• Journal of Korean Society of Environmental Engineers
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• v.27 no.1
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• pp.25-35
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• 2005

This study analyzed total concentrations and existing forms of heavy metals in soils of Ulsan using a sequential extraction method. Soil samples were collected from 6 categorized areas including green, residential, heavy traffic, petrochemical industrial complex(IC), mechanical and shipbuilding IC, and non-ferrous metal IC areas. which represent different emission characteristics. The highest total concentrations of heavy metals by a sequential extraction analysis were observed in the soils collected from the non-ferrous metal IC area, followed by the mechanical and shipbuilding IC and heavy traffic areas. Dominant(> 50%) existing forms of Cd, Cr and Ni were residual forms followed by Fe and Mn oxides in almost areas. Residual fractions in the non-ferrous metal IC areas were relatively lower than those in other areas. However, the fractions of organic and sulphides in the IC areas were higher. The dominant farms of Cu were much different with the investigated areas. In most areas, the dominant forms of Pb and Zn were Fe and Mn oxides, followed by residual fraction for Pb. The exchangeable and carbonate fractions represent mobility of metallic elements in soils. They are also significantly affected by the environmental renditions, such as pHs of soil and rainfall. In this study the exchangeable and carbonate fractions were lower than other fractions. Because the total concentrations of heavy metals in the soils of the non-ferrous metal IC area were extremely high, however, the mobile fractions of heavy metals in the IC area would be significant. Thus a large amount of heavy metals can be released into plants, water bodies, and soils. Therefore, urgent measures, such as source control for soil remediation of heavy metals, in the non-ferrous metal IC areas are essentially required. Analysis results obtained from the sequential extraction and the aqua regia extraction showed a high correlation, whose determination coefficients(R2) of heavy metals except Cd approximately ranged from 0.7 to 0.9.

• Proceedings of the Korean Society of Toxicology Conference
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• 2002.05a
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• pp.127-127
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• 2002

Methallothioneins(MTs) are low-molecular-mass cysteine-rich metal-binding proteins with high affinity for heavy metal ions, found in a large variety of organisms. Although the biological functions of MTS have not been fully elucidated, they are thought to play an important role in detoxification of toxic elements such as cadmium and mercury.(omitted)

• Journal of Environmental Science International
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• v.8 no.5
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• pp.607-610
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• 1999

The odor removal of landfill site leachate was carried out using pyroligenous liquid. The constituent elements of pyroligenous liquid and leachate were also analysed, employing Atomic Absorption Spectroscopy(AAS). Before order removal, the heavy metal ions such as Pb, Zn, Cu, Mn, Fe and Ni, in pyroligenous liquid were detected with ultra trace level. However, in this liquid, other metal ions such as As, Hg and Cd were not observed. The optimum condition for removing odor fromthe leachate was observed in 15 times dilution of pyroligenous liquid. Also, the degree of outlet odor was 1. Furthermore, the concentration of odor constituent compounds, e.g. $H_2S, NH_3, NH_2$ and $CO_2$ in the leachate was remarkably reduced. Finally, water quality of the leachate was improved.

• Journal of Ecology and Environment
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• v.38 no.2
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• pp.123-131
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• 2015

During several visits to the Cebu City landfill in the Philippines, plants were observed growing within the area, including on top of the garbage piles. Studying the response of these plants is important in assessing which can be used in remediating metal contaminated soils. This study aimed to determine whether the plants in the Cebu City landfill excluded or accumulated cadmium (Cd) and chromium (Cr) in the plant tissues. The floristic composition of the landfill was analyzed prior to the sample collection. The samples were acid-digested before the desired elements were measured using atomic absorption spectrophotometry (AAS). The Cd and Cr concentrations in the plant root-zone soil were also measured using AAS. The results indicated that the landfill substrate was generally acidic based on the results of the pH measurement. Of the 32 plant species sampled, Cyperus odoratus showed potential for Cd uptake and internal transfer; Cenchrus echinatus, Vernonia cinerea and Terminalia catappa for Cr uptake, and Cynodon dactylon for Cr internal transfer. The plants in the landfill differed in their response towards the heavy metals. To confirm the behavior of C. odoratus towards Cd, and C. echinatus, C. dactylon, V. cinerea, and T. catappa towards Cr, controlled experiments are recommended, as the plant samples analyzed were collected from the field.

• Korean Journal of Environment and Ecology
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• v.12 no.3
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• pp.271-278
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• 1998

Heavy metal concentrations in rocks and soils from serpentinite(SP) and in plants (Pinus densiflora: PD and Pinus rigida: PR) were examined at Baekdong mine in Hongsung, Chungnam. Parent rocks were compared with amphibole schist(AS) and gneiss(GN) and plants divided the above grounds and roots were examined, respectively. In rocks, Ni, Cr, Co, Fe concentrations in SP were higher than those in AS and GN. The concentrations of top soils had the similar differences to their rocks; especially Ni, Cr, Co, Fe concentrations were the highest in SP, Zn and Sc concentrations, however, were the highest in AS. Average Ni, Cr, Co, Au, As, Sb, W concentrations of PD were the highest in SP and especially Ni, Cr, Co concentrations were accorded with changes of rocks and top soils. Zn and Sc concentrations in AS were higher and Fe and Mo concentrations in GN were higher than those in SP. Compared with two plants in the same serpentinite sites, most elements of PR were higher than those of PD. Therefore, these suggested PR absorbed much heavy metal than PD. Most element concentrations of roots in two plants and three rocks were higher than those of the above ground. Relative ratios (average plant concentration/soil concentration) of Ni, Cr, Co, Zn, Sc, Fe in AS and GN were higher than those of SP. Especially, relative ratios of most elements except Zn in GN were the highest.

• Economic and Environmental Geology
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• v.56 no.3
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• pp.229-238
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• 2023

Bentonite is a type of rock that has been used as a traditional mineral medicine. It has a variety of pharmacological activities, and is used in traditional Korean medicine to treat jaundice, diarrhea, and hemostasis. In modern medicine, it is used as a raw material and additive for medicines such as antacids, gastrointestinal protective agents, and laxatives. Bentonite produced in Korea was produced through diagenesis or hydrothermal alteration of tertiary volcanic debris distributed in the Pohang and Gyeongju areas. It is mainly used for industrial purposes such as papermaking, paint, civil engineering, casting, and animal feed. Recently, technology is being developed to use it in cosmetics and pharmaceuticals. In this study, the geochemical characteristics of bentonite were identified by analyzing the main components and trace elements of 40 and 21 types of bentonite produced in the Gampo Gyeongju and Yeonil Pohang area. Also it were classifed by formation envrionment of bentonite deposits in the Gampo and Yeonil. As a result of the study, bentonite from the reserch area may be cased by argillic alteraton that alkali elements are removed form basaltic rocks by hydrothermal fluids and AI-CCPI alteration indices wrere also indentified argillic alteraton. It was found that there is a correlation between the behavior characteristics of heavy metal elements (P b, Cr, As) and the hydrothermal alteration of bentonite in the reserch area.

• Journal of the East Asian Society of Dietary Life
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• v.27 no.4
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• pp.450-458
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• 2017

The purpose of this study was to investigate the levels of risk perception characteristics for food risk elements using a psychometric paradigm from 298 university students in Yeungnam region, Korea, by a self-administered questionnaire. The respondents showed the highest level of risk concern about radioactive contaminated foods and the lowest level about GM (genetically modified) foods. In the risk perception characteristics for food risk elements, they perceived radioactive contaminated foods as a catastrophic, worried, new, and uncontrollable risk. In addition, they regarded food additives and foodborne illness as a chronic, controllable, old, and scientifically and individually known risk. According to the results of the factor analysis for risk perception characteristics, dread and unknown were categorized. In the risk perception map, mad cow disease, heavy metal contaminated foods, and radioactive contaminated foods were considered as a dreaded and unknown risk, whereas pesticide residues and GM foods were perceived as a less dreaded and unknown risk. Additionally, food additives and foodborne illness were regarded as a less dreaded and known risk and endocrine disruptors and avian influenza as a dreaded and known risk. These results imply that risk perception characteristics of consumers should be considered to establish strategies for risk communication in food science.

• Korean Journal of Environmental Agriculture
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• v.20 no.5
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• pp.317-324
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• 2001

Short-term effect of phosphogypsum on soil properties including acidification, salinity and metal availability were investigated under laboratory and field conditions. Phosphogypsum and mixtures of phosphogypsum and compost were added to soil and incubated in a laboratory condition with 15% moisture content. Phosphogypsum treatments were 2.5 and 5.0 g/kg soil and in the treatments of phosphogypsum and compost mixture 10 g of compost was added additionally. After the 30 days of incubation, an additional phosphogypsum and/or compost were added to the remaining soils at the same rates of the first treatments. pH, electrical conductivity, and available hazardous elements were measured periodically during the incubation. Field experiment was conducted in a plastic film house of mellon with four treatments of phosphogypsum and compost mixtures - 25+125, 50+125, 50+250 and 100+250 kg/165 $m^2$. pH, electrical conductivity, and hazardous elements in soil and total hazardous elements in leaf were measured. In the laboratory experiment, after 30 days of the first phosphogypsum application, soil pHs were lowered by 0.7-0.8 units. After the second treatment of phosphogypsum 0.2 units of additional acidification occurred. However, acidification was not observed in the soils treated with mixtures of phosphogypsum and compost. In the laboratory experiment, phosphogypsum treatments increased electrical conductivity very significantly. In field experiment, pH and electrical conductivity of soils treated with phosphogypsum were nearly the same as those of soil not treated with phosphogypsum. Since soil condition in the field study was an open system, the free acids and salts derived from phosphogypsum could be diffused down with water leaching through the soil profile and then any significant acidification or salt accumulation in the topsoil could not be observed. In both laboratory and field experiments, levels of available hazardous elements in soils treated with phosphogypsum were quite low and not different from the levels found in the control soil. Results obtained from this study suggest that application of phosphogypsum at appropriate rates on agricultural land appears of no concern in terms of acidity, salinity and hazardous element content of soil.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.88-95
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• 2009

This study is for understanding the domestic possibilities of the high temperature incineration of waste containing Polychlorinated Biphenyls (PCBs) with the analysis of normal operation case and waste gas, fly ash, dioxin about bottom ash, Total-PCBs, Co-PCBs, and the for analysis the heavy metal leaching feature included by bottom ash and fly ash, heavy metal leaching experiment was implemented. The result shows the dioxin density of the waste gas from waste containing PCBs was $0.00699{\sim}0.00763ng-TEQ/Nm^3$, which is lower than $0.0192ng-TEQ/Nm^3$ from the normal operation case. And each Co-PCBs and total PCBs shows $0.00043{\sim}0.00112ng-TEQ/Nm^3$ and $3.06{\sim}3.87ng/m^3$ respectively. The bottom ash test result shows Dioxin 0.00225~0.00630ng-TEQ/g, Co-PCBs 0.00027~0.00082ng-TEQ/g, Total PCBs 0.9~2.6ng/g, and the fly ash shows Dioxin 0.00164~0.00344ng-TEQ/g, Co-PCBs 0.00053~0.00054ng-EQ/g, Total PCBs 0.64~0.84ng/g. The bottom ash and fly ash experiments for heavy metal leaching did not show any leaching but when it comes to the ingredients of the fly ash, Pb elements shows 31.01~237.7ppm, higher than leaching criterion. The analysis of the density of all air pollution material from the waste gas shows the lower value than permissible criterion.

• Current Research on Agriculture and Life Sciences
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• v.11
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• pp.111-120
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• 1993

We investigated in the existential forms of heavy metals and their distribution in plant and soil surrounding ruined mine in Daduk area. The content of heavy metals in soils was more plentiful in A soil than that in another soil, excepting only Mn. The content of Mn in soils was greater in B soil than those in another soils. The content of each heavy metals, according to existential form, had different patterns on the comparision of each elements ; organic-form on Cd and As, Carbonate-form Cu, Pb and Mn and Residual-form on Fe and Zn. The popularity ration of M. senensis and J. decipiens were about 65% and 72%, respectively, and which means that these plants had resistances to heavy metals. The contents of heavy metals absorbed in root was higher than those of stem except Mn, In M. sinensis, the contents of Zn in root was similar to that of stem. To study the heavy metal contents in water, the highest content of heavy metal, mainly Fe, Mn and Zn, were calculated in extracting water.