyretin (TTR) is an indispensable transporter protein of thyroxine and a retinol molecule in humans. TTR has a stable homo-tetrameric structure in its native state, while upon dissociation into monomers, it becomes aggregation-prone and can form an amyloid fibril. Although the amyloidogenic propensity of TTR has been known and investigated since the late 1990s, the structural information regarding TTR's amyloidogenic species is still elusive. Here, we employed high-pressure nuclear magnetic resonance (HP-NMR) approaches on the monomeric variant of TTR (TTR[F87M/L110M]; M-TTR) and observed that it experiences a two-step transition in response to the pressurized condition. Our study demonstrated that M-TTR in an ambient condition has heterogeneous structural features, which is likely related to the amyloidogenic propensity of TTR.

P123-Templated Co3O4/Al2O3 Mesoporous Mixed Oxides for Epoxidation of Styrene

  • Jung, Mie-Won;Kim, Young-Sil
    • 한국재료학회지
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    • 제22권6호
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    • pp.316-320
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    • 2012
  • $Co_3O_4$, $Al_2O_3$ and $Co_3O_4$/$Al_2O_3$ mesoporous powders were prepared by a sol-gel method with starting matierals of aluminum isopropoxide and cobalt (II) nitrate. A P123 template is employed as an active organic additive for improving the specific surface area of the mixed oxide by forming surfactant micelles. A transition metal cobalt oxide supported on alumina with and without P123 was tested to find the most active and selective conditions as a heterogeneous catalyst in the reaction of styrene epoxidation. A bBlock copolymer-P123 template was added to the staring materials to control physical and chemical properties. The properties of $Co_3O_4$/$Al_2O_3$ powder with and without P123 were characterized using an X-ray diffractometer (XRD), a Field-Emission Scanning Electron Microscope (FE-SEM), a Bruner-Emmertt-Teller (BET) surface analyzer, and $^{27}Al$ MAS NMR spectroscopy. Powders with and without P123 were compared in catalytic tests. The catalytic activity and selectivity were monitored by GC/MS, $^1H$, and $^{13}C$-NMR spectroscopy. The performance for the reaction of epoxidation of styrene was observed to be in the following order: [$Co_3O_4$/$Al_2O_3$ with P123-1173 K > $Co_3O_4$/$Al_2O_3$ with P123-973 K > $Co_3O_4$-973 K>$Co_3O_4$/$Al_2O_3$-973 K > $Co_3O_4$/$Al_2O_3$ with P123-1473 K > $Al_2O_3$-973 K]. The existence of ${\gamma}$-alumina and the nature of the surface morphology are related to catalytic activity.

Heterogeneous Catalysts for Hydrogen Generation Based on Ru-Incorporated Hydroxyapatite

  • Jaworski, Justyn Wayne;Kim, Dae-Hyun;Jung, Kyeong-Mun;Kim, So-Hue;Jeong, Jong-Ok;Jeon, Hyo-Sang;Min, Byoung-Koun;Kwon, Ki-Young
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.319-319
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    • 2011
  • Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol $H_2$/ mol Ru. Moreover, we observe that the RuHAP support exhibits a high catalytic lifetime of approximately one month upon repeated exposure to $NaBH_4$ solutions. In addition to examining surface area effects, we also identified the role of complex surface morphology in enhancing hydrolysis by the catalytic transition metal covered surface. Particularly, we found that a polycrystalline RuHAP catalytic support exhibits shorter induction times for the initial bubble formation as well as increased hydrogen generation rates as compared to a single crystal supports. The independent factor of a complex surface morphology is believed to provide enhanced sites for gas release during the initial stages of the reaction. By demonstrating the ability to shorten induction time and enhance catalytic activity through changes in surface morphology and Ru content, we find it feasible to further explore this catalyst support in the construction of a practical hydrogen generator.

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LTE-Advanced 기반 이기종 네트워크 시스템의 간섭회피를 위한 효율적인 자원할당 기법 (Efficient Resource Allocation Technique for LTE-Advanced based Interference Avoidance of Heterogeneous Network)

  • 장성원;성현경
    • 융합신호처리학회논문지
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    • 제17권1호
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    • pp.46-52
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    • 2016
  • LTE-Advanced 시스템은 한정된 주파수 자원을 효율적으로 이용할 수 있도록 다수의 셀들로 구성된 셀룰러 환경에서 구축되기 때문에 인접 셀과의 간섭 회피를 고려해야 한다. 이동통신 기술의 발전에 따라 스마트폰과 태블릿 등 많은 모바일 데이터 트래픽을 유발시키는 단말이 확산되고 음성위주의 이동 통신 서비스에서 무선 멀티미디어 콘텐츠를 중심으로 하는 데이터 위주의 서비스로 전환됨에 따라 급증하는 모바일 데이터 트래픽에 의해 도심지역에서 증가되는 기지국은 막을 수 없는 현실이다. 증가되는 기지국으로 인해 송신 신호가 수신단에서 섞이는 셀간 간섭은 피할 수 없게 되었으며 이로 인해 셀간 간섭 회피 기법의 성능은 통신성능을 평가하는 중요한 지표 중 하나가 로 작용한다. 본 논문에서는 19셀의 셀룰러 시스템 모델을 바탕으로 LTE-Advanced 시스템 레벨 시뮬레이터를 통해 시뮬레이션을 수행하여 셀 경계에서의 성능 향상을 위한 새로운 Hybrid 자원 할당 기법을 제안한다.