• Title/Summary/Keyword: Heterocharge

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Low molecular weight components and space charge formation in LDPE (저분자량성분과 저밀도폴리에틸렌의 공간전하형성과의 관계)

  • 구중회;한재홍;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.87-89
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    • 1994
  • The effects of low molecular weight components of LDPE and sample molding condition were investigated to find the orgins for heterocharge in LDPE without any addtives. Low molecular weight chains of LDPE encourages the formation of heterocharge by being charged and migrating the counter electrode. The formation of heteroohage in LDPE was also effected by sample preparation process and the kind of a moling film. When PET film is used as a molding layer, the carbonyl, which may lead to increase the heterocharge, formed at surface of LDPE.

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Charge Distributions in Polyethylene/Ethylene n-Butyl Acrylate Blends (Polyethylene/Ethylene n-Butyl Acrylate Blends의 전하형성특성)

  • Kim, Ok;Lee, Chang-R.;Lee, Mi-Kyung;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.143-147
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    • 1995
  • The space charge formation in polyethylene (PE)/ethylene n-butyl acrylate (EnBA) blends were investigated. Heterocharge was found in PE and EnBA containing 5 mole% of nBA while homocharge was found in EnBAs containing 19 and 20% of nBA. All PE/EnBA blends except the one with the EnBA containing 5% nBA showed heterocharge formation. Heterocharge was also found in crosslinked PE/EnBA blends, which was attributed to the volatile residuals generated by the thermal decomposition of peroxide.

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Space charge characteristics in several polymers at high temperature (고분자 재료의 고온하분포특성)

  • 남진호;고정우;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.84-87
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    • 2001
  • Space charge formation at high temperature was investigated in several polymers using pulsed electro-acoustic (PEA) method. In SXLPE, homocharge is found and increased as an increase of temperature. In a charge of polarity of poling voltage(positive to negative), space charge mainly cause of hole injection. In Ionomer, heterocharge is found because of ion. As an increase of temperature heterocharge is also increased. In PET, As an increase of temperature homocharge is decreased.

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SPACE CHARGE IN LDPE OF DIFFERENT MOLECULAR CHARACTERISTICS (재료특성에 따른 LDPE의 전하형성)

  • Han, Jae-H.;Koo, Jung-H.;Lee, Kyung-Wan;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1262-1264
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    • 1994
  • Effects of molecular characteristics such as melt index and shapes of molecular weight distribution on the charge formation in LDPE have been investigated. Both homocharge and heterocharge were observed in LDPE depending on the value of melt index. It was found that the LDPE having intermediate melt indices shows heterocharge while the LDPE having small and high melt indecies shows homocharge. The shapes of molecular weight distributions were also found to affect the space charge in LDPE. These were explained by the role of short chains having low molecular weight in LDPE.

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Characteristic Comparison of Raw Materials Used for Power Cable Insulation (전력케이블 절연층용 원재료의 특성비교)

  • Oh, Woo-Jeong;Ko, Jung-Woo;Kim, Jong-Eun;Suh, Kwang-S.;Lee, Gun-Ju
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.302-304
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    • 1997
  • Chemical structure and electrical properties such as water treeing and space charge accumulation of various raw materials(XLPE) used for power cable insulation were investigated. It was found that chemical structure was changed after crosslinking reaction and every materials have different amounts of DCP and antioxidant. Electrical properties were also changed after extraction using $CHCl_3$ and xylene. Water tree length was smaller with additives such as DCP and antioxidant and bigger with low molecular weight components of polyethylene than that of extracted samples. Heterocharge was changed into homocharge after extraction. This shows that additives and low molecular weight components of polyethylene cause the heterocharge.

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SPACE CHARGE IN PE LAMINATE (PE Laminate의 공간전하 형성)

  • Roh, Hong-S.;Lee, Jae-Y.;Han, Jae-H.;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1428-1430
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    • 1994
  • The accumulation of space charge in PE/PE/PE laminates was investigated using the low density polyethylenes having different melt indices from 0.25 to 45 g/10 min. Both heterocharge and homocharge accumulated in parent polyethylenes depend on the value of melt index. A general rule found in this study was that the heterocharge decreases as the melt index increases and finally the homocharge accumulates when the melt index is very high. Because of this reason, PE laminates showed different charge formation characteristics depending on melt index of polyethylene. Details of up to date results are described in the text.

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A study on the analysis of carrier properties and trap energy depth in the low-density polythylene electrets (저밀도 폴리에틸렌 일렉트렉트에 있어서 케리어의 성질과 Trap 깊이 해석에 대한 연구)

  • 이준웅
    • 전기의세계
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    • v.29 no.8
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    • pp.511-518
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    • 1980
  • The thermostimulated discharge currents of low-density polyethylene electrets were measured versus the principal experimental variables. Several electrode types were used for the charging and discharging procedures. The results led to know the experimental conditions for the heterocharge and homocharge accumulating and decreasing. The electronic structure parameters of polyethylene such as trap level, density of traps, hopping length, mobility, trap time constants were deduced. A method for evaluating the local electric field inside the electret is proposed.

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Interfacial charge Behaviors in XLPE/SXLPE Laminates (XLPE/SXLPE laminate의 계면전하 거동)

  • 고정우;남진호;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.897-900
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    • 2001
  • Space charge distributions in silane crosslinked polyethylene (SXLPE)/ crosslinked polyethylene (XLPE) laminates was investigated using a pulsed electroacoustic (PEA) method. XLPE shows heterocharge while SXLPE shows homocharge. Positive charge is accumulated at the interface of SXLPE/XLPE laminate when applied electric field is more than 20 kV/mm. The charge profile at various temperatures was also acquired using temperature-controllable PEA system. Although applied electric field is only 8.6 kV/mm, positive interfacial charge starts to appear near 50$^{\circ}C$.

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Characteristics of Charge Formation in the EPDM/XLPE Laminate (EPDM/XLPE Laminate의 전하형성 특성)

  • 박성국;남진호;서광석;이철호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.287-290
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    • 1996
  • The behaviour of interfacial charge in EPDM/XLPE laminates has been investigated by measuring charge distributions using a pulsed electroacoustic (PEA) method. Homocharge develops in EPDM while heterocharge develops in XLPE. A broadly interfacial charge peak is observed at EPDM/XLPE interface. When EPDM /XLPE laminates are treated in high temperature for different times, the amount and polarity of interfacial charge are changed.

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