• Title/Summary/Keyword: Hemicellulose

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The Change of Kenaf Fiber Characteristics by the Contents of Noncellulosic Material (비셀룰로오스 함량에 따른 케나프 섬유의 특성변화)

  • Lee, Hye-Ja;Han, Young-Sook;Yoo, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.11 s.158
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    • pp.1581-1588
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    • 2006
  • The effects of removal of lignin or hemicellulose on the cottonizing and pulping characteristics of kenaf fiber were studied by comparing the conditions of non-cellulosic material contents, fiber lengths and dyeability. And the effects of lignin or hemicellulose on dyeability of the kenaf fiber using CI Direct Green 26 and CI Direct Red 81 were investigated. The results were as follows. The lignin contents decreased and the kenaf fiber became shorter and finer as the reaction time with sodium chlorite increased. The hemicellulose could be removed by treating sodium hydroxide solution to the fiber from which the lignin partly removed. The 80% of hemicellulose could be removed by 5% of sodium hydroxide solution in 5 minutes. But if lignin were not removed at all, hemicellulose could not be removed. The fiber lengths proper for apparel were obtained after treating sodium chlorite for 10-20 minutes and those for pulping were obtained after treating sodium chlorite for 40 minutes. The kenaf fibers from which lignin and hemicellulose partly removed were dyed with CI Direct Green 26 and CI Direct Red 81. Their dyeability increased as the removal rates of lignin increased. The ${\Delta}E$ values of kenaf fiber dyed with CI Direct Green 26 were lower than CI Direct Red 81.

Studies on the Nonstarchy Polysaccharides of Korean Ginseng, Punux ginseng C. A. Meyer 1. Cotent and Composition of dietary fober, hemicellulose, cellulose, lignin and pectin. (고려인삼(Panax ginseng C.A. Meyer)의 비전분성 다당류에 관한 연구 1. Dietary fibre, hemicellulose, Cellulose, lignin 및 Pectin 함량과 조성)

  • 민경천;조재순
    • Journal of Ginseng Research
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    • v.8 no.2
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    • pp.91-104
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    • 1984
  • This study was conducted to investigate the characteristics of nonstarchy polysaccharides in Korean ginseng, (Panax ginseng C.A. Meyer). The results obtained are as follows. 1. The total sugar content of ginseng roots were decreased with increasing the cultural period. On the other hand, the crude fiber content was increased with that of the ginseng leaves or stems. But the crude fiber in root was much less than that of leaves and stems. 2. The dietary fiber content of ginseng root on 5 years old was 14.20% as neutral detergent fiber, 9.08% as acid detergent fiber, hemicellulose 5.12%, cellulose 7.98% and lignin of 1.10%, respectively. 3. Much more pectin was found in ginseng roots which was cultivated for shooter Period. And it was contained much more in the root than in the leaves and stems. 4. ginseng hemicellulose content in root was 5% to 10%. It was decreased with increasing: cultivated period. Hemicellulose was constituted of xylose, arabinose, glucose, rhamnose and xylose of these sugars was the predominant. 5. X-ray diffraction Pattern of ginseng cellulose showed maximum intensity at tile interplanar angle of 4.1$^{\circ}$.

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Engineering of Sulfolobus acidocaldarius for Hemicellulosic Biomass Utilization

  • Lee, Areum;Jin, Hyeju;Cha, Jaeho
    • Journal of Microbiology and Biotechnology
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    • v.32 no.5
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    • pp.663-671
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    • 2022
  • The saccharification of cellulose and hemicellulose is essential for utilizing lignocellulosic biomass as a biofuel. While cellulose is composed of glucose only, hemicelluloses are composed of diverse sugars such as xylose, arabinose, glucose, and galactose. Sulfolobus acidocaldarius is a good potential candidate for biofuel production using hemicellulose as this archaeon simultaneously utilizes various sugars. However, S. acidocaldarius has to be manipulated because the enzyme that breaks down hemicellulose is not present in this species. Here, we engineered S. acidocaldarius to utilize xylan as a carbon source by introducing xylanase and β-xylosidase. Heterologous expression of β-xylosidase enhanced the organism's degradability and utilization of xylooligosaccharides (XOS), but the mutant still failed to grow when xylan was provided as a carbon source. S. acidocaldarius exhibited the ability to degrade xylan into XOS when xylanase was introduced, but no further degradation proceeded after this sole reaction. Following cell growth and enzyme reaction, S. acidocaldarius successfully utilized xylan in the synergy between xylanase and β-xylosidase.

Studies on the Utilization of Straw for Production of Glucose Isomerase (볏짚을 이용한 Glucose Isomerase 생산에 관한 연구)

  • Han, Youn-Woo;W. P. Chen
    • Microbiology and Biotechnology Letters
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    • v.7 no.1
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    • pp.9-14
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    • 1979
  • The hemicellulose fraction of ryegrass straw was extracted with NaOH and used for production of glucose isomerase by Streptomyces flavogriseus. Up to 25% crude hemicellulose (20% as pentosan) could he obtained by treating straw with 1 to 24% NaOH. The yield of hemicellulose was increased proportionately with increasing NaOH concentration up to 4%, but the rate of increase was slowed thereafter. The optimum condition for hemicellulose extraction from ryegrass straw was to treat straw with 4% NaOH for 3hrs at 9$0^{\circ}C$ or 24hrs at 3$0^{\circ}C$. Highest level of glucose isomerase activity (3.04 units/ml culture) was obtained when the organism was grown for 2 days at 3$0^{\circ}C$ on 2% straw hemicellulose. The organism also produced a good quantity of glucose isomerase on xylan, xylose or H$_2$SO$_4$-hydrolysate of straw. The hemicellulose-extracted straw residue could be used as animal feed, because the residue had 75% higher digestibility and 20% better feed efficiency for weanling meadow voles than the untreated straw.

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Effect of Hydrogen Peroxide on Pretreatment of Oakwood in a Percolation Process (Percolation 공정에서 참나무의 전처리에 과산화수소가 미치는 영향)

  • 하석중;김성배;박순철
    • KSBB Journal
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    • v.14 no.3
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    • pp.358-364
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    • 1999
  • The effect of hydrogen peroxide on pretreatment of oakwood was investigated. Reaction temperature was $170^{\circ}C$ and reaction solutions used in pretreatment were aqueous ammonia, sulfuric acid and pure water. When 10% ammonia solution was used, the extents of delignification and hemicellulose recovery were 55% and 26%, respectively. These values were significantly higher as delinigfication and lower as hemicellulose recovery than those of acid hydrolysis. To overcome this problem, hydrogen peroxide was added into ammonia solution stream to increase hemicellulose recovery. But delignification and hemicellulose recovery were not increased as much as hydrogen peroxide loading was increased. And as hydrogen peroxide loading was increased, the decomposition of sugars solubilized from hemicellulose and cellulose were increased. So there were significant differences between the total amount in solid residue and liquid hydrolyzate, and the total amount in the original biomass. It was found that hydrogen peroxide added was reacted with substrate packed mostly in the front part of reactor. In order to increase hemicellulose recovery, it was necessary to treat with acidic solution than with alkali solution. Effect of hydrogen peroxide was higher in water than acid solution.

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Softening Related Changes in Cell Wall Polysaccharides of Hot Pepper Fruit (고추과실 세포벽 다당류의 연화에 따른 변화)

  • Kim, Soon-Dong;Yoon, Soo-Hong;Kang, Meung-Su;Park, Nam-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.15 no.2
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    • pp.165-170
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    • 1986
  • Various cell wall polysaccharides such as IAP(ionically associated pectin), CBP(covalently bounded pectin), HF(hemicellulosic fraction) and CF(cellulosic fraction) were fractionated by chemical method from hot pepper fruit cell wall during ripening and softening. And then, the composition of the polysaccharides were determined. The IAP and CBP were composed of $65{\sim}88%$ polyuronide, $4{\sim}29%$ hemicellulose and $0.3{\sim}2.1%$ cellulose. And hemicellulose also contained $8{\sim}13%$ polyuronide and $0.1{\sim}1.1%$ cellulose. The containing ratio of hemicellulose associated with the CBP was higher than IAP. All of the polysaccharides except CF decreased by the turning stage showed softening. The polyuronide made up IAP changed little but, that of the CBP increased during softening owing mainly to decrease of the hemicellulose that was bounded to the CBP and was mostly linked to galactose.

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Dietary Effect of Hemicellulose from Soy Fiber on Blood Glucose and Cholesterol Content in Streptozotocin-Induced Diabetic Rats (콩 식이섬유로부터 추출한 헤미셀룰로즈의 식이가 Streptozotocin유도 당뇨 흰쥐의 혈당과 혈청 콜레스테롤 함량에 미치는 영향)

  • 이명예;김미경;신진기;김순동
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.7
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    • pp.1119-1125
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    • 2004
  • The effect of hemicellulose extracted from soy fiber on the level of blood glucose and serum cholesterol in the streptozotocin-induced diabetic rat were investigated. The experimental plots were divided to cellulose group (control, 0.5% hemicellulose group (H-l) and 1% hemicellulose group (H-2) group. The groups were fed for 6 weeks, then fed for 1 week more after streptozotocin injection. Food intakes, weight gain and food efficiency ratio of H-2 group were higher, while water intakes and liver weight were lower than those of control and H-l group. The content of blood glucose and urine glucose were 212.8 mg/dL, 0.97 mg/dL in the control group, 160.5 mg/dL, 0.53 mg/dL in the H-l group, 141.0 mg/dL, 0.35 mg/dL in the H-2 group, respectively. There was no significantly difference in the content of neutral lipid, while the content of total serum cholesterol was 101.6 mg/dL in the control group, 73.8-78.4 mg/dL in the hemicellulose groups. The content of serum HDL-cholesterol in the all experimental groups showed no significantly difference showing 39.8-44.7 mg/dL. HTR and atherogenic index were 0.44 and 1.27 in the control group, but 0.54 and 0.46-0.85 in the hemicellulose groups, respectively.

The Effects of Different Moisture Content and Ensiling Time on Silo Degradation of Structural Carbohydrate of Orchardgrass

  • Yahaya, M.S.;Kawai, M.;Takahashi, J.;Matsuoka, S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.2
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    • pp.213-217
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    • 2002
  • This study determined the influence of moisture, ensiling time and their interactions on the losses of hemicellulose and cellulose during ensiling of orchardgrass. Orchardgrass containing 80 (HM), 70 (MM) and 55% (LM) moisture was ensiled in 3 laboratory silos of 500 ml capacity for 3, 7, 21 and 91 days. The dry matter (DM), water-soluble carbohydrates (WSC), hemicellulose and cellulose contents of the ensiled orchardgrass was lowered than that of the untreated grass regardless of moisture content. Ensiling orchardgrass for 91 days (d) decreased (p<0.01) hemicellulose contents from 19 to 15%, 20 to 15% and 18 to 12% and cellulose from 31 to 29%, 29 to 26% and 27 to 26% for LM, MM and HM silage, respectively. Results from fermentation of LM and MM silages were within acceptable guidelines except for butyric acid and ammonia after 3 weeks of ensiling of MM which appeared to be lower than ideal. The results of the fermentation of HM silages were poor showing higher concentration of acetic, propionic and butyric acids and traces of isovaleric, valeric and caproic acids with ammonia at all stage of time. While the DM losses from LM and MM silages over the ensiling period were acceptable, that for HM silage increased to 13% after 91 d ensiling, confirming a poor fermentation process occurred. The greatest WSC losses occurred within 7 d of ensiling and the lowest losses occurred after 3 weeks of ensiling. Except in HM silage, the hemicellulose and cellulose losses were highest (p<0.01) in the first 3 weeks of ensiling. Hemicellulose losses were between 19 and 22% and 4.2 and 5.9% up to 3 weeks and after 3 weeks of ensiling LM and MM silages, respectively. Cellulose losses were small. In contrast, hemicellulose losses after 3 weeks of ensiling of HM silage was about 50% higher than over the first 3 weeks possibly due to clostridial type fermentation. The results showed that increasing ensiling time of high moisture orchardgrass would result in the excessive losses of DM, WSC, hemicellulose and cellulose in the silage.

Degradation Properties and Production of Fuels from Hemicellulose by Pyrolysis-liquefaction (열분해액화반응에 의한 헤미셀룰로오스의 분해특성 및 연료물질 생성)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.199-204
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    • 2008
  • Hemicellulose, consisteing of pentose as xylose and mannose, is usable as high octane fuels and heavy oil additives if depolymerized to monomer unit. In this study, thermochemical degradation by pyrolysis-liquefaction of hemicellulose, the effects of reaction temperature, conversion yield, degradation properties and degradation products were investigated. Experiments were performed in a tube reactor by varying reaction temperatures from $200^{\circ}C$ to $400^{\circ}C$ at 40 min of reaction time. The liquid products from pyrolysis-liquefaction of hemicellulose contained various kinds of ketones. Ketones, as 2,3-dimethyl-2-cyclopenten-1-one, 2,3,4-trimethyl-2-cyclopentan-1-one, and 2-methyl-cyclopentanone, could be used as high-octane-value fuels and fuel additives. However, phenols are not valuable as fuels. Combustion heating value of liquid products obtained from thermochemical conversion processes of hemicellulose was in the range of 6,680~7,170 cal/g. After 40 min of reaction at $400^{\circ}C$ in pyrolysis-liquefaction of hemicellulose, the energy yield and mass yield were as high as 72.2% and 41.2 g oil/100 g raw material, respectively.

Extraction and Component Sugar Analysis of Polysaccharides from Buckwheat (메밀의 다당류 추출과 구성당 분석)

  • Lee, Jung-Sun;Ra, Kyung-Soo;Son, Heung-Soo
    • Korean Journal of Food Science and Technology
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    • v.27 no.6
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    • pp.860-865
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    • 1995
  • This study was conducted to extract and isolate the polysaccharides from buckwheat. Also the sugar composition of the polysaccharides was investigated. The soluble and indigestible polysaccharides were isolated from supernatant and residue after enzyme treatment of raw, roast and steam buckwheat. The yields of low molecular weight soluble polysaccharides(LMS-P: MW<10 Kda) and high molecular weight soluble polysaccharides(HMS-P: MW>10 Kda) were $74.9{\sim}84.2%$ and $5.5{\sim}9.4%$, respectively. The yields of indigestible polysaccharides were low molecular weight insoluble polysaccharides; $0.8{\sim}4.2%$, crude hemicellulose; $3.2{\sim}9.6%$, alcohol insoluble hemicellulose; $0.9{\sim}1.7%$, residue; $2.0{\sim}2.4%$, respectively. The free sugars were detected in the soluble polysaccharides and low molecular weight insoluble polysaccharides but were not detected in the crude hemicellulose, alcohol insoluble hemicellulose and residue. The protein of all fraction were detected and the content was $1.0{\sim}18.9%$. The main sugar of soluble polysaccharides was glucose and the indigestible polysaccharides were composed of glucose, arabinose, rhamnose, xylose, mannose and galactose.

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