• Nuclear Engineering and Technology
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• v.54 no.2
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• pp.627-636
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• 2022

In nuclear power plants and other nuclear facilities the removal of cobalt from radioactive liquid waste is needed to reduce the radioactivity concentration in effluents. In liquid wastes containing strong organic complexing agents such as EDTA cobalt removal can be problematic due to the high stability of the Co-EDTA complex. In this study, the removal of cobalt from NaNO₃ solutions using antimony oxide (Sb₂O₃) synthesized from potassium hexahydroxoantimonate was investigated in the absence and presence of EDTA. The uptake studies on the ion exchange material were conducted both in the dark (absence of UV-light) and under UV-C irradiation. Ca²⁺ or Ni²⁺ were included in the experiments as competing cations to test the selectivity of the ion exchanger. Results show that UV-C irradiation noticeably enhances the cobalt sorption efficiency on the antimony oxide. It was shown that nickel decreased the sorption of cobalt to a higher extent than calcium. Finally, the sorption data collected for Co²⁺ on antimony oxide was modeled using six different isotherm models. The Sips model was found to be the most suitable model to describe the sorption process. The Dubinin-Radushkevich model was further used to calculate the adsorption energy, which was found to be 6.2 kJ mol^-1.

• Smart Structures and Systems
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• v.30 no.3
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• pp.221-237
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• 2022

This paper is concerned with nonlinear modeling and efficient numerical simulation of electrostrictive materials and structures. Two types of such materials are considered: relaxor ferroelectric ceramics and electrostrictive polymers. For ceramics, a geometrically linear formulation is developed, whereas polymers are studied in a geometrically nonlinear regime. In the paper, we focus on constitutive modeling first. For the reversible constitutive response under consideration, we introduce the augmented Helmholtz free energy, which is composed of a purely elastic part, a dielectric part and an augmentation term. For the elastic part, we involve an additive decomposition of the strain tensor into an elastic strain and an electrostrictive eigenstrain, which depends on the polarization of the material. In the geometrically nonlinear case, a corresponding multiplicative decomposition of the deformation gradient tensor replaces the additive strain decomposition used in the geometrically linear formulation. For the dielectric part, we first introduce the internal energy, to which a Legendre transformation is applied to compute the free energy. The augmentation term accounts for the contribution from vacuum to the energy. In our formulation, the augmented free energy depends not only on the strain and the electric field, but also on the polarization and an internal polarization; the latter two are internal variables. With the constitutive framework established, a Finite Element implementation is briefly discussed. We use high-order elements for the discretization of the independent variables, which include also the internal variables and, in case the material is assumed incompressible, the hydrostatic pressure, which is introduced as a Lagrange multiplier. The elements are implemented in the open source code Netgen/NGSolve. Finally, example problems are solved for both, relaxor ferroelectric ceramics and electrostrictive polymers. We focus on thin plate-type structures to show the efficiency of the numerical scheme and its applicability to thin electrostrictive structures.

• Journal of Sensor Science and Technology
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• v.31 no.3
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• pp.175-179
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• 2022

The physical properties of biomaterials are important for their isolation and separation from body fluids. In particular, the precise evaluation of the multi-physical properties of single biomolecules is essential in that the correlation between physical and biological properties of specific biomolecule. However, the majority of scientific equipment, can only determine specific-physical properties of single nanoparticles, making the evaluation of the multi-physical properties difficult. The improvement of analytical techniques for the evaluation of multi-physical properties is therefore required in various research fields. In this study, we developed a motion-tracking algorithm to evaluate the multi-physical properties of single-nanoparticles by analyzing their behavior. We observed the Brownian motion and electric-field-induced drift of fluorescent nanoparticles injected in a microfluidic chip with two electrodes using confocal microscopy. The proposed algorithm is able to determine the size of the nanoparticles by i) removing the background noise from images, ii) tracking the motion of nanoparticles using the circular-Hough transform, iii) extracting the mean squared displacement (MSD) of the tracked nanoparticles, and iv) applying the MSD to the Stokes-Einstein equation. We compared the evaluated size of the nanoparticles with the size measured by SEM. We also determined the zeta-potential and surface-charge density of the nanoparticles using the extracted electrophoretic velocity and the Helmholtz-Smoluchowski equation. The proposed motion-tracking algorithm could be employed in various fields related to biomaterial analysis, such as exosome analysis.

• The Journal of the Acoustical Society of Korea
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• v.26 no.1
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• pp.32-41
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• 2007

The control room has been usually designed by the consideration of only one listening position for the sound engineer. By this study. many listening positions with the very similar acoustical condition were located in the specific region, so-called 'the reflection free zone', where the several engineer could evaluate the quality of sound at the same time. For constructing the reflection free zone, the control room has been designed by the concept of the $LEDE^{TM}$, and the initial time delay gap has been controled by the structure of control room and the properties of sound-absorbing materials. diffuser, Helmholtz resonator and image source of sound. The occurrence of any harmful phenomena like the standing wave, acoustic focusing. coloring. Hass effect and flutter echo, has greatly reduced in the reflection free zone.

• Journal of Platform Technology
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• v.12 no.1
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• pp.119-127
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• 2024

This paper utilized electromagnetic field energy as an external stimulus to enhance the germination rate of acacia(Robinia pseudoacacia) seeds. Electromagnetic field energy comprises three types: static magnetic field(SMF) energy, static electric field(SEF) energy, and microwave(MW) energy. When SMF energy was applied to seeds through a dry method for 90 minutes, the germination rate increased by more than 10% compared to the control group. Similarly, SEF energy applied through a dry method for 90 minutes resulted in an improvement of over 20% in the germination rate. Furthermore, when MW energy at 2.45 GHz was applied to the seeds through a wet method for 3 minutes, the germination rate increased by over 25%. Experimental results showed that seeds treated with MW energy exhibited the highest germination rate and the greatest sprout growth. Consequently, this paper confirms that treating seeds with MW energy through a wet method yields the most superior germination rate and seedling growth.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.2
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• pp.139-144
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• 2015

Recently, to realize sound-absorbing structures, we have to insert sound-absorbing materials into wall. These shapes are taken limitations because sound-absorbing materials should be fixed. Therefore, the sound absorption is changed by environment that used the sound-absorbing materials. On the other hand, we will take same effect without sound-absorbing material, if we change the shape of wall to sound absorbing structure. If we use this sound absorbing structure, we can get benefits by removing limitation of materials. Therefore we suggest perforated plate for effective sound-absorbing structure. We confirmed the function of sound-absorption of this structure using equivalent property. Then, we found the similarity between perforated plate and resonator. Also, we verify these theories through computer simulation by FEM(Finite Element Method). Finally, we validated that perforated plate has function of sound absorption without sound-absorbing material. This perforated plate is used for sound-absorbing material of buildings and transportations such as vehicle, train etc. Also, these results could be further used basic tool for design of sound-absorption structure.

• Tunnel and Underground Space
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• v.25 no.4
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• pp.320-331
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• 2015

This paper presents a case study of an enhanced geothermal system(EGS) demonstration project conducted in $Gro{\ss}$ $Sch{\ddot{o}}nebeck$, Northerm Germany, focusing on hydraulic stimulation. The project was conducted with doublet system in sandstone and volcanic formations at 4 - 4.4 km depth. Under normal faulting to strike-slip faulting stress regime, hydraulic stimulations were conducted at injection and production wells by massive waterfrac and gel-proppant fracturing. Injectivity index increased from $0.97m^3/(hr^*MPa)$ to $7.5m^3/(hr^*MPa)$ and productivity index increased from $2.4m^3/(hr^*MPa)$ to $10.1m^3/(hr^*MPa)$ by a series of hydraulic stimulations at both wells. After circulation tests through injection and production wells, however, productivity index decreased from $8.9m^3/(hr^*MPa)$ to $0.6m^3/(hr^*MPa)$ in two years. Slip tendency analysis for the stimulation in volcanic layer estimated the required pressure for shear slip and its preferred orientations and it showed reasonable match with actual stimulation results. Through the microseismicity observation for the stimulation of volcanic formation, only 80 seismic events with its moment magnitudes in -1.8<$M_W$<-1.0 were observed, which are unexpectedly low for EGS hydraulic stimulation.

• Textile Coloration and Finishing
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• v.1 no.1
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• pp.19-25
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• 1989

In past, dye diffusion and dyeing rate in fibers have been emphasized in dyeing phenomena. However, in the light of the properties of colloids in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Electrostatic bonding, hydrogen bonding and Van der Waals adsorption are common in dyeing as well as covalent bonding. Particularly, electrostatic bonding is premised on the existance of ionic radicals in fibers. The present study was aimed to clarify the electrokinetic phenomena of dyeing through the role of electric double layer by ion in amphoteric fibers with different ionic effects under different pH. Spectrophotometric analysis method was used to compare dyeing condition of surface, which can be detected by electrokinetic phenomena and the inner of fibers after deceleration of dyed fibers. Nylon and wool, the typical amphoteric fibers were dyed with monoazo acid dyes such as C.I. Acid Orange 20, and C.I. Acid Orange 10. Various combinations were prepared by combining pH, temperature and dye concentration, in order to generate streaming electric potential which were measured by microvolt meter and specific conductivity meter. The results were transformed to zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers. The amount of dyes of inner fibers were also measured by the Lambert-Beer’s law. The main results obtained are as follows. 1. By measuring zeta pontential, it was possible to detect the dyeing mechanism, surface charge density, surface dye amount and effective surface area concerning dye adsorption of the amphoteric fibers. 2. Zeta pontential increases in negative at low pH and high dye concentration in the process of dyeing. This implied that there existed ionic bond formation in the dyeing mechanism between acid dyes and amphoteric fibers. 3. Dibasic acid dye had little changing rate in zeta potential due to the difference in solubility of dye and in number of dissociated ions per dye molecule to bond with amino radicals of amphoteric fibers. The dye adsorption of mono basic acid dye was higher than that of dibasic acid dye. 4. The effective surface areas concerning dyeing were $6.3E+05\;cm^2/g$ in nylon, $1.6E+07\;cm^2/g$ in wool fiber being higher order of wool then nylon.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.7
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• pp.677-687
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• 2017

Aircraft can often be exposed to a variety of environments and vibrations such as engine, hydraulic pump, aerodynamic force. These may cause cracking and destruction of the mechanical structure and sub-components by high-cycle fatigue. The axial piston type pump which is usually applied to the aircraft hydraulic pump can be necessarily accompanied by the fluid pulsation by continuous rotation of the axial piston. The fatigue crack was identified at the dampener fitting welding zone to prevent vibration damping during the running of aircraft equipped with this type of pulsation hydraulic pump. In order to understand the root cause of this matter, fracture and component analyses were carried out and also integral type dampener fitting was applied to prevent recurrence of the crack as a subject of design improvements. Structural integrity stress analysis, fatigue analysis, qualification test and aircraft system equipped test was conducted to verify the design validity in application to integral type dampener fitting. The test results were sufficiently satisfactory with the demand lifetime of the material from the various types of test as conducted and the subject of design improvement in this study could be objectively evaluated that shall be applied to the operational aircraft.

• Journal of Astronomy and Space Sciences
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• v.26 no.4
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• pp.499-510
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• 2009

In this paper, relative orbit of Low Earth Orbit satellites is determined using only GPS measurements and the effects of Equatorial Spread-F (ESF), that is one of biggest ionospheric irregularities, are investigated. First, relative orbit determiation process is constructed based on doubly differenced GPS observations. In order to see orbit determination performance, relative orbit of two GRACE satellites is estimated for one month in 2004 when no ESF is observed. The root mean square of the achieved baselines compared with that from K-Band Ranger sensor is about 2~3 mm and average of 95% of ambiguities are resolved. Based on this performance, the relative orbit is estimated for two weeks of two difference years, 2003 when there are lots of ESF occurred, and 2004 when only few ESF occurred. For 2003, the averaged baseline error over two weeks is about 15 mm. That is about 4 times larger than the case of 2004 (3.6 mm). Ionospheric status achieved from K-Band Ranging sensor also shows that more Equatorial Spread-F occurred at 2003 than 2004. Investigation on raw observations and screening process revealed that the ionospheric irregualarities caused by Equatorial Spread-F gave significant effects on GPS signal like signal loss or enhancement ionospheric error, From this study, relative orbit determination using GPS observations should consider the effect of Equatorial Spread-F and adjust orbit determination strategy, especially at the time of solar maximum.