• 제목/요약/키워드: Heavy metal analysis

검색결과 825건 처리시간 0.033초

음식물쓰레기의 자원화를 위한 배출업종별 성상 및 특성의 비교분석 (Comparison and Analysis on Characteristics for recycling of Multifarious Food Waste)

  • 주흥수;류재영;배재근
    • 유기물자원화
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    • 제9권4호
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    • pp.117-124
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    • 2001
  • 본 연구는 각 업종별로 배출되는 음식물쓰레기의 다양한 성상 및 그 특성을 분석하여 검토함으로서 그 특성에 맞는 적절한 처리방안과 설계단계에 있어서 기초자료로 활용하기 위하여 실시하였다. 전체적으로 업종별로 성상이 차이가 있었고, 일식업소가 다른 업소에 비교하여 많은 차이를 보였다. 조성면에서는 채소류가 가장 많이 차지하였고 또한 계절에 따라 채소류의 함량은 차이가 많았다 이물질은 조개껍질류가 가장 많았으며, 요식업소에서 배출되는 이물질 비율이 공동주택에서 보다 높아 사전분리가 필요한 것으로 조사되었다. 염분은 일식업소에서 가장 높았고, 대부분의 업소에서는 1% 전후로 자원화에 바람직하지 않지만, 전단계에서 세척공정을 둔다면 큰 문제가 없을 것으로 사료되었다. 사료성분은 조섬유가 28%, 조단백질이 25%, 조지방이 11%로 나타났다. 유해균 및 중금속에 대한 분석도 동시에 실시하였으나, 병원성미생물은 검출되지 않았고, 각종 유해물질은 규제농도이하 값을 보였다. 각종 성상의 분석결과, 자원화에 있어서 계절요인과 요식업소와 공동주택의 수거비율을 설계에 반영하는 것이 필요하며, 공동주택은 부패 등의 문제로 인하여 사료화보다는 퇴비화가 적합하고, 요식업소중 중식, 분식, 집단급식업소 등에서 배출되는 음식물쓰레기는 사료화가 유리한 것으로 평가되었다.

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Status and Changes in Chemical Properties of Paddy Soil in Gangwon Province

  • Yoon, Byeong-Sung;Choi, Seung-Chul;Lim, Soo-Jeoung;Heo, Su-Jeong;Kim, In-Jong;Kang, Seong-Soo
    • 한국토양비료학회지
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    • 제49권4호
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    • pp.293-299
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    • 2016
  • The chemical properties of paddy fields in Gangwon province were monitored every 4 years from 2003 to 2015 in order to provide basic information for soil fertility management of paddy fields. In 2015, the soil chemical properties of paddy fields were 5.9 in pH, $22g\;kg^{-1}$ in organic matter (OM), and $123mg\;kg^{-1}$ in available (Avail.) phosphate $P_2O_5$. Exchangeable (Exch.) potassium (K), calcium (Ca) and magnesium (Mg) were 0.39, 4.8 and $0.9cmolc\;kg^{-1}$, respectively, and Avail. $SiO_2$ was $170mg\;kg^{-1}$. In the long-term analysis, the contents of Avail. $SiO_2$, Exch. K and pH of paddy soils showed increasing tendency. However, Avail. $P_2O_5$, Exch. Ca and Mg tended to decrease, and there were no significant changes in the contents of OM. Soil OM, Avail. $P_2O_5$ and $SiO_2$ were not different among the different topographical sampling sites. However, the mean value of Exch. K and Ca were different among the different topographical sampling sites, and exceeded optimal values in the fluvio-marine plains. Different soil texture resulted in different soil pH, while no difference for OM, Avail. $P_2O_5$ and $SiO_2$. Paddy soil samples within appropriate pH range increased from 65% in 2003 to 77% in 2007, 68% in 2011, and 71% in 2015. In case of Avail. $SiO_2$, soil samples within appropriate range increased from 20% in 2003, to 37% in 2007, 29% in 2011, and 45% in 2015. Meanwhile, Cd and Pb were distributed to less than 5% of soil pollution standards. Cu, As and Zn were distributed to less than 10%, 15% and 20%, respectively. Therefore, paddy soil in Gangwon Province was judged to be safe. As a result, paddy fields with more or less in nutrient level need to be fertilized based on the soil analysis. And the application of silicate fertilizer is strongly recommended to those of paddy fields in need. In addition, soil management including the cultivation of green manure crop or application of rice straw is necessary to increase the organic matter content of paddy soil.

체계적인 광산관리를 위한 광산현황 및 광산공간정보 구축 기술 분석 (Analysis of the Status of Mine and Methods of Mine Geospatial Information Construction Technology for Systematic Mine Management)

  • 박준규;이근왕
    • 한국산학기술학회논문지
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    • 제19권9호
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    • pp.355-361
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    • 2018
  • 광업은 국가 산업발전의 기반이 되는 에너지와 원료자원을 공급하는 국가 기간산업으로 중요성을 가지고 있다. 한편 광산 개발은 필연적으로 광해를 동반하는데 대표적인 예로 지반침하, 중금속 오염, 수질오염 등을 들 수 있다. 광해는 피해의 범위가 크고, 복구에 많은 시간과 비용이 필요하며, 기간 지속적으로 피해가 발생할 수 있기 때문에 이를 방지하기 위한 체계적인 광산관리가 필요한 실정이다. 이에 본 연구에서는 국내 광산 및 광산공간정보 구축 현황과 광산관리를 위한 광산공간정보 구축 기술을 분석하였다. 조사된 광산은 95%가 비금속광으로 석회석 광산이 67%로 가장 많았으며, 구축된 광산공간정보는 2차원의 현황도 및 단면도, 지질도로 3차원 광산공간정보는 구축되어 있지 않은 것으로 나타났다. 3D 레이저 스캐너에 대한 조사 및 분석 결과와 우리나라 광산의 특징을 고려할 때 광산공간정보 구축을 위한 방안으로 이동식 스캐너가 가장 적합할 것으로 판단된다. 3D 레이저스캐너를 통해 취득되는 데이터는 대상물을 효과적으로 시각화 할 수 있으며, 갱내 도면의 제작, 체적의 산출 등 다양한 활용이 가능하기 때문에 체계적인 광산관리에 기여할 것이다.

한의과대학 본초학 교육과정의 개정 및 보완을 위한 설문조사 연구 (Survey on Revision and Complements for the Current Curriculum of Herbology)

  • 김홍준;최고야;김철;이금산;김정훈;이승호;황성연;주영승
    • 대한한의학회지
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    • 제30권4호
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    • pp.118-128
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    • 2009
  • Objects: This study was conducted to investigate the current educational environment of herbology and to develop a future-oriented curriculum for oriental medicine. The questionnaire used in this research was drawn up based on the current curriculum referring to the current curriculum of herbology and pharmacognosy. Methods: The survey was carried out presenting the questionnaires to a total 12,754 of the students and doctors of oriental medicine through e-mailing five times; of these, 2,074 replied. Results: 1. Among the respondents, about 97% agreed that it was necessary to revise and complement the current curriculum of herbology. 2. The respondents felt that the assigned lecture time of subject was "sufficient" (19%), "insufficient" (39%) and "average" (39%), respectively, and the level of lecture was "insufficient" (37%) or "average" (43%) respectively. According to priority, it showed that the contents which needed complement in lecture were discrimination of medicinal herbs (24%), practical use of action and indications (23%), and correlation with modern disease (21%). In theoretical lectures, 69% of the respondents agreed on the introduction of natural scientific methods 3. In practice, 51% of the respondents replied that the lecture time for practice was insufficient. The contents which needed to be complemented in practice were as follows: audio-visual materials for discrimination of medicinal herbs (22%), concrete exercise for the processing of medicinal herbs (21%), and attempts for the objective discrimination of medicinal herbs using instruments (microscope, analytical instrument, residual pesticide, heavy metal, genetic analysis) (16%). 70% replied that the discrimination of medicinal herbs of high price and rarity was "none or insufficient". 4. 56% replied that it was necessary to introduce and practice physicochemical analysis, and they showed higher requests according to the increase of their educational level. However, 86% replied that they had never experienced concrete attempts for objective discrimination of medicinal herbs, which seemed to indicate that, excepting some schools, practice exercise was rarely performed. Conclusions: According to results, it seems that an urgent review on the current course of herbology and a workshop on the process of experimental practice for professors is needed.

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포도와 포도 가공품에 함유되어 있는 trans-resveratrol의 함량 분석 (Analysis of trans-Resveratrol Contents of Grape and Grape Products Consumed in Korea)

  • 김대중;김상균;김명희;이희봉;이준수
    • 한국식품과학회지
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    • 제35권5호
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    • pp.764-768
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    • 2003
  • 본 연구는 생물학적, 비생물학적인 스트레스에 대한 방어물질중의 한가지인 trans-resveratrol를 포도와 포도가공품(포도주, 포도쥬스)으로부터 분석하는 방법을 확립하였다. trans-Resveratrol 기기분석 조건은 다음과 같다. 분석 column은 Nucleosil 100-5 C18을 사용하였으며 이동상은 acetonitrile: water(40:60, v/v)로서 UV검출기(306 nm)를 이용하여 0.3 mL/min의 유속으로 측정하였다. 분석한 결과, 재현성과 반복성의 CV%는 10%이하였으며, 회수율은 $90{\sim}110%$이었다. 또한, 포도, 포도주 그리고 포도쥬스의 최소검출한계는 14.5 ng/g, 3.62 ng/mL 그리고 4.02 ng/mL이고, 최소정량한계는 14.8 ng/g, 3.69 ng/mL 그리고 4.10 ng/mL이었다. 표준물질인 trans-resveratrol 농도가 $0.048{\sim}2.4\;{\mu}g/mL$일때 $R^2$ 값은 0.999이었다. 32품종의 포도, 9종류의 포도주 그리고 9종류의 포도쥬스 내의 trans-resveratrol 함량은 각각 $0.76{\sim}207.14\;{\mu}g/100\;g$, $5.41{\sim}275.66\;{\mu}g/L$ 그리고 $63.25{\sim}751.55\;{\mu}g/L$로 분석되었다.

Diversity of Arbuscular Mycorrhizal Fungi Associated with a Sb Accumulator Plant, Ramie (Boehmeria nivea), in an Active Sb Mining

  • Wei, Yuan;Chen, ZhiPeng;Wu, FengChang;Li, JiNing;ShangGuan, YuXian;Li, FaSheng;Zeng, Qing Ru;Hou, Hong
    • Journal of Microbiology and Biotechnology
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    • 제25권8호
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    • pp.1205-1215
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    • 2015
  • Arbuscular mycorrhizal fungi (AMF) have great potential for assisting heavy metal hyperaccumulators in the remediation of contaminated soils. However, little information is available about the symbiosis of AMF associated with an antimony (Sb) accumulator plant under natural conditions. Therefore, the objective of this study was to investigate the colonization and molecular diversity of AMF associated with the Sb accumulator ramie (Boehmeria nivea) growing in Sb-contaminated soils. Four Sb mine spoils and one adjacent reference area were selected from Xikuangshan in southern China. PCR-DGGE was used to analyze the AMF community composition in ramie roots. Morphological identification was also used to analyze the species in the rhizosphere soil of ramie. Results obtained showed that mycorrhizal symbiosis was established successfully even in the most heavily polluted sites. From the unpolluted site Ref to the highest polluted site T4, the spore numbers and AMF diversity increased at first and then decreased. Colonization increased consistently with the increasing Sb concentrations in the soil. A total of 14 species were identified by morphological analysis. From the total number of species, 4 (29%) belonged to Glomus, 2 (14%) belonged to Acaulospora, 2 (14%) belonged to Funneliformis, 1 (7%) belonged to Claroideoglomus, 1 (7%) belonged to Gigaspora, 1 (7%) belonged to Paraglomus, 1 (7%) belonging to Rhizophagus, 1 (7%) belonging to Sclervocystis, and 1 (7%) belonged to Scutellospora. Some AMF sequences were present even in the most polluted site. Morphological identification and phylogenetic analysis both revealed that most species were affiliated with Glomus, suggesting that Glomus was the dominant genus in this AMF community. This study demonstrated that ramie associated with AMF may have great potential for remediation of Sb-contaminated soils.

동진강 상류하천 유역의 수질특성 (Characteristics of Water Quality in Upper Stream Watershed of Dongjin River)

  • 손재권;박종민;최진규;송재도
    • 농촌계획
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    • 제9권2호
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    • pp.19-28
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    • 2003
  • It is the purpose of this study to investigate the change of stream water quality in upper stream of Dongjin river, and to give the basic information for the conservation of water quality. Water samples were taken periodically at 9 sampling sites during 8 months from March to October in 2002. The results of this study were as follows : 1. The water temperature and pH of stream water were ranged $9.0{\sim}29.4^{\circ}C,\;6.48{\sim}9.33$, respectively. The COD values of stream water was ranged from 0.60 to 19.06. The contents of T-N and T-P mainly affected by the livestock wastes, and agricultural activity were $1.88{\sim}6.74\;mg/L$, ND(not deleted)${\sim}0.50\;mg/L$, respectively. 2. The SS, DO and BOD values of stream water were ranged $0.4mg/L{\sim}274.0mg/L$, $0.5{\sim}6.0\;mg/L$, and $7.3{\sim}13.7\;mg/L$ respectively. 3. The cation is one of the important components in analysis of stream water quality. The contents of analysis, $Ca^{++},\;Mg^{++},\;Na^+$ and $K^+$ were ranged $1.96{\sim}11.08\;mg/L$, $1.21{\sim}6.16\;mg/L$, $3.38{\sim}18.44\;mg/L$, $1.12{\sim}7.96\;mg/L$, respectively. SAR was ranged $0.31{\sim}1.63$ below 2.0. The contents of cation showed in the order $Na^{++}>Ca^{++}>K^+>Mg^+$. 4. The contents of heavy metal Zn, Cu, and Pb were $ND{\sim}0.071\;mg/L$, $ND{\sim}0.012\;mg/L$, and $ND{\sim}0.043\;mg/L$, respectively. Cd was not detected in all samples. 5. As a result of these researches showed water quality in upper stream watershed of Dongjin river more affected by livestock wastes and living sewage than agricultural activity.

환경매체별 카드뮴의 생태위해성평가 (Ecological Risk Assessment for Cadmium in Environmental Media)

  • 이병우;이병천;윤효정;박경화;김필제
    • 한국환경보건학회지
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    • 제44권6호
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    • pp.548-555
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    • 2018
  • Objectives: We conducted ecological risk assessment for cadmium, a heavy metal and carcinogen, to identify safety standards by environmental media and to determine its impact on ecosystems by estimating and evaluating exposure levels. Methods: Species sensitivity distributions (SSDs) were generated using ECOTOX DB. A hazardous concentration of 5% (HC5) protective of most species (95%) in the environment was estimated. Using this estimate, predicted no effect concentrations (PNECs) were calculated for aquatic organisms. Based on the calculated PNECs for aquatic organisms, PNEC values for soil and sediment were calculated using the partition coefficient. Predicted exposure concentrations (PECs) were also calculated from environmental monitoring data with hazard quotients (HQs) calculated using PNECs for environmental media. Results: Chronic toxicity data were categorized into four groups and 11 species. In species sensitivity distribution (SSD) analysis, HC5 was $0.340{\mu}g/L$. Based on this value, the PNEC value for aquatic organisms was calculated as $0.113{\mu}g/L$. PNEC values for soil and sediments using a partition coefficient were calculated as 15.02 mg/kg and 90.61 mg/kg, respectively. In an analysis of environmental monitoring data, PEC values were calculated as $0.017{\mu}g/L$ for water, 1.01 mg/kg for soil, and 0.521 mg/kg for sediment. Conclusions: HQs were 0.150, 0.067 and 0.006 for water, soil and sediment, respectively. HQs of secondary toxicity were 0.365 for birds and 0.024 for mammals. In principle, it is judged that an HQ above 1 indicates a high level of risk concern while an HQ less than 1 indicates an extremely low level of risk concern. Therefore, with HQs of cadmium in the environment being <1, its risk levels can be considered low for each media.

순환토사 재활용에 관한 연구 - 농업성토용 중심으로 - (Study on the Recycling of Waste Soil from Constructed Site - Focused on Agricultural Planting Soil -)

  • 김재형;박제철
    • 한국건설순환자원학회논문집
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    • 제7권1호
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    • pp.16-21
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    • 2019
  • 본 연구에서는 순환토사가 농지개량용으로 적용 가능성이 있는지 그리고 채움재로서의 활용 가능성이 있는지 알아보기 위하여 순환토사의 물리적 화학적 성분 분석을 평가하였고, 비교생육실험 및 발아실험 그리고 식생대층 높이에 따른 생육실험을 진행하였다. 물리적 성분 분석결과 SW와 SP계열로 조사되었으며 토성은 양질사토로 조사되었다. 순환토사를 농지개량용으로 사용하기 위해서는 점토 및 미사와 혼합하여 사용하면 될 것으로 사료된다. 화학적 성분 분석결과 pH는 일반 토양보다 높으나 중금속은 토양오염우려기준의 1지역 기준치 이내로 나타났다. 발아실험결과 순환토사를 75% 미만으로 혼합하여 사용했을때 영향이 거의 없는 것으로 조사되었고, 원예용 상토에 순환토사 40% 미만을 혼합하여 사용하면 생육장해가 미비한 것으로 나타나 일반적인 토양과 차이가 없는 것으로 확인되었다.

이산화탄소 고정 탄산화물을 적용한 콘크리트 2차 제품의 기초 특성 분석 (Analysis of mechanical properties of secondary concrete products using CO2 captured material)

  • 유혜진;서성관;박금단;권혁준;김정환
    • 한국결정성장학회지
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    • 제34권2호
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    • pp.66-72
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    • 2024
  • 본 연구에서는 탈황석고(DG)에 이산화탄소를 반응시켜 제조한 탄산화물(CCMs)을 콘크리트 2차 제품의 시멘트 대체재로서 적용 가능성을 평가하고 최적 배합비 도출을 위한 탄산화물 혼입 모르타르 및 콘크리트 시편의 기초 물성 측정을 실시하였다. 탄산화물은 다량의 CaO 및 SO3로 이루어져 있으며, 주요 결정상은 CaSO4·2H2O, Ca(OH)2, CaCO3 및 CaSO4로 나타났다. 또한 입도 분석 및 폐기물공정시험기준에 따른 중금속 측정 결과 콘크리트 2차 제품의 시멘트 대체재로서 탄산화물의 적용 가능성이 확인되었다. 모르타르 및 콘크리트 공시체 제작 후 강도 거동 측정 결과 탄산화물 혼입량이 증가할수록 강도가 감소하는 경향을 나타내었으나 최적 배합인 치환 비율 10 wt.% 배합까지 대상 제품인 인터로킹 블록 및 옹벽 블록의 기준에서 요구하는 모든 조건을 만족하였다. 따라서 콘크리트 2차 제품의 시멘트 대체재로서 적용 가능성이 확인되었다.